Periodic Table & Periodicity · Chemistry · JEE Main
MCQ (Single Correct Answer)
The type of oxide formed by the element among Li, Na, Be, Mg, B and Al that has the least atomic radius is :
First ionisation enthalpy values of first four group 15 elements are given below. Choose the correct value for the element that is a main component of apatite family :
An element ‘E’ has the ionisation enthalpy value of 374 kJ mol⁻¹. ‘E’ reacts with elements A, B, C and D with electron gain enthalpy values of −328, −349, −325 and −295 kJ mol⁻¹, respectively. The correct order of the products EA, EB, EC and ED in terms of ionic character is :
Given below are two statements :
Statement (I) : The radii of isoelectronic species increases in the order.
Mg²⁺ < Na⁺ < F⁻ < O²⁻
Statement (II) : The magnitude of electron gain enthalpy of halogen decreases in the order.
Cl > F > Br > I
In the light of the above statements, choose the most appropriate answer from the options given below :
Given below are two statements :
Statement I : According to the Law of Octaves, the elements were arranged in the increasing order of their atomic number.
Statement II : Meyer observed a periodically repeated pattern upon plotting physical properties of certain elements against their respective atomic numbers.
In the light of the above statements, choose the correct answer from the options given below :
The incorrect decreasing order of atomic radii is
Consider the following elements $\mathrm{In}, \mathrm{Tl}, \mathrm{Al}, \mathrm{Pb}, \mathrm{Sn}$ and Ge . The most stable oxidation states of elements with highest and lowest first ionisation enthalpies, respectively, are
The successive 5 ionisation energies of an element are $800,2427,3658,25024$ and $32824 \mathrm{~kJ} / \mathrm{mol}$, respectively. By using the above values predict the group in which the above element is present :
Given below are two statements :
Statement (I) : The first ionization energy of Pb is greater than that of Sn .
Statement (II) : The first ionization energy of Ge is greater than that of Si .
In the light of the above statements, choose the correct answer from the options given below :
Which of the following statements are NOT true about the periodic table?
A. The properties of elements are function of atomic weights.
B. The properties of elements are function of atomic numbers.
C. Elements having similar outer electronic configurations are arranged in same period.
D. An element's location reflects the quantum numbers of the last filled orbital.
E. The number of elements in a period is same as the number of atomic orbitals available in energy level that is being filled.
Choose the correct answer from the options given below:
Given below are the atomic numbers of some group 14 elements. The atomic number of the element with lowest melting point is :
The element that does not belong to the same period of the remaining elements (modern periodic table) is:
Given below are two statements :
Statement (I) : An element in the extreme left of the periodic table forms acidic oxides.
Statement (II) : Acid is formed during the reaction between water and oxide of a reactive element present in the extreme right of the periodic table.
In the light of the above statements, choose the correct answer from the options given below :
Match List-I with List-II.
List - I | List - II | ||
---|---|---|---|
(A) | $\mathrm{Al}^{3+}<\mathrm{Mg}^{2+}<\mathrm{Na}^{+}<\mathrm{F}^{-}$ | (I) | Ionisation Enthalpy |
(B) | $\mathrm{B}<\mathrm{C}<\mathrm{O}<\mathrm{N}$ | (II) | Metallic character |
(C) | $\mathrm{B}<\mathrm{Al}<\mathrm{Mg}<\mathrm{K}$ | (III) | Electronegativity |
(D) | $\mathrm{Si}<\mathrm{P}<\mathrm{S}<\mathrm{Cl}$ | (IV) | Ionic radii |
Choose the correct answer from the options given below :
Which of the following electronegativity order is incorrect?
