1
JEE Main 2025 (Online) 29th January Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

0.1 M solution of KI reacts with excess of $\mathrm{H}_2 \mathrm{SO}_4$ and $\mathrm{KIO}_3$ solutions. According to equation

$$ 5 \mathrm{I}^{-}+\mathrm{IO}_3^{-}+6 \mathrm{H}^{+} \rightarrow 3 \mathrm{I}_2+3 \mathrm{H}_2 \mathrm{O} $$

Identify the correct statements :

(A) 200 mL of KI solution reacts with 0.004 mol of $\mathrm{KIO}_3$

(B) 200 mL of KI solution reacts with 0.006 mol of $\mathrm{H}_2 \mathrm{SO}_4$

(C) 0.5 L of KI solution produced 0.005 mol of $\mathrm{I}_2$

(D) Equivalent weight of $\mathrm{KIO}_3$ is equal to ( $\frac{\text { Molecular weight }}{5}$ )

Choose the correct answer from the options given below :

A

(C) and (D) only

B

(A) and (B) only

C

(B) and (C) only

D

(A) and (D) only

2
JEE Main 2025 (Online) 28th January Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Given below are two statements:

Statement I: In the oxalic acid vs $\mathrm{KMnO}_4$ (in the presence of dil $\mathrm{H}_2 \mathrm{SO}_4$ ) titration the solution needs to be heated initially to $60^{\circ} \mathrm{C}$, but no heating is required in Ferrous ammonium sulphate (FAS) vs $\mathrm{KMnO}_4$ titration (in the presence of dil $\mathrm{H}_2 \mathrm{SO}_4$)

Statement II: In oxalic acid vs $\mathrm{KMnO}_4$ titration, the initial formation of $\mathrm{MnSO}_4$ takes place at high temperature, which then acts as catalyst for further reaction. In the case of FAS vs $\mathrm{KMnO}_4$, heating oxidizes $\mathrm{Fe}^{2+}$ into $\mathrm{Fe}^{3+}$ by oxygen of air and error may be introduced in the experiment.

In the light of the above statements, choose the correct answer from the options given below

A
Statement I is false but Statement II is true
B
Statement I is true but Statement II is false
C
Both Statement I and Statement II are true
D
Both Statement I and Statement II are false
3
JEE Main 2025 (Online) 28th January Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Match the List - I with List - II

List - I
(Redox Reaction)
List - II
(Type of Redox Reaction)
(A) $\begin{aligned} & \mathrm{CH}_{4(\mathrm{~g})}+2 \mathrm{O}_{2(\mathrm{~g})} \xrightarrow{\Delta} \mathrm{CO}_{2(\mathrm{~g})} \\ & +2 \mathrm{H}_2 \mathrm{O}_{(\mathrm{l})}\end{aligned}$ (I) Disproportionation reaction
(B) $2 \mathrm{NaH}_{(\mathrm{s})} \xrightarrow{\Delta} 2 \mathrm{Na}_{(\mathrm{s})}+\mathrm{H}_{2(\mathrm{~g})}$ (II) Combination reaction
(C) $\begin{aligned} & \mathrm{V}_2 \mathrm{O}_{5(\mathrm{~s})}+5 \mathrm{Ca}_{(\mathrm{s})} \xrightarrow{\Delta} 2 \mathrm{~V}_{(\mathrm{s})} \\ & +5 \mathrm{CaO}_{(\mathrm{s})}\end{aligned}$ (III) Decomposition reaction
(D) $\begin{aligned} & 2 \mathrm{H}_2 \mathrm{O}_{2(\mathrm{aq})} \stackrel{\Delta}{\longrightarrow} 2 \mathrm{H}_2 \mathrm{O}_{(\mathrm{l})}+ \\ & \mathrm{O}_{2(\mathrm{~g})}\end{aligned}$ (IV) Displacement reaction

Choose the correct answer from the options given below:

A
A-III, B-IV, C-I, D-II
B
A-IV, B-I, C-II, D-III
C
A-II, B-III, C-I, D-IV
D
A-II, B-III, C-IV, D-I
4
JEE Main 2025 (Online) 28th January Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Which of the following oxidation reactions are carried out by both $\mathrm{K}_2 \mathrm{Cr}_2 \mathrm{O}_7$ and $\mathrm{KMnO}_4$ in acidic medium?

A. $\Gamma^{-} \rightarrow \mathrm{I}_2$

B. $\mathrm{S}^{2-} \rightarrow \mathrm{S}$

C. $\mathrm{Fe}^{2+} \rightarrow \mathrm{Fe}^{3+}$

D. $\mathrm{I}^{-} \rightarrow \mathrm{IO}_3^{-}$

E. $\mathrm{S}_2 \mathrm{O}_3{ }^{2-} \rightarrow \mathrm{SO}_4^{2-}$

Choose the correct answer from the options given below :

A
A, B and C Only
B
C, D and E Only
C
B, C and D Only
D
A, D and E Only
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