' $x$ ' is the product which is obtained from benzene by reacting it with carbon monoxide and hydrogen chloride in the presence of cuprous chloride. ' $y$ ' is the major product obtained from the benzene by reacting it with ethanoyl chloride in the presence of anhydrous $\mathrm{AlCl}_3$. Product (major) obtained by heating $x$ and $y$ in the presence of alkali is $z$. Total number of $\pi$ (pi) electrons in $z$ is $\_\_\_\_$ .

$$ \text { Consider the following sequence of reactions to give the major product }(\mathrm{X}) $$

P g of the major product $(\mathrm{X})$ formed is reacted with $\mathrm{NaHCO}_3$ solution to liberate a gas which occupied $11.2 \mathrm{dm}^3$ at STP.

$$ \mathrm{P}=\text {______________ g. } $$

(Given molar mass in $\mathrm{g} \mathrm{mol}^{-1} \mathrm{H}: 1, \mathrm{C}: 12, \mathrm{O}: 16, \mathrm{Cl}: 35.5$ )

Grignard reagent $\mathrm{RMgBr}(\mathrm{P})$ reacts with water and forms a gas $(\mathrm{Q})$. One gram of Q occupies $1.4 \mathrm{dm}^3$ at STP. (P) on reaction with dry ice in dry ether followed by $\mathrm{H}_3 \mathrm{O}^{+}$forms a compound (Z). 0.1 mole of (Z) will weigh $\_\_\_\_$ g. (Nearest integer)

Identify the structure of the final product (D) in the following sequence of the reactions :

Total number of $\mathrm{sp}^2$ hybridised carbon atoms in product D is ____________.