Which one of the following, with HBr will give a phenol?

Given below are two statements :

Statement I :

Statement II : In , intramolecular substitution takes place first by involving lone pair of electrons on nitrogen.

In the light of the above statements, choose the most appropriate answer from the options given below

Given below are two statements :

Statement (I) : The boiling points of alcohols and phenols increase with increase in the number of C -atoms.

Statement (II) : The boiling points of alcohols and phenols are higher in comparison to other class of compounds such as ethers, haloalkanes.

In the light of the above statements, choose the correct answer from the options given below :

What amount of bromine will be required to convert 2 g of phenol into 2,4,6-tribromophenol?

(Given molar mass in $\mathrm{g} \mathrm{mol}^{-1}$ of $\mathrm{C}, \mathrm{H}, \mathrm{O}, \mathrm{Br}$ are $12,1,16,80$ respectively )