1
JEE Main 2024 (Online) 5th April Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

The number of complexes from the following with no electrons in the $$t_2$$ orbital is ______.

$$\mathrm{TiCl}_4,\left[\mathrm{MnO}_4\right]^{-},\left[\mathrm{FeO}_4\right]^{2-},\left[\mathrm{FeCl}_4\right]^{-},\left[\mathrm{CoCl}_4\right]^{2-}$$

A
4
B
2
C
3
D
1
2
JEE Main 2024 (Online) 5th April Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

The metal atom present in the complex MABXL (where A, B, X and L are unidentate ligands and $$\mathrm{M}$$ is metal) involves $$\mathrm{sp}^3$$ hybridization. The number of geometrical isomers exhibited by the complex is :

A
0
B
2
C
3
D
4
3
JEE Main 2024 (Online) 5th April Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

The correct order of ligands arranged in increasing field strength.

A
$$\mathrm{F}^{-}<\mathrm{Br}^{-}<\mathrm{I}^{-}<\mathrm{NH}_3$$
B
$$\mathrm{H}_2 \mathrm{O}<\mathrm{^{-}OH}<\mathrm{CN}^{-}<\mathrm{NH}_3$$
C
$$\mathrm{Br}^{-}<\mathrm{F}^{-}<\mathrm{H}_2 \mathrm{O}<\mathrm{NH}_3$$
D
$$\mathrm{Cl}^{-}<\mathrm{^{-}OH}<\mathrm{Br}^{-}<\mathrm{CN}^{-}$$
4
JEE Main 2024 (Online) 5th April Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Which one of the following complexes will exhibit the least paramagnetic behaviour ? [Atomic number, $$\mathrm{Cr}=24, \mathrm{Mn}=25, \mathrm{Fe}=26, \mathrm{Co}=27$$]

A
$$\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}$$
B
$$\left[\mathrm{Mn}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}$$
C
$$\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}$$
D
$$\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}$$
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