Given below are two statements :

Statement I : Vapours of the liquid with higher boiling point condense before vapours of the liquid with lower boiling points in fractional distillation.

Statement II : The vapours rising up in the fractionating column become richer in high boiling component of the mixture.

In the light of the above statements, choose the correct answer from the options given below :

$$ \text { The total number of aromatic compounds/species from the following is } $$

Shown below is the structure of methyl acetate with three different $\alpha, \beta$ and $\gamma$ carbon - oxygen bonds.

The correct order of bond lengths of these bonds is :

Given below are two statements :

Statement I : On the basis of inductive effect, the order of stability of alkyl carbanions is $\mathrm{CH}_3{ }^{-}>\mathrm{CH}_3-\mathrm{CH}_2{ }^{-}>\left(\mathrm{CH}_3\right)_2 \mathrm{CH}^{-}>\left(\mathrm{CH}_3\right)_3 \mathrm{C}^{-}$.

Statement II : Allyl and benzyl carbanions are more stabilised by inductive effect and not by resonance effect.

In the light of the above statements, choose the correct answer from the options given below :