JEE Main 2020 (Online) 2nd September Morning Slot | Coordination Compounds Question 184 | Chemistry

Consider that a d⁶ metal ion (M²⁺) forms a complex with aqua ligands, and the spin only magnetic moment of the complex is 4.90 BM. The geometry and the crystal field stabilization energy of the complex is

tetrahedral and – 1.6 $$\Delta $$_t + 1P

octahedral and –2.4 $$\Delta $$₀ + 2P

tetrahedral and –0.6 $$\Delta $$_t

octahedral and –1.6 $$\Delta $$₀

JEE Main 2020 (Online) 9th January Evening Slot

MCQ (Single Correct Answer)

-1

The correct order of the spin-only magnetic moments of the following complexes is :
(I) [Cr(H₂O)₆]Br₂
(II) Na₄[Fe(CN)₆]
(III) Na₃[Fe(C₂O₄)₃] ($$\Delta $$₀ $$>$$ P)
(IV) (Et₄N)₂[CoCl₄]

(III) > (I) > (II) > (IV)

(II) $$ \approx $$ (I) > (IV) > (III)

(III) > (I) > (IV) > (II)

(I) > (IV) > (III) > (II)

JEE Main 2020 (Online) 9th January Evening Slot

MCQ (Single Correct Answer)

-1

The isomer(s) of [Co(NH₃)₄Cl₂] that has/have a Cl–Co–Cl angle of 90°, is/are :

cis only

cis and trans

meridional and trans

trans only

JEE Main 2020 (Online) 9th January Morning Slot

MCQ (Single Correct Answer)

-1

[Pd(F)(Cl)(Br)(I)]^2– has n number of geometrical isomers. Then, the spin-only magnetic moment and crystal field stabilisation energy [CFSE] of [Fe(CN)₆]^n–6, respectively, are:
[Note : Ignore the pairing energy]

1.73 BM and –2.0 $$\Delta $$₀

5.92 BM and 0

2.84 BM and –1.6 $$\Delta $$₀

0 BM and –2.4 $$\Delta $$₀

PREVIOUS NEXT

Questions Asked from Coordination Compounds (MCQ (Single Correct Answer))

Number in Brackets after Paper Indicates No. of Questions