1
JEE Main 2026 (Online) 22nd January Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

$\left[\mathrm{Ni}\left(\mathrm{PPh}_3\right)_2 \mathrm{Cl}_2\right]$ is a paramagnetic complex. Identify the INCORRECT statements about this complex.

A. The complex exhibits geometrical isomerism.

B. The complex is white in colour.

C. The calculated spin-only magnetic moment of the complex is 2.84 BM .

D. The calculated CFSE (Crystal Field Stabilization Energy) of Ni in this complex is $-0.8 \Delta_{\mathrm{o}}$.

E. The geometrical arrangement of ligands in this complex is similar to that in $\mathrm{Ni}(\mathrm{CO})_4$.

Choose the correct answer from the options given below :

A

C and D Only

B

A, B and D Only

C

C, D and E Only

D

A and B Only

2
JEE Main 2026 (Online) 22nd January Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Consider the transition metal ions $\mathrm{Mn}^{3+}, \mathrm{Cr}^{3+}, \mathrm{Fe}^{3+}$ and $\mathrm{Co}^{3+}$ and all form low spin octahedral complexes. The correct decreasing order of unpaired electrons in their respective d-orbitals of the complexes is

A

$\mathrm{Cr}^{3+}>\mathrm{Mn}^{3+}>\mathrm{Fe}^{3+}>\mathrm{Co}^{3+}$

B

$\mathrm{Mn}^{3+}>\mathrm{Fe}^{3+}>\mathrm{Co}^{3+}>\mathrm{Cr}^{3+}$

C

$\mathrm{Fe}^{3+}>\mathrm{Co}^{3+}>\mathrm{Mn}^{3+}>\mathrm{Cr}^{3+}$

D

$\mathrm{Cr}^{3+}>\mathrm{Fe}^{3+}>\mathrm{Co}^{3+}>\mathrm{Mn}^{3+}$

3
JEE Main 2026 (Online) 22nd January Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

A first row transition metal $(\mathrm{M})$ does not liberate $\mathrm{H}_2$ gas from dilute HCl .1 mol of aqueous solution of $\mathrm{MSO}_4$ is treated with excess of aqueous KCN and then $\mathrm{H}_2 \mathrm{~S}(\mathrm{~g})$ is passed through the solution. The amount of MS (metal sulphide) formed from the above reaction is $\_\_\_\_$ mol.

A

1

B

2

C

0

D

3

4
JEE Main 2026 (Online) 21st January Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Given below are two statements :

Statement I : Crystal Field Stabilization Energy (CFSE) of [Cr(H2O)6]2+ is greater than that of [Mn(H2O)6]2+.

Statement II : Potassium ferricyanide has a greater spin-only magnetic moment than sodium ferrocyanide.

In the light of the above statements, choose the correct answer from the options given below :

A

Statement I is true but Statement II is false

B

Both Statement I and Statement II are true

C

Both Statement I and Statement II are false

D

Statement I is false but Statement II is true

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