1
JEE Main 2025 (Online) 24th January Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

The conditions and consequence that favours the $t_{2 \mathrm{~g}}{ }^3 \mathrm{e}_{\mathrm{g}}{ }^1$ configuration in a metal complex are :

A
strong field ligand, low spin complex
B
strong field ligand, high spin complex
C
weak field ligand, high spin complex
D
weak field ligand, low spin complex
2
JEE Main 2025 (Online) 24th January Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

When Ethane-1,2-diamine is added progressively to an aqueous solution of Nickel (II) chloride, the sequence of colour change observed will be:

A
Pale Blue $\rightarrow$ Blue $\rightarrow$ Green $\rightarrow$ Violet
B
Pale Blue $\rightarrow$ Blue $\rightarrow$ Violet $\rightarrow$ Green
C
Green $\rightarrow$ Pale Blue $\rightarrow$ Blue $\rightarrow$ Violet
D
Violet $\rightarrow$ Blue $\rightarrow$ Pale Blue $\rightarrow$ Green
3
JEE Main 2025 (Online) 24th January Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

One mole of the octahedral complex compound $\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}_3$ gives 3 moles of ions on dissolution in water. One mole of the same complex reacts with excess of $\mathrm{AgNO}_3$ solution to yield two moles of $\mathrm{AgCl}_{(\mathrm{s})}$. The structure of the complex is:

A
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{Cl}_2$
B
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}\right] \cdot \mathrm{Cl}_2 \cdot \mathrm{NH}_3$
C
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3 \mathrm{Cl}_3\right] \cdot 2 \mathrm{NH}_3$
D
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right] \cdot \mathrm{Cl} \cdot \mathrm{NH}_3$
4
JEE Main 2025 (Online) 23rd January Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Identify the coordination complexes in which the central metal ion has $\mathrm{d}^4$ configuration.

(A) $\left[\mathrm{FeO}_4\right]^{2-}$

(B) $\quad\left[\mathrm{Mn}(\mathrm{CN})_6\right]^{3-}$

(C) $\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{3-}$

(D) JEE Main 2025 (Online) 23rd January Evening Shift Chemistry - Coordination Compounds Question 27 English (E) $\left[\mathrm{NiF}_6\right]^{2-}$

Choose the correct answer from the options given below :

A
(B), (C) and (D) only
B
(C) and (E) only
C
$(A),(B)$ and $(E)$ only
D
(B) and (D) only
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