1
JEE Main 2025 (Online) 7th April Evening Shift
MCQ (Single Correct Answer)
+4
-1

Match List - I with List - II.

List - I (Complex) List - II (Primary valency and Secondary valency)
(A) [Co(en)2Cl2]Cl (I) 3,    6
(B) [Pt(NH3)2Cl(NO2)] (II) 3,    4
(C) Hg [Co(SCN)4] (III) 2,    6
(D) [Mg (EDTA)]2− (IV) 2,    4

Choose the correct answer from the options given below :

A

(A)-(I), (B)-(III), (C)-(II), (D)-(IV)

B

(A)-(II), (B)-(III), (C)-(IV), (D)-(I)

C

(A)-(I), (B)-(IV), (C)-(II), (D)-(III)

D

(A)-(III), (B)-(I), (C)-(II), (D)-(IV)

2
JEE Main 2025 (Online) 7th April Evening Shift
MCQ (Single Correct Answer)
+4
-1

The number of unpaired electrons responsible for the paramagnetic nature of the following complex species are respectively :

[Fe(CN)6]3−, [FeF6]3−, [CoF6]3−, [Mn(CN)6]3−

A

1, 5, 4, 2

B

1, 4, 4, 2

C

1, 5, 5, 2

D

1, 1, 4, 2

3
JEE Main 2025 (Online) 7th April Evening Shift
MCQ (Single Correct Answer)
+4
-1

'X' is the number of acidic oxides among VO2, V2O3, CrO3, V2O5 and Mn2O7. The primary valency of cobalt in
[Co(H2NCH2CH2NH2)3]2(SO4)3 is Y. The value of X + Y is _________.

A

3

B

4

C

2

D

5

4
JEE Main 2025 (Online) 7th April Morning Shift
MCQ (Single Correct Answer)
+4
-1

An octahedral complex having molecular composition $\mathrm{Co} \cdot 5 \mathrm{NH}_3 \cdot \mathrm{Cl}^2 . \mathrm{SO}_4$ has two isomers A and B. The solution of A gives a white precipitate with $\mathrm{AgNO}_3$ solution and the solution of B gives white precipitate with $\mathrm{BaCl}_2$ solution. The type of isomerism exhibited by the complex is,

A
Co-ordinate isomerism
B
Ionisation isomerism
C
Geometrical isomerism
D
Linkage isomerism
JEE Main Subjects
EXAM MAP
Medical
NEETAIIMS
Graduate Aptitude Test in Engineering
GATE CSEGATE ECEGATE EEGATE MEGATE CEGATE PIGATE IN
Civil Services
UPSC Civil Service
Defence
NDA
Staff Selection Commission
SSC CGL Tier I
CBSE
Class 12