1
JEE Main 2025 (Online) 29th January Evening Shift
MCQ (Single Correct Answer)
+4
-1

Identify the homoleptic complexes with odd number of $d$ electrons in the central metal :

(A) $\left[\mathrm{FeO}_4\right]^{2-}$

(B) $\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{3-}$

(C) $\left[\mathrm{Fe}(\mathrm{CN})_5 \mathrm{NO}\right]^{2-}$

(D) $\left[\mathrm{CoCl}_4\right]^{2-}$

(E) $\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_3 \mathrm{~F}_3\right]$

Choose the correct answer from the options given below :

A

(C) and (E) only

B

(A), (B) and (D) only

C

(B) and (D) only

D

(A), (C) and (E) only

2
JEE Main 2025 (Online) 29th January Evening Shift
MCQ (Single Correct Answer)
+4
-1

The calculated spin-only magnetic moments of $K_3[Fe(OH)_6]$ and $K_4[Fe(OH)_6]$ respectively are :

A

4.90 and 4.90 B.M.

B

4.90 and 5.92 B.M.

C

5.92 and 4.90 B.M.

D

3.87 and 4.90 B.M.

3
JEE Main 2025 (Online) 22nd January Morning Shift
MCQ (Single Correct Answer)
+4
-1

From the magnetic behaviour of $\left[\mathrm{NiCl}_4\right]^{2-}$ (paramagnetic) and $\left[\mathrm{Ni}(\mathrm{CO})_4\right]$ (diamagnetic), choose the correct geometry and oxidation state.

A
$\left[\mathrm{NiCl}_4\right]^{2-}: \mathrm{Ni}(0)$, tetrahedral $\left[\mathrm{Ni}(\mathrm{CO})_4\right]: \mathrm{Ni}(0)$, square planar
B
$\left[\mathrm{NiCl}_4\right]^{2-}: \mathrm{Ni}^{\mathrm{II}}$, tetrahedral $\left[\mathrm{Ni}(\mathrm{CO})_4\right]: \mathrm{Ni}(0)$, tetrahedral
C
$\left[\mathrm{NiCl}_4\right]^{2-}: \mathrm{Ni}^{\mathrm{II}}$, tetrahedral $\left[\mathrm{Ni}(\mathrm{CO})_4\right]: \mathrm{Ni}^{I I}$, square planar
D
$\left[\mathrm{NiCl}_4\right]^{2-}: \mathrm{Ni}^{\mathrm{II}}$, square planar $\left[\mathrm{Ni}(\mathrm{CO})_4\right]: \mathrm{Ni}(0)$, square planar
4
JEE Main 2025 (Online) 22nd January Morning Shift
MCQ (Single Correct Answer)
+4
-1
 

In which of the following complexes the CFSE, $\Delta_o$ will be equal to zero?

A
$\mathrm{K}_3\left[\mathrm{Fe}(\mathrm{SCN})_6\right]$
B
$\left[\mathrm{Fe}(\mathrm{en})_3\right] \mathrm{Cl}_3$
C
$\left[\mathrm{Fe}\left(\mathrm{NH}_3\right)_6\right] \mathrm{Br}_2$
D
$\mathrm{K}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]$
JEE Main Subjects
EXAM MAP
Medical
NEETAIIMS
Graduate Aptitude Test in Engineering
GATE CSEGATE ECEGATE EEGATE MEGATE CEGATE PIGATE IN
Civil Services
UPSC Civil Service
Defence
NDA
Staff Selection Commission
SSC CGL Tier I
CBSE
Class 12