1
JEE Main 2025 (Online) 28th January Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Match List - I with List - II.

List - I (Complex) List - II (Hybridisation of central metal ion)
(A) [CoF6]3- (I) d2sp3
(B) [NiCl4]2- (II) sp3
(C) [Co(NH3)6]3+ (III) sp3d2
(D) [Ni(CN)4]2- (IV) dsp2
Choose the correct answer from the options given below:

A

(A)-(I), (B)-(II), (C)-(III), (D)-(IV)

B

(A)-(III), (B)-(IV), (C)-(I), (D)-(II)

C

(A)-(I), (B)-(IV), (C)-(III), (D)-(II)

D

(A)-(III), (B)-(II), (C)-(I), (D)-(IV)

2
JEE Main 2025 (Online) 24th January Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

The conditions and consequence that favours the $t_{2 \mathrm{~g}}{ }^3 \mathrm{e}_{\mathrm{g}}{ }^1$ configuration in a metal complex are :

A
strong field ligand, low spin complex
B
strong field ligand, high spin complex
C
weak field ligand, high spin complex
D
weak field ligand, low spin complex
3
JEE Main 2025 (Online) 24th January Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

When Ethane-1,2-diamine is added progressively to an aqueous solution of Nickel (II) chloride, the sequence of colour change observed will be:

A
Pale Blue $\rightarrow$ Blue $\rightarrow$ Green $\rightarrow$ Violet
B
Pale Blue $\rightarrow$ Blue $\rightarrow$ Violet $\rightarrow$ Green
C
Green $\rightarrow$ Pale Blue $\rightarrow$ Blue $\rightarrow$ Violet
D
Violet $\rightarrow$ Blue $\rightarrow$ Pale Blue $\rightarrow$ Green
4
JEE Main 2025 (Online) 24th January Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

One mole of the octahedral complex compound $\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}_3$ gives 3 moles of ions on dissolution in water. One mole of the same complex reacts with excess of $\mathrm{AgNO}_3$ solution to yield two moles of $\mathrm{AgCl}_{(\mathrm{s})}$. The structure of the complex is:

A
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{Cl}_2$
B
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}\right] \cdot \mathrm{Cl}_2 \cdot \mathrm{NH}_3$
C
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3 \mathrm{Cl}_3\right] \cdot 2 \mathrm{NH}_3$
D
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right] \cdot \mathrm{Cl} \cdot \mathrm{NH}_3$
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