p-Block Elements · Chemistry · JEE Main

The correct statements from the following are :

(A) Tl³⁺ is a powerful oxidising agent

(B) Al³⁺ does not get reduced easily

(C) Both Al³⁺ and Tl³⁺ are very stable in solution

(D) Tl¹⁺ is more stable than Tl³⁺

(E) Al³⁺ and Tl¹⁺ are highly stable

Choose the correct answer from the options given below :

Given below are two statements :

Statement (I) : The first ionisation enthalpy of group 14 elements is higher than the corresponding elements of group 13.

Statement (II) : Melting points and boiling points of group 13 elements are in general much higher than those of corresponding elements of group 14.

In the light of the above statements, choose the most appropriate answer from the options given below :

Given below are two statements:

Statement I: Nitrogen forms oxides with +1 to +5 oxidation states due to the formation of $\mathrm{p} \pi-\mathrm{p} \pi$ bond with oxygen.

Statement II: Nitrogen does not form halides with +5 oxidation state due to the absence of d-orbital in it.

In the light of given statements, choose the correct answer from the options given below.

Given below are the pairs of group 13 elements showing their relation in terms of atomic radius. $(\mathrm{B}<\mathrm{Al}),(\mathrm{Al}<\mathrm{Ga}),(\mathrm{Ga}<\mathrm{In})$ and $(\mathrm{In}<\mathrm{Tl})$ Identify the elements present in the incorrect pair and in that pair find out the element (X) that has higher ionic radius $\left(\mathrm{M}^{3+}\right)$ than the other one. The atomic number of the element $(\mathrm{X})$ is

Given below are two statements :

Statement I : The N - N single bond is weaker and longer than that of P - P single bond.

Statement II : Compounds of group 15 elements in +3 oxidation states readily undergo disproportionation reactions.

In the light of the above statements, choose the correct answer from the options given below

The large difference between the melting and boiling points of oxygen and sulphur may be explained on the basis of

The incorrect statement among the following is

The maximum covalency of a non-metallic group 15 element ' E ' with weakest $\mathrm{E}-\mathrm{E}$ bond is :

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : Both rhombic and monoclinic sulphur exist as $$\mathrm{S}_8$$ while oxygen exists as $$\mathrm{O}_2$$.

Reason (R) : Oxygen forms $$p \pi-p \pi$$ multiple bonds with itself and other elements having small size and high electronegativity like $$\mathrm{C}, \mathrm{N}$$, which is not possible for sulphur.

In the light of the above statements, choose the most appropriate answer from the options given below :

On reaction of Lead Sulphide with dilute nitric acid which of the following is not formed?

Identify the correct statements about p-block elements and their compounds.

(A) Non metals have higher electronegativity than metals.

(B) Non metals have lower ionisation enthalpy than metals.

(C) Compounds formed between highly reactive nonmetals and highly reactive metals are generally ionic.

(D) The non-metal oxides are generally basic in nature.

(E) The metal oxides are generally acidic or neutral in nature.

Choose the correct answer from the options given below :

Identify the incorrect statements about group 15 elements :

(A) Dinitrogen is a diatomic gas which acts like an inert gas at room temperature.

(B) The common oxidation states of these elements are $$-3,+3$$ and +5.

(C) Nitrogen has unique ability to form $$\mathrm{p} \pi-\mathrm{p} \pi$$ multiple bonds.

(D) The stability of +5 oxidation states increases down the group.

(E) Nitrogen shows a maximum covalency of 6.

Choose the correct answer from the options given below :

In qualitative test for identification of presence of phosphorous, the compound is heated with an oxidising agent. Which is further treated with nitric acid and ammonium molybdate respectively. The yellow coloured precipitate obtained is :

Give below are two statements: One is labelled as Assertion A and the other is labelled as Reason R:

Assertion A: The stability order of +1 oxidation state of $$\mathrm{Ga}$$, In and $$\mathrm{Tl}$$ is Ga < In < Tl.

Reason R: The inert pair effect stabilizes the lower oxidation state down the group.

