Match List I with List II
LIST I (Complex ion) |
LIST II (Spin only magnetic moment in B.M.) |
||
---|---|---|---|
A. | $$ \left[\mathrm{Cr}\left(\mathrm{NH}_3\right)_6\right]^{3+} $$ |
I. | 4.90 |
B. | $$ \left[\mathrm{NiCl}_4\right]^{2-} $$ |
II. | 3.87 |
C. | $$ \left[\mathrm{CoF}_6\right]^{3-} $$ |
III. | 0.0 |
D. | $$ \left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-} $$ |
IV. | 2.83 |
Choose the correct answer from the options given below :
Number of Complexes with even number of electrons in $$\mathrm{t_{2 g}}$$ orbitals is -
$$\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+},\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+},\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+},\left[\mathrm{Cu}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+},\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}$$
An octahedral complex with the formula $$\mathrm{CoCl}_3 \cdot \mathrm{nNH}_3$$ upon reaction with excess of $$\mathrm{AgNO}_3$$ solution gives 2 moles of $$\mathrm{AgCl}$$. Consider the oxidation state of $$\mathrm{Co}$$ in the complex is '$$x$$'. The value of "$$x+n$$" is __________.
Given below are two statements:
Statement I: $$\mathrm{N}\left(\mathrm{CH}_3\right)_3$$ and $$\mathrm{P}\left(\mathrm{CH}_3\right)_3$$ can act as ligands to form transition metal complexes.
Statement II: As N and P are from same group, the nature of bonding of $$\mathrm{N}\left(\mathrm{CH}_3\right)_3$$ and $$\mathrm{P}\left(\mathrm{CH}_3\right)_3$$ is always same with transition metals.
In the light of the above statements, choose the most appropriate answer from the options given below: