Identify the homoleptic complexes with odd number of $d$ electrons in the central metal :
(A) $\left[\mathrm{FeO}_4\right]^{2-}$
(B) $\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{3-}$
(C) $\left[\mathrm{Fe}(\mathrm{CN})_5 \mathrm{NO}\right]^{2-}$
(D) $\left[\mathrm{CoCl}_4\right]^{2-}$
(E) $\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_3 \mathrm{~F}_3\right]$
Choose the correct answer from the options given below :
The calculated spin-only magnetic moments of $K_3[Fe(OH)_6]$ and $K_4[Fe(OH)_6]$ respectively are :
The correct increasing order of stability of the complexes based on $\Delta_0$ value is :
- I. $[\text{Mn}(\text{CN})_6]^{3-}$
- II. $[\text{Co}(\text{CN})_6]^{4-}$
- III. $[\text{Fe}(\text{CN})_6]^{4-}$
- IV. $[\text{Fe}(\text{CN})_6]^{3-}$
Match List - I with List - II.
| List - I (Complex) | List - II (Hybridisation & Magnetic characters) |
|---|---|
| (A) [MnBr4]2- | (I) d2sp3 & diamagnetic |
| (B) [FeF6]3- | (II) sp3d2 & paramagnetic |
| (C) [Co(C2O4)3]3- | (III) sp3 & diamagnetic |
| (D) [Ni(CO)4] | (IV) sp3 & paramagnetic |
Choose the correct answer from the options given below :
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