In the light of the above statements, choose the correct answer from the options given below:

Among the following halogens

$$\mathrm{F}_2, \mathrm{Cl}_2, \mathrm{Br}_2 \text { and } \mathrm{I}_2$$

Which can undergo disproportionation reactions?

Evaluate the following statements related to group 14 elements for their correctness.

(A) Covalent radius decreases down the group from $$\mathrm{C}$$ to $$\mathrm{Pb}$$ in a regular manner.

(B) Electronegativity decreases from $$\mathrm{C}$$ to $$\mathrm{Pb}$$ down the group gradually.

(C) Maximum covalance of $$\mathrm{C}$$ is 4 whereas other elements can expand their covalance due to presence of d orbitals.

(D) Heavier elements do not form $$\mathrm{p} \pi-\mathrm{p} \pi$$ bonds.

(E) Carbon can exhibit negative oxidation states.

Choose the correct answer from the options given below :

Given below are two statements :

Statement I : Gallium is used in the manufacturing of thermometers.

Statement II : A thermometer containing gallium is useful for measuring the freezing point $$(256 \mathrm{~K})$$ of brine solution.

In the light of the above statements, choose the correct answer from the options given below :

Which of the following material is not a semiconductor.

The correct statements from the following are :

(A) The decreasing order of atomic radii of group 13 elements is $$\mathrm{Tl}>\mathrm{In}>\mathrm{Ga}>\mathrm{Al}>\mathrm{B}$$.

(B) Down the group 13 electronegativity decreases from top to bottom.

(C) $$\mathrm{Al}$$ dissolves in dil. $$\mathrm{HCl}$$ and liberates $$\mathrm{H}_2$$ but conc. $$\mathrm{HNO}_3$$ renders $$\mathrm{Al}$$ passive by forming a protective oxide layer on the surface.

(D) All elements of group 13 exhibits highly stable +1 oxidation state.

(E) Hybridisation of $$\mathrm{Al}$$ in $$[\mathrm{Al}(\mathrm{H}_2 \mathrm{O})_6]^{3+}$$ ion is $$\mathrm{sp}^3 \mathrm{d}^2$$.

Choose the correct answer from the options given below :

The number of neutrons present in the more abundant isotope of boron is '$$x$$'. Amorphous boron upon heating with air forms a product, in which the oxidation state of boron is '$$y$$'. The value of $$x+y$$ is _________ .

Given below are two statements:

Statement I : Group 13 trivalent halides get easily hydrolyzed by water due to their covalent nature.

Statement II : $$\mathrm{AlCl}_3$$ upon hydrolysis in acidified aqueous solution forms octahedral $$\left[\mathrm{Al}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}$$ ion.

In the light of the above statements, choose the correct answer from the options given below :

Given below are two statements:

Statement I : $$\mathrm{S}_8$$ solid undergoes disproportionation reaction under alkaline conditions to form $$\mathrm{S}^{2-}$$ and $$\mathrm{S}_2 \mathrm{O}_3{ }^{2-}$$.

Statement II : $$\mathrm{ClO}_4^{-}$$ can undergo disproportionation reaction under acidic condition.

In the light of the above statements, choose the most appropriate answer from the options given below :

Choose the correct statements from the following

A. All group 16 elements form oxides of general formula $$\mathrm{EO}_2$$ and $$\mathrm{EO}_3$$, where $$\mathrm{E}=\mathrm{S}, \mathrm{Se}, \mathrm{Te}$$ and $$\mathrm{Po}$$. Both the types of oxides are acidic in nature.

B. $$\mathrm{TeO}_2$$ is an oxidising agent while $$\mathrm{SO}_2$$ is reducing in nature.

C. The reducing property decreases from $$\mathrm{H}_2 \mathrm{~S}$$ to $$\mathrm{H}_2$$ Te down the group.

D. The ozone molecule contains five lone pairs of electrons.

Choose the correct answer from the options given below:

Consider the oxides of group 14 elements $$\mathrm{SiO}_2, \mathrm{GeO}_2, \mathrm{SnO}_2, \mathrm{PbO}_2, \mathrm{CO}$$ and $$\mathrm{GeO}$$. The amphoteric oxides are

The compound that is white in color is

Give below are two statements:

Statement - I: Noble gases have very high boiling points.

