1
JEE Main 2024 (Online) 6th April Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Consider the following complexes

(A) $$\left[\mathrm{CoCl}\left(\mathrm{NH}_3\right)_5\right]^{2+}$$, (B) $$\left[\mathrm{Co}(\mathrm{CN})_6\right]^{3-}$$, (C) $$ \left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{H}_2 \mathrm{O}\right)\right]^{3+} $$, (D) $$\left[\mathrm{Cu}\left(\mathrm{H}_2 \mathrm{O}\right)_4\right]^{2+}$$

The correct order of A, B, C and D in terms of wavenumber of light absorbed is :

A
D < A < C < B
B
B < C < A < D
C
C < D < A < B
D
A < C < B < D
2
JEE Main 2024 (Online) 6th April Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Match List I with List II

LIST I
(Hybridization)
LIST II
(Orientation in Shape)
A. sp$$^3$$ I. Trigonal bipyramidal
B. dsp$$^2$$ II. Octahedral
C. sp$$^3$$d III. Tetrahedral
D. sp$$^3$$d$$^2$$ IV. Square planar

Choose the correct answer from the options given below:

A
A-III, B-I, C-IV, D-II
B
A-III, B-IV, C-I, D-II
C
A-IV, B-III, C-I, D-II
D
A-II, B-I, C-IV, D-III
3
JEE Main 2024 (Online) 5th April Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

The number of complexes from the following with no electrons in the $$t_2$$ orbital is ______.

$$\mathrm{TiCl}_4,\left[\mathrm{MnO}_4\right]^{-},\left[\mathrm{FeO}_4\right]^{2-},\left[\mathrm{FeCl}_4\right]^{-},\left[\mathrm{CoCl}_4\right]^{2-}$$

A
4
B
2
C
3
D
1
4
JEE Main 2024 (Online) 5th April Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

The metal atom present in the complex MABXL (where A, B, X and L are unidentate ligands and $$\mathrm{M}$$ is metal) involves $$\mathrm{sp}^3$$ hybridization. The number of geometrical isomers exhibited by the complex is :

A
0
B
2
C
3
D
4
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