The observed and normal molar masses of compound $\mathrm{MX}_2$ are 65.6 and 164 respectively. The percent degree of ionisation of $\mathrm{MX}_2$ is __________%. (Nearest integer)

If 1 mM solution of ethylamine produces $\mathrm{pH}=9$, then the ionization constant $\left(\mathrm{K}_{\mathrm{b}}\right)$ of ethylamine is $10^{-x}$. The value of $x$ is _________ (nearest integer).

[The degree of ionization of ethylamine can be neglected with respect to unity.]

Consider the dissociation of the weak acid HX as given below

$$\mathrm{HX}(\mathrm{aq}) \rightleftharpoons \mathrm{H}^{+}(\mathrm{aq})+\mathrm{X}^{-}(\mathrm{aq}), \mathrm{Ka}=1.2 \times 10^{-5}$$

[$$\mathrm{K}_{\mathrm{a}}$$ : dissociation constant]

The osmotic pressure of $$0.03 \mathrm{M}$$ aqueous solution of $$\mathrm{HX}$$ at $$300 \mathrm{~K}$$ is _________ $$\times 10^{-2}$$ bar (nearest integer).

[Given : $$\mathrm{R}=0.083 \mathrm{~L} \mathrm{~bar} \mathrm{~mol}^{-1} \mathrm{~K}^{-1}$$]