Statement - II: Noble gases are monoatomic gases. They are held together by strong dispersion forces. Because of this they are liquefied at very low temperature. Hence, they have very high boiling points.

In the light of the above statements, choose the correct answer from the options given below:

A and B formed in the following reactions are:

$$\begin{aligned} & \mathrm{CrO}_2 \mathrm{Cl}_2+4 \mathrm{NaOH} \rightarrow \mathrm{A}+2 \mathrm{NaCl}+2 \mathrm{H}_2 \mathrm{O}, \\ & \mathrm{A}+2 \mathrm{HCl}+2 \mathrm{H}_2 \mathrm{O}_2 \rightarrow \mathrm{B}+3 \mathrm{H}_2 \mathrm{O} \end{aligned}$$

Choose the correct statements about the hydrides of group 15 elements.

A. The stability of the hydrides decreases in the order $$\mathrm{NH}_3>\mathrm{PH}_3>\mathrm{AsH}_3> \mathrm{SbH}_3>\mathrm{BiH}_3$$.

B. The reducing ability of the hydride increases in the order $$\mathrm{NH}_3<\mathrm{PH}_3<\mathrm{AsH}_3 <\mathrm{SbH}_3<\mathrm{BiH}_3$$.

C. Among the hydrides, $$\mathrm{NH}_3$$ is strong reducing agent while $$\mathrm{BiH}_3$$ is mild reducing agent.

D. The basicity of the hydrides increases in the order $$\mathrm{NH}_3<\mathrm{PH}_3<\mathrm{AsH}_3< \mathrm{SbH}_3<\mathrm{BiH}_3$$.

Choose the most appropriate from the options given below :

Given below are two statements :

Statement (I) : The gas liberated on warming a salt with dil $$\mathrm{H}_2 \mathrm{SO}_4$$, turns a piece of paper dipped in lead acetate into black, it is a confirmatory test for sulphide ion.

Statement (II) : In statement-I the colour of paper turns black because of formation of lead sulphite. In the light of the above statements, choose the most appropriate answer from the options given below :

The Lassiagne's extract is boiled with dil $$\mathrm{HNO}_3$$ before testing for halogens because,

On passing a gas, '$$\mathrm{X}$$', through Nessler's regent, a brown precipitate is obtained. The gas '$$\mathrm{X}$$' is

Identify the incorrect pair from the following :

Given below are two statements :

Statement (I) : Oxygen being the first member of group 16 exhibits only -2 oxidation state.

Statement (II) : Down the group 16 stability of +4 oxidation state decreases and +6 oxidation state increases.

In the light of the above statements, choose the most appropriate answer from the options given below :

Element not showing variable oxidation state is :

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : Melting point of Boron (2453 K) is unusually high in group 13 elements.

Reason (R) : Solid Boron has very strong crystalline lattice.

In the light of the above statements, choose the most appropriate answer from the options given below ;

The correct group of halide ions which can be oxidised by oxygen in acidic medium is :

The covalency and oxidation state respectively of boron in $$\left[\mathrm{BF}_{4}\right]^{-}$$, are :

The incorrect statement from the following for borazine is :

Given below are two statements :

Statement I : Boron is extremely hard indicating its high lattice energy.

Statement II : Boron has highest melting and boiling point compared to its other group members.

In the light of the above statements, choose the most appropriate answer from the options given below :

Given below are two statements :

Statement I : $$\mathrm{SbCl}_{5}$$ is more covalent than $$\mathrm{SbCl}_{3}$$

Statement II: The higher oxides of halogens also tend to be more stable than the lower ones.

In the light of the above statements, choose the most appropriate answer from the options given below :

Which one of the following pairs is an example of polar molecular solids?

