1
JEE Main 2025 (Online) 4th April Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

' $X$ ' is the number of electrons in $t_{2 g}$ orbitals of the most stable complex ion among $\left[\mathrm{Fe}\left(\mathrm{NH}_3\right)_6\right]^{3+},\left[\mathrm{FeCl}_6\right]^{3-}, \quad\left[\mathrm{Fe}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]^{3-}$ and $\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}$. The nature of oxide of vanadium of the type $\mathrm{V}_2 \mathrm{O}_{\mathrm{X}}$ is :

A
Amphoteric
B
Acidic
C
Basic
D
Neutral
2
JEE Main 2025 (Online) 4th April Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

The correct order of $\left[\mathrm{FeF}_6\right]^{3-},\left[\mathrm{CoF}_6\right]^{3-},\left[\mathrm{Ni}(\mathrm{CO})_4\right]$ and $\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}$ complex species based on the number of unpaired electrons present is:

A
$\left[\mathrm{CoF}_6\right]^{3-}>\left[\mathrm{FeF}_6\right]^{3-}>\left[\mathrm{Ni}(\mathrm{CO})_4\right]>\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}$
B
$\left[\mathrm{FeF}_6\right]^{3-}>\left[\mathrm{CoF}_6\right]^{3-}>\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}>\left[\mathrm{Ni}(\mathrm{CO})_4\right]$
C
$\left[\mathrm{FeF}_6\right]^{3-}>\left[\mathrm{CoF}_6\right]^{3-}>\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}=\left[\mathrm{Ni}(\mathrm{CO})_4\right]$
D
$\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}>\left[\mathrm{FeF}_6\right]^{3-}>\left[\mathrm{CoF}_6\right]^{3-}>\left[\mathrm{Ni}(\mathrm{CO})_4\right]$
3
JEE Main 2025 (Online) 4th April Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Which one of the following complexes will have $\Delta_{\mathrm{o}}=0$ and $\mu=5.96$ B.M?

A
$\left[\mathrm{FeF}_6\right]^{4-}$
B
$\left[\mathrm{Mn}(\mathrm{SCN})_6\right]^{4-}$
C
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}$
D
$\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{4-}$
4
JEE Main 2025 (Online) 4th April Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Number of stereoisomers possible for the complexes, $\left[\mathrm{CrCl}_3(\mathrm{py})_3\right]$ and $\left[\mathrm{CrCl}_2(\mathrm{ox})_2\right]^{3-}$ are respectively $(p y=$ pyridine,$o x=$ oxalate $)$

A
3 & 3
B
2 & 3
C
1 & 2
D
2 & 2
JEE Main Subjects
EXAM MAP