1
JEE Main 2025 (Online) 22nd January Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

The correct order of the following complexes in terms of their crystal field stabilization energies is :

A
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4\right]^{2+}<\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{2+}<\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}<\left[\mathrm{Co}(\mathrm{en})_3\right]^{3+}$
B
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4\right]^{2+}<\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{2+}<\left[\mathrm{Co}(\mathrm{en})_3\right]^{3+}<\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}$
C
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{2+}<\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}<\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4\right]^{2+}<\left[\mathrm{Co}(\mathrm{en})_3\right]^{3+}$
D
$\left[\mathrm{Co}(\mathrm{en})_3\right]^{3+}<\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}<\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{2+}<\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4\right]^{2+}$
2
JEE Main 2025 (Online) 22nd January Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Identify the homoleptic complex(es) that is/are low spin.

(A) $\left[\mathrm{Fe}(\mathrm{CN})_5 \mathrm{NO}\right]^{2-}$

(B) $\left[\mathrm{CoF}_6\right]^{3-}$

(C) $\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{4-}$

(D) $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}$

(E) $\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}$

Choose the correct answer from the options given below :

A
(C) and (D) only
B
(C) only
C
(A) and (C) only
D
(B) and (E) only
3
JEE Main 2025 (Online) 22nd January Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

From the magnetic behaviour of $\left[\mathrm{NiCl}_4\right]^{2-}$ (paramagnetic) and $\left[\mathrm{Ni}(\mathrm{CO})_4\right]$ (diamagnetic), choose the correct geometry and oxidation state.

A
$\left[\mathrm{NiCl}_4\right]^{2-}: \mathrm{Ni}(0)$, tetrahedral $\left[\mathrm{Ni}(\mathrm{CO})_4\right]: \mathrm{Ni}(0)$, square planar
B
$\left[\mathrm{NiCl}_4\right]^{2-}: \mathrm{Ni}^{\mathrm{II}}$, tetrahedral $\left[\mathrm{Ni}(\mathrm{CO})_4\right]: \mathrm{Ni}(0)$, tetrahedral
C
$\left[\mathrm{NiCl}_4\right]^{2-}: \mathrm{Ni}^{\mathrm{II}}$, tetrahedral $\left[\mathrm{Ni}(\mathrm{CO})_4\right]: \mathrm{Ni}^{I I}$, square planar
D
$\left[\mathrm{NiCl}_4\right]^{2-}: \mathrm{Ni}^{\mathrm{II}}$, square planar $\left[\mathrm{Ni}(\mathrm{CO})_4\right]: \mathrm{Ni}(0)$, square planar
4
JEE Main 2025 (Online) 22nd January Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language
 

In which of the following complexes the CFSE, $\Delta_o$ will be equal to zero?

A
$\mathrm{K}_3\left[\mathrm{Fe}(\mathrm{SCN})_6\right]$
B
$\left[\mathrm{Fe}(\mathrm{en})_3\right] \mathrm{Cl}_3$
C
$\left[\mathrm{Fe}\left(\mathrm{NH}_3\right)_6\right] \mathrm{Br}_2$
D
$\mathrm{K}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]$
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