One mole of $$\mathrm{P}_{4}$$ reacts with 8 moles of $$\mathrm{SOCl}_{2}$$ to give 4 moles of $$\mathrm{A}, x$$ mole of $$\mathrm{SO}_{2}$$ and 2 moles of $$\mathrm{B} . \mathrm{A}, \mathrm{B}$$ and $$x$$ respectively are :

For compound having the formula $$\mathrm{GaAlCl}_{4}$$, the correct option from the following is :

Match List I with List II

Choose the correct answer from the options given below:

The correct order of bond enthalpy ($$\mathrm{kJ~mol^{-1}}$$) is :

For electron gain enthalpies of the elements denoted as $$\Delta_{\mathrm{eg}} \mathrm{H}$$, the incorrect option is :

Given below are two statements:

Statement I : Chlorine can easily combine with oxygen to form oxides; and the product has a tendency to explode.

Statement II : Chemical reactivity of an element can be determined by its reaction with oxygen and halogens.

In the light of the above statements, choose the correct answer from the options given below :

During the borax bead test with $$\mathrm{CuSO_4}$$, a blue green colour of the bead was observed in oxidising flame due to the formation of :

"A" obtained by Ostwald's method involving air oxidation of NH$$_3$$, upon further air oxidation produces "B", "B" on hydration forms an oxoacid of Nitrogen along with evolution of "A". The oxoacid also produces "A" and gives positive brown ring test.

Identify A and B, respectively :

Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R

Assertion A : Carbon forms two important oxides - CO and CO$$_2$$. CO is neutral whereas CO$$_2$$ is acidic in nature

Reason R : CO$$_2$$ can combine with water in a limited way to form carbonic acid, while CO is sparingly soluble in water

In the light of the above statements, choose the most appropriate answer from the options given below :

A. Ammonium salts produce haze in atmosphere.

B. Ozone gets produced when atmospheric oxygen reacts with chlorine radicals.

C. Polychlorinated biphenyls act as cleansing solvents.

D. 'Blue baby' syndrome occurs due to the presence of excess of sulphate ions in water.

Choose the correct answer from the options given below :

Potassium dichromate acts as a strong oxidizing agent in acidic solution. During this process, the oxidation state changes from :

Reaction of thionyl chloride with white phosphorus forms a compound [A], which on hydrolysis gives [B], a dibasic acid. [A] and [B] are respectively :

Compound A reacts with NH$$_4$$Cl and forms a compound B. Compound B reacts with H$$_2$$O and excess of CO$$_2$$ to form compound C which on passing through or reaction with saturated NaCl solution forms sodium hydrogen carbonate. Compound A, B and C, are respectively :

$$\mathrm{K_2Cr_2O_7}$$ paper acidified with dilute $$\mathrm{H_2SO_4}$$ turns green when exposed to :

Which of the Phosphorus oxoacid can create silver mirror from $$\mathrm{AgNO_3}$$ solution?

In liquation process used for tin (Sn), the metal :

Given below are two statements.

Statement I : Stannane is an example of a molecular hydride.

Statement II : Stannane is a planar molecule.

In the light of the above statement, choose the most appropriate answer from the options given below.

When borax is heated with $$\mathrm{CoO}$$ on a platinum loop, blue coloured bead formed is largely due to :

Dinitrogen is a robust compound, but reacts at high altitudes to form oxides. The oxide of nitrogen that can damage plant leaves and retard photosynthesis is :

White phosphorus reacts with thionyl chloride to give :

Concentrated $$\mathrm{HNO}_{3}$$ reacts with Iodine to give :

Dinitrogen and dioxygen, the main constituents of air do not react with each other in atmosphere to form oxides of nitrogen because :

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : Boron is unable to form $$\mathrm{BF}_{6}^{3-}$$.

Reason (R) : Size of B is very small.

In the light of the above statements, choose the correct answer from the options given below :

Given below are two statements. One is labelled as Assertion A and the other is labelled as Reason R.

Assertion A : Activated charcoal adsorbs SO₂ more efficiently than CH₄.

Reason R : Gases with lower critical temperatures are readily adsorbed by activated charcoal.

In the light of the above statements, choose the correct answer from the options given below.

Given below are two statements.

