1
JEE Main 2025 (Online) 2nd April Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language
The d-orbital electronic configuration of the complex among $\left[\mathrm{Co}(\mathrm{en})_3\right]^{3+},\left[\mathrm{CoF}_6\right]^{3-}$, $\left[\mathrm{Mn}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}$ and $\left[\mathrm{Zn}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}$ that has the highest CFSE is :
A
$t_{2 g}{ }^6 e_g^0$
B
$t_{2 g}{ }^3 e_g^2$
C
$\mathrm{t}_{2 \mathrm{~g}}{ }^4 \mathrm{e}_{\mathrm{g}}{ }^2$
D
$t_{2 g}{ }^6 e_g^4$
2
JEE Main 2025 (Online) 2nd April Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Given below are two statements :

Statement (I) : In octahedral complexes, when $\Delta_0<\mathrm{P}$ high spin complexes are formed. When $\Delta_0>P$ low spin complexes are formed.

Statement (II) : In tetrahedral complexes because of $\Delta_t < P$, low spin complexes are rarely formed.

In the light of the above statements, choose the most appropriate answer from the options given below :

A
Both Statement I and Statement II are incorrect
B
Statement I is correct but Statement II is incorrect
C
Statement I is incorrect but Statement II is correct
D
Both Statement I and Statement II are correct
3
JEE Main 2025 (Online) 29th January Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Identify the homoleptic complexes with odd number of $d$ electrons in the central metal :

(A) $\left[\mathrm{FeO}_4\right]^{2-}$

(B) $\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{3-}$

(C) $\left[\mathrm{Fe}(\mathrm{CN})_5 \mathrm{NO}\right]^{2-}$

(D) $\left[\mathrm{CoCl}_4\right]^{2-}$

(E) $\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_3 \mathrm{~F}_3\right]$

Choose the correct answer from the options given below :

A

(C) and (E) only

B

(A), (B) and (D) only

C

(B) and (D) only

D

(A), (C) and (E) only

4
JEE Main 2025 (Online) 29th January Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

The calculated spin-only magnetic moments of $K_3[Fe(OH)_6]$ and $K_4[Fe(OH)_6]$ respectively are :

A

4.90 and 4.90 B.M.

B

4.90 and 5.92 B.M.

C

5.92 and 4.90 B.M.

D

3.87 and 4.90 B.M.

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