Match List I with List II
LIST I (Element) |
LIST II (Electronic Configuration) |
||
---|---|---|---|
A. | $$\mathrm{N}$$ | I. | $$[\mathrm{Ar}] 3 \mathrm{~d}^{10} 4 \mathrm{~s}^2 4 \mathrm{p}^5$$ |
B. | $$\mathrm{S}$$ | II. | $$[\mathrm{Ne}] 3 \mathrm{~s}^2 3 \mathrm{p}^4$$ |
C. | $$\mathrm{Br}$$ | III. | $$[\mathrm{He}] 2 \mathrm{~s}^2 2 \mathrm{p}^3$$ |
D. | $$\mathrm{Kr}$$ | IV. | $$[\mathrm{Ar}] 3 \mathrm{~d}^{10} 4 \mathrm{~s}^2 4 \mathrm{p}^6$$ |
Choose the correct answer from the options given below:
Match List I with List II
LIST I | LIST II | ||
---|---|---|---|
A. | Melting Point $$[\mathrm{K}]$$ | I. | $$\mathrm{T} 1>\mathrm{In}>\mathrm{Ga}>\mathrm{A} 1>\mathrm{B}$$ |
B. | Ionic Radius $$[\mathrm{M}^{+3} / \mathrm{pm}]$$ | II. | $$\mathrm{B}>\mathrm{T} 1>\mathrm{Al} \approx \mathrm{Ga}>\mathrm{In}$$ |
C. | $$\Delta_{\mathrm{i}} \mathrm{H}_1[\mathrm{~kJ} \mathrm{~mol}^{-1}]$$ | III. | $$\mathrm{T} 1>\mathrm{In}>\mathrm{Al}>\mathrm{Ga}>\mathrm{B}$$ |
D. | Atomic Radius [pm] | IV. | $$\mathrm{B}>\mathrm{A} 1>\mathrm{T} 1>\mathrm{In}>\mathrm{Ga}$$ |
Choose the correct answer from the options given below:
Given below are two statements :
Statement (I) : The oxidation state of an element in a particular compound is the charge acquired by its atom on the basis of electron gain enthalpy consideration from other atoms in the molecule.
Statement (II) : $$\mathrm{p} \pi-\mathrm{p} \pi$$ bond formation is more prevalent in second period elements over other periods.
In the light of the above statements, choose the most appropriate answer from the options given below :
LIST I (Elements) |
LIST II (Properties in their respective groups) |
||
---|---|---|---|
A. | $$\mathrm{Cl,S}$$ | I. | Elements with highest electronegativity |
B. | $$\mathrm{Ge,As}$$ | II. | Elements with largest atomic size |
C. | $$\mathrm{Fr,Ra}$$ | III. | Elements which show properties of both metals and non-metal |
D. | $$\mathrm{F,O}$$ | IV. | Elements with highest negative electron gain enthalpy |
Choose the correct answer from the options given below:
The electron affinity value are negative for
A. $$\mathrm{Be} \rightarrow \mathrm{Be}^{-}$$
B. $$\mathrm{N} \rightarrow \mathrm{N}^{-}$$
C. $$\mathrm{O} \rightarrow \mathrm{O}^{2-}$$
D. $$\mathrm{Na} \rightarrow \mathrm{Na}^{-}$$
E. $$\mathrm{Al} \rightarrow \mathrm{Al}^{-}$$
Choose the most appropriate answer from the options given below :
Given below are two statements :
Statement I : The metallic radius of $$\mathrm{Na}$$ is $$1.86 \mathrm{~A}^{\circ}$$ and the ionic radius of $$\mathrm{Na}^{+}$$ is lesser than $$1.86 \mathrm{~A}^{\circ}$$
Statement II : Ions are always smaller in size than the corresponding elements.
In the light of the above statements, choose the correct answer from the options given below :
Given below are two statements:
Statement I: In group 13, the stability of +1 oxidation state increases down the group.
Statement II : The atomic size of gallium is greater than that of aluminium.
In the light of the above statements, choose the most appropriate answer from the options given below :
The statement(s) that are correct about the species $$\mathrm{O}^{2-}, \mathrm{F}^{-}, \mathrm{Na}^{+}$$ and $$\mathrm{Mg}^{2+}$$.
(A) All are isoelectronic
(B) All have the same nuclear charge
(C) $$\mathrm{O}^{2-}$$ has the largest ionic radii
(D) $$\mathrm{Mg}^{2+}$$ has the smallest ionic radii
Choose the most appropriate answer from the options given below :
The correct order of the first ionization enthalpy is
Given below are two statements :
Statement I : The correct order of first ionization enthalpy values of $$\mathrm{Li}, \mathrm{Na}, \mathrm{F}$$ and $$\mathrm{Cl}$$ is $$\mathrm{Na}<\mathrm{Li}<\mathrm{Cl}<\mathrm{F}$$.
Statement II : The correct order of negative electron gain enthalpy values of $$\mathrm{Li}, \mathrm{Na}, \mathrm{F}$$ and $$\mathrm{Cl}$$ is $$\mathrm{Na}<\mathrm{Li}<\mathrm{F}<\mathrm{Cl}$$
In the light of the above statements, choose the correct answer from the options given below :
The correct order of first ionization enthalpy values of the following elements is :
(A) O
(B) N
(C) Be
(D) F
(E) B
Choose the correct answer from the options given below :
Number of elements from the following that CANNOT form compounds with valencies which match with their respective group valencies is ________. B, C, N, S, O, F, P, Al, Si
Statement (I) : Both metals and non-metals exist in p and d-block elements.
