Given below are two statements :
Statement I : Due to increase in van der Waals forces, the order of boiling points is $\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CH}_2 \mathrm{I}>\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{I}>\mathrm{CH}_3 \mathrm{I}$.
$$ \text { Statement II : } $$
In the light of the above statements, choose the correct answer from the options given below :
Given below are two statements :
Statement I : 3-phenylpropene reacts with HBr and gives secondary alkyl bromide having a chiral carbon atom as the major product.
Statement II : Aryl chlorides and aryl cyanides can be prepared by Sandmeyer reaction as well as Gattermann reaction.
In the light of the above statements, choose the correct answer from the options given below
$$ \text { Match the LIST-I with LIST-II } $$
| $$ \begin{gathered} \text { List-I } \\ \text { Name of reaction } \end{gathered} $$ |
$$ \begin{gathered} \text { List-II } \\ \text { Reagent or catalyst used } \end{gathered} $$ |
||
|---|---|---|---|
| A. | Finkelstein reaction | I. | $\mathrm{SbF}_3$ |
| B. | Swarts reaction | II. | Na, dry ether |
| C. | Sandmeyer's reaction | III. | NaI |
| D. | Fittig reaction | IV. | $\mathrm{Cu}_2 \mathrm{Cl}_2$ |
Choose the correct answer from the options given below :
Correct statements regarding alkyl halides (R–X) among the following are :
A. Alcohol being less polar solvent as compared to water, alcoholic KOH favours elimination reaction with R–X.
B. Order of reactivity towards SN1 mechanism is C6H5–CH2–Cl > C6H5–CHCl–C6H5.
C. Non substituted aryl halides exhibit properties similar to alkyl halides.
D. Vinyl chloride is an example of haloalkene and allyl chloride is an example of haloalkyne.
E. R–Cl can be prepared by reacting R–OH with SOCl2 but Ar–Cl cannot be prepared by reacting Ar–OH with SOCl2.
Choose the correct answer from the options given below :
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