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MCQ (Single Correct Answer)

1

Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R.

Assertion A : Isotopes of hydrogen have almost same chemical properties, but difference in their rates of reaction.

Reason R : Isotopes of hydrogen have different enthalpy of bond dissociation.

In the light of the above statements, choose the most appropriate answer from the options given below:

JEE Main 2023 (Online) 13th April Evening Shift
2

Given below are two statements :

Statement I : Permutit process is more efficient compared to the synthetic resin method for the softening of water.

Statement II : Synthetic resin method results in the formation of soluble sodium salts.

In the light of the above statements, choose the most appropriate answer from the options given below:

JEE Main 2023 (Online) 13th April Morning Shift
3

Match List I with List II

LIST I
Type of Hydride
LIST II
Example
A. Electron deficient hydride I. $$\mathrm{MgH_2}$$
B. Electron rich hydride II. $$\mathrm{HF}$$
C. Electron precise hydride III. $$\mathrm{B_2H_6}$$
D. Saline hydride IV. $$\mathrm{CH_4}$$

Choose the correct answer from the options given below:

JEE Main 2023 (Online) 12th April Morning Shift
4

Which hydride among the following is less stable?

JEE Main 2023 (Online) 11th April Evening Shift
5

Given below are two statements:

Statement-I : Methane and steam passed over a heated $$\mathrm{Ni}$$ catalyst produces hydrogen gas.

Statement-II : Sodium nitrite reacts with $$\mathrm{NH}_{4} \mathrm{Cl}$$ to give $$\mathrm{H}_{2} \mathrm{O}, \mathrm{N}_{2}$$ and $$\mathrm{NaCl}$$.

In the light of the above statements, choose the most appropriate answer from the options given below :

JEE Main 2023 (Online) 11th April Morning Shift
6

Given below are two statements: one is labelled as Assertion $$\mathbf{A}$$ and the other is labelled as Reason $$\mathbf{R}$$

Assertion A : Physical properties of isotopes of hydrogen are different.

Reason R : Mass difference between isotopes of hydrogen is very large.

In the light of the above statements, choose the correct answer from the options given below:

JEE Main 2023 (Online) 10th April Evening Shift
7

Given below are two reactions, involved in the commercial production of dihydrogen (H$$_2$$). The two reactions are carried out at temperature "T$$_1$$" and "T$$_2$$", respectively

$$C(s) + {H_2}O(g)\buildrel {{T_1}} \over \longrightarrow CO(g) + {H_2}(g)$$

$$CO(g) + {H_2}O(g)\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{Catalyst}^{{T_2}}} C{O_2}(g) + {H_2}(g)$$

The temperatures T$$_1$$ and T$$_2$$ are correctly related as :

JEE Main 2023 (Online) 10th April Morning Shift
8

Which of the following can reduce decomposition of $$\mathrm{H}_{2} \mathrm{O}_{2}$$ on exposure to light :

JEE Main 2023 (Online) 8th April Evening Shift
9

Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R.

Assertion A : Loss of electron from hydrogen atom results in nucleus of $$\sim 1.5 \times 10^{-3} \mathrm{pm}$$ size.

Reason R : Proton $$\left(\mathrm{H}^{+}\right)$$ always exists in combined form.

In the light of the above statements, choose the most appropriate answer from the options given below:

JEE Main 2023 (Online) 6th April Morning Shift
10

The starting material for convenient preparation of deuterated hydrogen peroxide ($$\mathrm{D_{2}O_{2}}$$) in :

JEE Main 2023 (Online) 1st February Evening Shift
11

Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R

Assertion A : Hydrogen is an environment friendly fuel.

Reason R : Atomic number of hydrogen is 1 and it is a very light element.

In the light of the above statements, choose the correct answer from the options given below :

JEE Main 2023 (Online) 1st February Morning Shift
12
The normal rain water is slightly acidic and its $\mathrm{pH}$ value is $5.6$ because of which one of the following?
JEE Main 2023 (Online) 31st January Evening Shift
13

Given below are two statements :

Statement I : $ \mathrm{H}_{2} \mathrm{O}_{2}$ is used in the synthesis of Cephalosporin

Statement II : $ \mathrm{H}_{2} \mathrm{O}_{2}$ is used for the restoration of aerobic conditions to sewage wastes.