Statement (II) : Non-metals have higher ionisation enthalpy and higher electronegativity than the metals.
In the light of the above statements, choose the most appropriate answer from the options given below :
Consider the following elements.
Which of the following is/are true about $$\mathrm{A}^{\prime}, \mathrm{B}^{\prime}, \mathrm{C}^{\prime}$$ and $$\mathrm{D}^{\prime}$$ ?
A. Order of atomic radii: $$\mathrm{B}^{\prime}<\mathrm{A}^{\prime}<\mathrm{D}^{\prime}<\mathrm{C}^{\prime}$$
B. Order of metallic character: $$\mathrm{B}^{\prime}<\mathrm{A}^{\prime}<\mathrm{D}^{\prime}<\mathrm{C}^{\prime}$$
C. Size of the element: $$\mathrm{D}^{\prime}<\mathrm{C}^{\prime}<\mathrm{B}^{\prime}<\mathrm{A}^{\prime}$$
D. Order of ionic radii: $$\mathrm{B}^{\prime+}<\mathrm{A}^{1^{+}}<\mathrm{D}^{\prime+}<\mathrm{C}^{+}$$
Choose the correct answer from the options given below :
The correct sequence of electron gain enthalpy of the elements listed below is
A. Ar
B. Br
C. F
D. S
Choose the most appropriate from the options given below:
Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R:
Assertion A: $$\mathrm{H}_2 \mathrm{Te}$$ is more acidic than $$\mathrm{H}_2 \mathrm{~S}$$.
Reason R: Bond dissociation enthalpy of $$\mathrm{H}_2 \mathrm{Te}$$ is lower than $$\mathrm{H}_2 \mathrm{~S}$$.
In the light of the above statements, choose the most appropriate from the options given below:
Given below are two statements:
Statement - I: Along the period, the chemical reactivity of the elements gradually increases from group 1 to group 18 .
Statement - II: The nature of oxides formed by group 1 elements is basic while that of group 17 elements is acidic.
In the light of the above statements, choose the most appropriate from the options given below:
Match List I with List II.
List I Species |
List II Electronic distribution |
||
---|---|---|---|
(A) | $$\mathrm{Cr^{+2}}$$ | (I) | $$\mathrm{3d^8}$$ |
(B) | $$\mathrm{Mn^+}$$ | (II) | $$\mathrm{3d^34s^1}$$ |
(C) | $$\mathrm{Ni^{+2}}$$ | (III) | $$\mathrm{3d^4}$$ |
(D) | $$\mathrm{V^+}$$ | (IV) | $$\mathrm{3d^54s^1}$$ |
Choose the correct answer from the options given below :
Given below are two statements:
Statement I : Fluorine has most negative electron gain enthalpy in its group.
Statement II : Oxygen has least negative electron gain enthalpy in its group.
In the light of the above statements, choose the most appropriate from the options given below
The element having the highest first ionization enthalpy is
Anomalous behavior of oxygen is due to its
Given below are two statements : one is labelled as Assertion $$\mathbf{A}$$ and the other is labelled as Reason $$\mathbf{R}$$ :
Assertion A : The first ionisation enthalpy decreases across a period.
Reason $$\mathbf{R}$$ : The increasing nuclear charge outweighs the shielding across the period.
In the light of the above statements, choose the most appropriate from the options given below :
Given below are two statements :
Statement I : The electronegativity of group 14 elements from $$\mathrm{Si}$$ to $$\mathrm{Pb}$$, gradually decreases.
Statement II : Group 14 contains non-metallic, metallic, as well as metalloid elements.
In the light of the above statements, choose the most appropriate from the options given below :
Given below are two statements :
Statement (I) : The $$4 \mathrm{f}$$ and $$5 \mathrm{f}$$ - series of elements are placed separately in the Periodic table to preserve the principle of classification.
Statement (II) : S-block elements can be found in pure form in nature.
In the light of the above statements, choose the most appropriate answer from the options given below :
Which of the following statements are not correct?
