1
JEE Main 2024 (Online) 9th April Morning Shift
MCQ (Single Correct Answer)
+4
-1

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A): The total number of geometrical isomers shown by $$[\mathrm{Co}(\mathrm{en})_2 \mathrm{Cl}_2]^{+}$$ complex ion is three.

Reason (R): $$[\mathrm{Co}(\mathrm{en})_2 \mathrm{Cl}_2]^{+}$$ complex ion has an octahedral geometry.

In the light of the above statements, choose the most appropriate answer from the options given below :

A
(A) is correct but (R) is not correct
B
(A) is not correct but (R) is correct
C
Both (A) and (R) are correct but (R) is not the correct explanation of (A)
D
Both (A) and (R) are correct and (R) is the correct explanation of (A)
2
JEE Main 2024 (Online) 8th April Evening Shift
MCQ (Single Correct Answer)
+4
-1

Match List I with List II

LIST I
(Complex ion)
LIST II
(Spin only magnetic moment in B.M.)
A. $$
\left[\mathrm{Cr}\left(\mathrm{NH}_3\right)_6\right]^{3+}
$$
I. 4.90
B. $$
\left[\mathrm{NiCl}_4\right]^{2-}
$$
II. 3.87
C. $$
\left[\mathrm{CoF}_6\right]^{3-}
$$
III. 0.0
D. $$
\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}
$$
IV. 2.83

Choose the correct answer from the options given below :

A
(A)-(IV), (B)-(III), (C)-(I), (D)-(II)
B
(A)-(II), (B)-(III), (C)-(I), (D)-(IV)
C
(A)-(I), (B)-(IV), (C)-(II), (D)-(III)
D
(A)-(II), (B)-(IV), (C)-(I), (D)-(III)
3
JEE Main 2024 (Online) 8th April Morning Shift
MCQ (Single Correct Answer)
+4
-1

Number of Complexes with even number of electrons in $$\mathrm{t_{2 g}}$$ orbitals is -

$$\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+},\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+},\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+},\left[\mathrm{Cu}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+},\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}$$

A
3
B
2
C
1
D
5
4
JEE Main 2024 (Online) 8th April Morning Shift
MCQ (Single Correct Answer)
+4
-1

An octahedral complex with the formula $$\mathrm{CoCl}_3 \cdot \mathrm{nNH}_3$$ upon reaction with excess of $$\mathrm{AgNO}_3$$ solution gives 2 moles of $$\mathrm{AgCl}$$. Consider the oxidation state of $$\mathrm{Co}$$ in the complex is '$$x$$'. The value of "$$x+n$$" is __________.

A
6
B
5
C
3
D
8
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