If A2B is 30% ionised in an aqueous solution, then the value of van't Hoff factor (i) is _______ × 10−1.
The vapor pressure of pure benzene and methyl benzene at $$27^{\circ} \mathrm{C}$$ is given as 80 Torr and 24 Torr, respectively. The mole fraction of methyl benzene in vapor phase, in equilibrium with an equimolar mixture of those two liquids (ideal solution) at the same temperature is _________ $$\times 10^{-2}$$ (nearest integer)
A solution containing $$10 \mathrm{~g}$$ of an electrolyte $$\mathrm{AB}_2$$ in $$100 \mathrm{~g}$$ of water boils at $$100.52^{\circ} \mathrm{C}$$. The degree of ionization of the electrolyte $$(\alpha)$$ is _________ $$\times 10^{-1}$$. (nearest integer)
[Given : Molar mass of $$\mathrm{AB}_2=200 \mathrm{~g} \mathrm{~mol}^{-1}, \mathrm{~K}_{\mathrm{b}}$$ (molal boiling point elevation const. of water) $$=0.52 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$$, boiling point of water $$=100^{\circ} \mathrm{C} ; \mathrm{AB}_2$$ ionises as $$\mathrm{AB}_2 \rightarrow \mathrm{A}^{2+}+2 \mathrm{~B}^{-}]$$
When '$$x$$' $$\times 10^{-2} \mathrm{~mL}$$ methanol (molar mass $$=32 \mathrm{~g}$$' density $$=0.792 \mathrm{~g} / \mathrm{cm}^3$$) is added to $$100 \mathrm{~mL}$$. water (density $$=1 \mathrm{~g} / \mathrm{cm}^3$$), the following diagram is obtained.
$$x=$$ ________ (nearest integer).
[Given : Molal freezing point depression constant of water at $$273.15 \mathrm{~K}$$ is $$1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$$]