Consider the following complexes
(A) $$\left[\mathrm{CoCl}\left(\mathrm{NH}_3\right)_5\right]^{2+}$$, (B) $$\left[\mathrm{Co}(\mathrm{CN})_6\right]^{3-}$$, (C) $$ \left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{H}_2 \mathrm{O}\right)\right]^{3+} $$, (D) $$\left[\mathrm{Cu}\left(\mathrm{H}_2 \mathrm{O}\right)_4\right]^{2+}$$
The correct order of A, B, C and D in terms of wavenumber of light absorbed is :
Match List I with List II
LIST I (Hybridization) |
LIST II (Orientation in Shape) |
||
---|---|---|---|
A. | sp$$^3$$ | I. | Trigonal bipyramidal |
B. | dsp$$^2$$ | II. | Octahedral |
C. | sp$$^3$$d | III. | Tetrahedral |
D. | sp$$^3$$d$$^2$$ | IV. | Square planar |
Choose the correct answer from the options given below:
The number of complexes from the following with no electrons in the $$t_2$$ orbital is ______.
$$\mathrm{TiCl}_4,\left[\mathrm{MnO}_4\right]^{-},\left[\mathrm{FeO}_4\right]^{2-},\left[\mathrm{FeCl}_4\right]^{-},\left[\mathrm{CoCl}_4\right]^{2-}$$
The metal atom present in the complex MABXL (where A, B, X and L are unidentate ligands and $$\mathrm{M}$$ is metal) involves $$\mathrm{sp}^3$$ hybridization. The number of geometrical isomers exhibited by the complex is :