Number of paramagnetic ions among the following d- and f-block metal ions is __________.
Mn2+, Cu2+, Zn2+, Yb2+, Sc3+, La3+, Gd3+, Lu3+, Ti4+, Ce4+
(Atomic number of Mn = 25, Cu = 29, Zn = 30, Yb = 70, Sc = 21, La = 57, Gd = 64, Lu = 71, Ti = 22, Ce = 58)
Among the following oxides of $3 d$ elements, the number of mixed oxides are $\_\_\_\_$ .
$$ \mathrm{Ti}_2 \mathrm{O}_3, \mathrm{~V}_2 \mathrm{O}_4, \mathrm{Cr}_2 \mathrm{O}_3, \mathrm{Mn}_3 \mathrm{O}_4, \mathrm{Fe}_3 \mathrm{O}_4, \mathrm{Fe}_2 \mathrm{O}_3, \mathrm{Co}_3 \mathrm{O}_4 $$
Consider the following reactions :
$$ \begin{aligned} & \mathrm{NaCl}+\mathrm{K}_2 \mathrm{Cr}_2 \mathrm{O}_7+\mathrm{H}_2 \mathrm{SO}_4 \rightarrow \mathrm{~A}+\mathrm{KHSO}_4+\mathrm{NaHSO}_4+\mathrm{H}_2 \mathrm{O} \\ & \mathrm{~A}+\mathrm{NaOH} \rightarrow \mathrm{~B}+\mathrm{NaCl}+\mathrm{H}_2 \mathrm{O} \\ & \mathrm{~B}+\mathrm{H}_2 \mathrm{SO}_4+\mathrm{H}_2 \mathrm{O}_2 \rightarrow \mathrm{C}+\mathrm{Na}_2 \mathrm{SO}_4+\mathrm{H}_2 \mathrm{O} \end{aligned} $$
In the product ' $C^{\prime}$, ' $X$ ' is the number of $O_2^{2-}$ units, ' $Y$ ' is the total number oxygen atoms present and ' $Z$ ' is the oxidation state of $C r$. The value of $X+Y+Z$ is $\_\_\_\_$ .
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