Statement I: The chlorides of $$\mathrm{Be}$$ and $$\mathrm{Al}$$ have Cl-bridged structure. Both are soluble in organic solvents and act as Lewis bases.

Statement II: Hydroxides of $$\mathrm{Be}$$ and $$\mathrm{Al}$$ dissolve in excess alkali to give beryllate and aluminate ions.

In the light of the above statements, choose the correct answer from the options given below.

Which oxoacid of phosphorous has the highest number of oxygen atoms present in its chemical formula?

Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R.

Assertion : Boric acid is a weak acid.

Reason R : Boric acid is not able to release $$\mathrm{H}^{+}$$ ion on its own. It receives $$\mathrm{OH}^{-}$$ ion from water and releases $$\mathrm{H}^{+}$$ ion.

In the light of the above statements, choose the most appropriate answer from the options given below.

Match List - I with List - II.

Choose the correct answer from the options given below :

Borazine, also known as inorganic benzene, can be prepared by the reaction of 3-equivalents of "$$X$$" with 6-equivalents of "$$Y$$". "$$X$$" and "$$Y$$", respectively are :

The total number of acidic oxides from the following list is

NO, N₂O, B₂O₃, N₂O₅, CO, SO₃, P₄O₁₀

Match List I with List II:

Choose the correct answer from the options given below :

Match List I with List II

Choose the correct answer from the options given below :

The geometry around boron in the product 'B' formed from the following reaction is

$$ \begin{aligned} &\mathrm{BF}_{3}+\mathrm{NaH} \stackrel{450 \mathrm{~K}}{\rightarrow} \mathrm{A}+\mathrm{NaF} \\\\ &\mathrm{A}+\mathrm{NMe}_{3} \rightarrow \mathrm{B} \end{aligned} $$

The interhalogen compound formed from the reaction of bromine with excess of fluorine is a :

A $$\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{}^{573\,K}} $$ Red phosphorus $$\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{under\,pressure}^{heat\,;\,803\,K}} $$ B

Red phosphorus is obtained by heating "A" at 573 K, and can be converted to "B" by heating at 803 K under pressure.

A and B, respectively, are

Aqueous solution of which of the following boron compounds will be strongly basic in nature?

Sulphur dioxide is one of the components of polluted air. SO₂ is also a major contributor to acid rain. The correct and complete reaction to represent acid rain caused by SO₂ is :

Match List-I with List-II.

Choose the most appropriate answer from the options given below :

The oxoacid of phosphorus that is easily obtained from a reaction of alkali and white phosphorus and has two P-H bonds, is :

Among the given oxides of nitrogen ; N₂O, N₂O₃, N₂O₄ and N₂O₅, the number of compound/(s) having N - N bond is :

Which of the following oxoacids of sulphur contains "S" in two different oxidation states?

Nitrogen gas is obtained by thermal decomposition of :

Given below are two statements :

Statement I : The pentavalent oxide of group-15 element, E₂O₅, is less acidic than trivalent oxide, E₂O₃, of the same element.

Statement II : The acidic character of trivalent oxide of group 15 elements, E₂O₃, decreases down the group.

In light of the above statements, choose most appropriate answer from the options given below :

The gas produced by treating an aqueous solution of ammonium chloride with sodium nitrite is :

Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R.

Assertion A : Fluorine forms one oxoacid.

Reason R : Fluorine has smallest size amongst all halogens and is highly electronegative.

In the light of the above statements, choose the most appropriate answer from the options given below :

Match List I with List II.

Choose the correct answer from the options given below :

Match List - I with List - II.

Choose the correct answer from the options given below :

Heating white phosphorus with conc. NaOH solution gives mainly :

Which of the following elements is considered as a metalloid?

The oxide which contains an odd electron at the nitrogen atom is :

Choose the correct stability order of group 13 elements in their + 1 oxidation state :

The correct order of melting points of hydrides of group 16 elements is :

Consider the following reaction :

A + alkali $$\to$$ B (Major Product)

If B is an oxoacid of phosphorus with no P-H bond, then A is :

The number of bridged oxygen atoms present in compound B formed from the following reactions is

Pb(NO₃)₂ $$\buildrel {673\,K} \over \longrightarrow $$ A + PbO + O₂

A $$\buildrel {Dimerise} \over \longrightarrow $$ B

White precipitate of AgCl dissolves in aqueous ammonia solution due to formation of :

Identify the correct statement for B₂H₆ from those given below :

(A) In B₂H₆, all B-H bonds are equivalent.