A. The electron gain enthalpy of $$\mathrm{F}$$ is more negative than that of $$\mathrm{Cl}$$.
B. Ionization enthalpy decreases in a group of periodic table.
C. The electronegativity of an atom depends upon the atoms bonded to it.
D. $$\mathrm{Al}_{2} \mathrm{O}_{3}$$ and $$\mathrm{NO}$$ are examples of amphoteric oxides.
Choose the most appropriate answer from the options given below :
For elements $$\mathrm{B}, \mathrm{C}, \mathrm{N}, \mathrm{Li}, \mathrm{Be}, \mathrm{O}$$ and $$\mathrm{F}$$, the correct order of first ionization enthalpy is
Given below are two statements: one is labelled as Assertion $$\mathbf{A}$$ and the other is labelled as Reason $$\mathbf{R}$$
Assertion A : The energy required to form $$\mathrm{Mg}^{2+}$$ from $$\mathrm{Mg}$$ is much higher than that required to produce $$\mathrm{Mg}^+$$
Reason $$\mathbf{R}: \mathrm{Mg}^{2+}$$ is small ion and carry more charge than $$\mathrm{Mg}^{+}$$
In the light of the above statements, choose the correct answer from the options given below.
The correct order of electronegativity for given elements is:
Which one of the following elements will remain as liquid inside pure boiling water?
Group-13 elements react with $$\mathrm{O}_{2}$$ in amorphous form to form oxides of type $$\mathrm{M}_{2} \mathrm{O}_{3}~(\mathrm{M}=$$ element). Which among the following is the most basic oxide?
The difference between electron gain enthalpies will be maximum between :
(Given : atomic number $\mathrm{Sm}=62 ; \mathrm{Eu}=63 ; \mathrm{Tb}=65 ; \mathrm{Gd}=64, \mathrm{Pm}=61$ )
A. $\mathrm{Sm}$
B. Eu
C. $\mathrm{Tb}$
D. Gd
E. $\mathrm{Pm}$
Choose the correct answer from the options given below :
Assertion (A): The first ionization enthalpy of $3 \mathrm{~d}$ series elements is more than that of group 2 metals
Reason (R): In 3d series of elements successive filling of d-orbitals takes place.
In the light of the above statements, choose the correct answer from the options given below :
The correct increasing order of the ionic radii is
A. $\mathrm{O}$
B. $\mathrm{S}$
C. Se
D. $\mathrm{Te}$
Choose the correct from the options given below:
Match List I with List II
List I (Atomic number) |
List II (Block of periodic table) |
||
---|---|---|---|
A. | 37 | I. | p-block |
B. | 78 | II. | d-block |
C. | 52 | III. | f-block |
D. | 65 | IV. | s-block |
Choose the correct answer from the options given below :
Given below are two statements :
Statement I : The decrease in first ionization enthalpy from B to Al is much larger than that from Al to Ga.
Statement II : The d orbitals in Ga are completely filled.
In the light of the above statements, choose the most appropriate answer from the options given below
Inert gases have positive electron gain enthalpy. Its correct order is :
The first ionization enthalpy of Na, Mg and Si, respectively, are : 496, 737 and $$786 \mathrm{~kJ} \mathrm{~mol}^{-1}$$. The first ionization enthalpy ($$\mathrm{kJ} \,\mathrm{mol}^{-1}$$) of $$\mathrm{Al}$$ is :
In which of the following pairs, electron gain enthalpies of constituent elements are nearly the same or identical?
(A) Rb and Cs
(B) Na and K
(C) Ar and Kr
(D) I and At
Choose the correct answer from the options given below :
The incorrect statement is
Given two statements below :
Statement I : In $$\mathrm{Cl}_{2}$$ molecule the covalent radius is double of the atomic radius of chlorine.
Statement II : Radius of anionic species is always greater than their parent atomic radius.
Choose the most appropriate answer from options given below :
The first ionization enthalpies of Be, B, N and O follow the order
The IUPAC nomenclature of an element with electronic configuration [Rn] $$5 \mathrm{f}^{14} 6 \mathrm{d}^{1} 7 \mathrm{s}^{2}$$ is :
The correct order of electron gain enthalpy ($$-$$ ve value) is :
Given below are two statements. One is labelled as Assertion A and the other is labelled as Reason R.
Assertion A : The first ionization enthalpy for oxygen is lower than that of nitrogen.
Reason R : The four electrons in 2p orbitals of oxygen experience more electron-electron repulsion.
In the light of the above statements, choose the correct answer from the options given below.
Match List - I with List - II :
List-I (Oxide) | List-II (Nature) | ||
---|---|---|---|
(A) | $$C{l_2}{O_7}$$ | (I) | Amphoteric |
(B) | $$N{a_2}O$$ | (II) | Basic |
(C) | $$A{l_2}{O_3}$$ | (III) | Neutral |
(D) | $${N_2}O$$ | (IV) | Acidic |
Choose the correct answer from the options given below :
Among the following, basic oxide is :
Element "E" belongs to the period 4 and group 16 of the periodic table. The valence shell electron configuration of the element, which is just above "E" in the group is
The correct order of increasing ionic radii is
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A) : The ionic radii of O2$$-$$ and Mg2+ are same.
