Correct formula of the compound which gives a white precipitate with BaCl₂ solution, but not with AgNO₃ solution, is :

Given below are two statements.

$$\bullet$$ Statement I : In CuSO₄ . 5H₂O, Cu-O bonds are present.

$$\bullet$$ Statement II : In CuSO₄ . 5H₂O, ligands coordinating with Cu(II) ion are O-and S-based ligands.

In the light of the above statements, choose the correct answer from the options given below.

Given below are two statements :

Statement I : [Ni(CN)₄]^2$$-$$ is square planar and diamagnetic complex, with dsp² hybridization for Ni but [Ni(CO)₄] is tetrahedral, paramagnetic and with sp³-hybridication for Ni.

Statement II : [NiCl₄]^2$$-$$ and [Ni(CO)₄] both have same d-electron configuration have same geometry and are paramagnetic.

In light the above statements, choose the correct answer from the options given below :

Arrange the following coordination compounds in the increasing order of magnetic moments. (Atomic numbers : Mn = 25; Fe = 26)

A. [FeF₆]^3$$-$$

B. [Fe(CN)₆]^3$$-$$

C. [MnCl₆]^3$$-$$ (high spin)

D. [Mn(CN)₆]^3$$-$$

Choose the correct answer from the options given below :