(B) In B₂H₆, there are four 3-centre-2-electron bonds.

(C) B₂H₆ is a Lewis acid.

(D) B₂H₆ can be synthesized from both BF₃ and NaBH₄.

(E) B₂H₆ is a planar molecule.

Choose the most appropriate answer from the options given below :

The most stable trihalide of nitrogen is :

Which one of the following elemental forms is not present in the enamel of the teeth?

A group 15 element forms $\mathrm{d} \pi-\mathrm{d} \pi$ bond with transition metals. It also forms hydride, which is a strongest base among the hydrides of other group members that form $d \pi-d \pi$ bond.

The atomic number of the element is _______ .

Number of oxygen atoms present in chemical formula of fuming sulphuric acid is ___________.

1 mole of $$\mathrm{PbS}$$ is oxidised by "$$\mathrm{X}$$" moles of $$\mathrm{O}_3$$ to get "$$\mathrm{Y}$$" moles of $$\mathrm{O}_2$$. $$\mathrm{X}+\mathrm{Y}=$$ _________.

From the given list, the number of compounds with +4 oxidation state of Sulphur ________.

$$\mathrm{SO}_3, \mathrm{H}_2 \mathrm{SO}_3, \mathrm{SOCl}_2, \mathrm{SF}_4, \mathrm{BaSO}_4, \mathrm{H}_2 \mathrm{S}_2 \mathrm{O}_7 $$

If the formula of Borax is $$\mathrm{Na_2B_4O_x(OH)_y~.~zH_2O}$$, then $$x+y+z=$$ ___________

The difference in the oxidation state of $$\mathrm{Xe}$$ between the oxidised product of $$\mathrm{Xe}$$ formed on complete hydrolysis of $$\mathrm{XeF}_{4}$$ is ___________

In the following reactions, the total number of oxygen atoms in X and Y is ___________.

Na$$_2$$O + H$$_2$$O $$\to$$ 2X

Cl$$_2$$O$$_7$$ + H$$_2$$O $$\to$$ 2Y

The ratio of sigma and $$\pi$$ bonds present in pyrophosphoric acid is ___________.

$$\mathrm{XeF}_{4}$$ reacts with $$\mathrm{SbF}_{5}$$ to form

$$[\mathrm{XeF}_{m}]^{\mathrm{n}+}\left[\mathrm{SbF}_{y}\right]^{z-}$$.

$$\mathrm{m}+\mathrm{n}+\mathrm{y}+\mathrm{z}=$$ __________

Sum of $$\pi$$-bonds present in peroxodisulphuric acid and pyrosulphuric acid is ___________

Consider the following sulphur based oxoacids.

$$\mathrm{H}_{2} \mathrm{SO}_{3}, \mathrm{H}_{2} \mathrm{SO}_{4}, \mathrm{H}_{2} \mathrm{S}_{2} \mathrm{O}_{8}$$ and $$\mathrm{H}_{2}\mathrm{S}_{2} \mathrm{O}_{7}$$.

Amongst these oxoacids, the number of those with peroxo $$(\mathrm{O}-\mathrm{O})$$ bond is ________.

The number of non-ionisable protons present in the product B obtained from the following reactions is ___________.

$$ \mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}+\mathrm{PCl}_{3} \rightarrow \mathrm{C}_{2} {\mathrm{H}_{5} \mathrm{Cl}+\mathrm{A}} $$

$$\mathrm{A}\,{+}\, \mathrm{PCl}_{3} \rightarrow \mathrm{B}$$

Consider the following reactions:

PCl₃ + H₂O $$\to$$ A + HCl

A + H₂O $$\to$$ B + HCl

The number of ionisable protons present in the product B is _______________.