Reason (R) : Both O2$$-$$ and Mg2+ are isoelectronic species.
In the light of the above statements, choose the correct answer from the options given below.
The correct order of electron gain enthalpies of Cl, F, Te and Po is
Given below are the oxides:
Na2O, As2O3, N2O, NO and Cl2O7
Number of amphoteric oxides is :
List - I (Metal Ion) |
List - II (Group of Qualitative analysis) |
||
---|---|---|---|
(a) | $$M{n^{2 + }}$$ | (i) | Group - III |
(b) | $$A{s^{3 + }}$$ | (ii) | Group - IIA |
(c) | $$C{u^{2 + }}$$ | (iii) | Group - IV |
(d) | $$A{l^{3 + }}$$ | (iv) | Group - IIB |
Choose the most appropriate answer from the options given below :
Assertion (A) : Metallic character decreases and non-metallic character increases on moving from left to right in a period.
Reason (R) : It is due to increase in ionisation enthalpy and decrease in electron gain enthalpy, when one moves from left to right in a period.
In the light of the above statements, choose the most appropriate answer from the options given below :
Assertion (A) : Barium carbonate is insoluble in water and is highly stable.
Reason (R) : The thermal stability of the carbonates increases with increasing cationic size.
List - I | List - II | ||
---|---|---|---|
(a) | NaOH | (i) | Acidic |
(b) | $$Be{(OH)_2}$$ | (ii) | Basic |
(c) | $$Ca{(OH)_2}$$ | (iii) | Amphoteric |
(d) | $$B{(OH)_3}$$ | ||
(e) | $$Al{(OH)_3}$$ |
Choose the most appropriate answer from the options given below
The correct statement for the ionic radius of N3$$-$$ from the following is :
Ionization energy (kJ/mol) | ||
---|---|---|
1$${st}$$ | 2$${nd}$$ | |
X | 495 | 4563 |
Y | 731 | 1450 |
List I Electronic configuration |
List II $${\Delta _i}H$$ in kJ $$mo{l^{ - 1}}$$ |
||
---|---|---|---|
(a) | $$1{s^2}2{s^2}$$ | (i) | 801 |
(b) | $$1{s^2}2{s^2}2{p^4}$$ | (ii) | 899 |
(c) | $$1{s^2}2{s^2}2{p^3}$$ | (iii) | 1314 |
(d) | $$1{s^2}2{s^2}2{p^1}$$ | (iv) | 1402 |
Choose the most appropriate answer from the options given below :
O2–, N3–, F– , Mg2+, Na+ and Al3+ is :
(I) Be has smaller atomic radius compared to Mg.
(II) Be has higher ionization enthalpy than Al.
(III) Charge/radius ratio of Be is greater than that of Al.
(IV) Both Be and Al form mainly covalent compounds.
(atomic number : Xe = 54, Ce = 58, Eu = 63)
(I) It is easier to remove 2p electron than 2s electron
(II) 2p electron of B is more shielded from the nucleus by the inner core of electrons than the 2s electrons of Be.
(III) 2s electron has more penetration power than 2p electron.
(IV) atomic radius of B is more than Be (Atomic number B = 5, Be = 4)
The correct statements are :
(a) C (b) O
(c) F (d) Cl
(e) Br
Element | Ionization enthalpy (kJ/mol) | ||
---|---|---|---|
1st | 2nd | 3rd | |
A | 899 | 1757 | 14847 |
B | 737 | 1450 | 7731 |
Which of the following statements is correct ?
O(g) + e- = $$O_{(g)}^{-}$$ $$\Delta $$Ho = -142 kJmol-1
$$O_{(g)}^{-}$$ + e- = $$O_{(g)}^{2-}$$ $$\Delta $$Ho = 844 kJmol-1
This because
Numerical
If IUPAC name of an element is "Unununnium" then the element belongs to nth group of Periodic table. The value of n is ________.
Total number of acidic oxides among
$$\mathrm{N_2O_3,NO_2,N_2O,Cl_2O_7,SO_2,CO,CaO,Na_2O}$$ and $$\mathrm{NO}$$ is ____________.
(A) BeO
(B) BaO
(C) Be(OH)2
(D) Sr(OH)2