1
JEE Main 2020 (Online) 8th January Evening Slot
MCQ (Single Correct Answer)
+4
-1
Change Language
The correct order of the calculated spin-only magnetic moments of complexs (A) to (D) is:
(A) Ni(CO)4
(B) [Ni(H2O)6]Cl2
(C) Na2[Ni(CN)4]
(D) PdCl2(PPh3)2
A
(C) < (D) < (B) < (A)
B
(C) $$ \approx $$ (D) < (B) < (A)
C
(A) $$ \approx $$ (C) $$ \approx $$ (D) < (B)
D
(A) $$ \approx $$ (C) < (B) $$ \approx $$ (D)
2
JEE Main 2020 (Online) 8th January Morning Slot
MCQ (Single Correct Answer)
+4
-1
Change Language
The complex that can show fac- and mer-isomers is :
A
[CoCl2(en)2]
B
[Pt(NH3)2Cl2]
C
[Co(NH3)3(NO2)3]
D
[Co(NH3)4Cl2]+
3
JEE Main 2020 (Online) 7th January Evening Slot
MCQ (Single Correct Answer)
+4
-1
Change Language
The number of possible optical isomers for the complexes MA2B2 with sp3 and dsp2 hydridized metal atom. respectively, is :
Note : A and B are unidentate netural and unidentate monoanionic ligands, respectively.
A
0 and 2
B
0 and 0
C
0 and 1
D
2 and 2
4
JEE Main 2020 (Online) 7th January Evening Slot
MCQ (Single Correct Answer)
+4
-1
Change Language
Among the statements(a)-(d) the incorrect ones are :
(a) Octahedral CO(III) complexes with strong fields ligands have very high magnetic moments.
(b) When $$\Delta $$0 < P, the d-electron configuration of Co(III) in an octahedral complex is $$t_{eg}^4e_g^2$$
(c) Wavelength of light absorbed by [Co(en)3]3+ is lower than that of [CoF6]3-
(d) If the $$\Delta $$0 for an octahedral complex of CO(III) is 18,000 cm-1, the $$\Delta $$t for its tetrahedral complex with the same ligand be 16,000 cm-1
A
(a) and (b) only
B
(b) and (c) only
C
(c) and (d) only
D
(a) and (d) only
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