1
JEE Main 2024 (Online) 4th April Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Number of complexes from the following with even number of unpaired "$$\mathrm{d}$$" electrons is ________ $$[\mathrm{V}(\mathrm{H}_2 \mathrm{O})_6]^{3+},[\mathrm{Cr}(\mathrm{H}_2 \mathrm{O})_6]^{2+},[\mathrm{Fe}(\mathrm{H}_2 \mathrm{O})_6]^{3+},[\mathrm{Ni}(\mathrm{H}_2 \mathrm{O})_6]^{3+},[\mathrm{Cu}(\mathrm{H}_2 \mathrm{O})_6]^{2+}$$ [Given atomic numbers: $$\mathrm{V}=23, \mathrm{Cr}=24, \mathrm{Fe}=26, \mathrm{Ni}=28 \mathrm{Cu}=29$$]

A
1
B
5
C
2
D
4
2
JEE Main 2024 (Online) 4th April Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

The correct sequence of ligands in the order of decreasing field strength is :

A
$$\mathrm{NCS}^{-}>\mathrm{EDTA}^{4-}>\mathrm{CN}^{-}>\mathrm{CO}$$
B
$$\mathrm{CO}>\mathrm{H}_2 \mathrm{O}>\mathrm{F}^{-}>\mathrm{S}^{2-}$$
C
$$\mathrm{S}^{2-}>{ }^{-} \mathrm{OH}>\mathrm{EDTA}^{4-}>\mathrm{CO}$$
D
$${ }^{-} \mathrm{OH}>\mathrm{F}^{-}>\mathrm{NH}_3>\mathrm{CN}^{-}$$
3
JEE Main 2024 (Online) 1st February Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}$ and $\left[\mathrm{CoF}_6\right]^{3-}$ are respectively known as :
A
Inner orbital Complex, Spin paired Complex
B
Spin paired Complex, Spin free Complex
C
Spin free Complex, Spin paired Complex
D
Outer orbital Complex, Inner orbital Complex
4
JEE Main 2024 (Online) 1st February Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language
Given below are two statements :

Statement (I) : Dimethyl glyoxime forms a six-membered covalent chelate when treated with $\mathrm{NiCl}_2$ solution in presence of $\mathrm{NH}_4 \mathrm{OH}$.

Statement (II) : Prussian blue precipitate contains iron both in $(+2)$ and $(+3)$ oxidation states.

In the light of the above statements, choose the most appropriate answer from the options given below :
A
Statement I is false but Statement II is true
B
Both Statement I and Statement II are true
C
Statement I is true but Statement II is false
D
Both Statement I and Statement II are false
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