In the light of the above statements, choose the most appropriate answer from the options given below :

JEE Main 2023 (Online) 31st January Evening Shift
14

$$\mathrm{H}_{2} \mathrm{O}_{2}$$ acts as a reducing agent in :

JEE Main 2023 (Online) 31st January Morning Shift
15

Which of the given compounds can enhance the efficiency of hydrogen storage tank?

JEE Main 2023 (Online) 29th January Morning Shift
16

Match List I with List II

List I List II
A. Cobalt catalyst I. $$\mathrm{(H_2+Cl_2)}$$ production
B. Syngas II. Water gas production
C. Nickel catalyst III. Coal gasification
D. Brine solution IV. Methanol production

Choose the correct answer from the options given below :

JEE Main 2023 (Online) 25th January Evening Shift
17

In which of the following reactions the hydrogen peroxide acts as a reducing agent?

JEE Main 2023 (Online) 24th January Evening Shift
18

The products obtained during treatment of hard water using Clark's method are :

JEE Main 2022 (Online) 28th July Evening Shift
19

The metal salts formed during softening of hardwater using Clark's method are :

JEE Main 2022 (Online) 28th July Morning Shift
20

Given below are two statements.

Statement I : Hydrogen peroxide can act as an oxidizing agent in both acidic and basic conditions.

Statement II : Density of hydrogen peroxide at $$298 \mathrm{~K}$$ is lower than that of $$\mathrm{D}_{2} \mathrm{O}$$.

In the light of the above statements, choose the correct answer from the options given below.

JEE Main 2022 (Online) 27th July Morning Shift
21
The products obtained from a reaction of hydrogen peroxide and acidified potassium permanganate are :
JEE Main 2022 (Online) 26th July Evening Shift
22

Which of the following can be used to prevent the decomposition of $$\mathrm{H}_{2} \mathrm{O}_{2}$$ ?

JEE Main 2022 (Online) 26th July Morning Shift
23

High purity (> 99.95%) dihydrogen is obtained by :

JEE Main 2022 (Online) 25th July Evening Shift
24

The reaction of $$\mathrm{H}_{2} \mathrm{O}_{2}$$ with potassium permanganate in acidic medium leads to the formation of mainly :

JEE Main 2022 (Online) 25th July Morning Shift
25

Which one of the following reactions indicates the reducing ability of hydrogen peroxide in basic medium?

JEE Main 2022 (Online) 29th June Morning Shift
26

Hydrogen has three isotopes : protium (1H), deuterium (2H or D) and tritium (3H or T). They have nearly same chemical properties but different physical properties. They differ in :

JEE Main 2022 (Online) 28th June Evening Shift
27

Dihydrogen reacts with CuO to give :

JEE Main 2022 (Online) 28th June Morning Shift
28

Boiling of hard water is helpful in removing the temporary hardness by converting calcium hydrogen carbonate and magnesium hydrogen carbonate to :

JEE Main 2022 (Online) 26th June Evening Shift
29

Consider the following reaction:

$$2HSO_4^ - (aq)\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{(2)\,Hydrolysis}^{(1)\,Electrolysis}} 2HSO_4^ - + 2{H^ + } + A$$

The dihedral angle in product A in its solid phase at 110 K is :

JEE Main 2022 (Online) 26th June Morning Shift
30

The highest industrial consumption of molecular hydrogen is to produce compounds of element :

JEE Main 2022 (Online) 24th June Morning Shift
31
Hydrogen peroxide reacts with iodine in basic medium to give :
JEE Main 2021 (Online) 1st September Evening Shift
32
Which one of the following statements is incorrect?
JEE Main 2021 (Online) 31st August Evening Shift
33
Given below are two statements :

Statement I : The process of producing syn-gas is called gasification of coal.

Statement II : The composition of syn-gas is CO + CO2 + H2 (1 : 1 : 1)

In the light of the above statements, choose the most appropriate answer from the options given below :
JEE Main 2021 (Online) 31st August Morning Shift
34
The oxide that gives H2O2 most readily on treatment with H2O is :
JEE Main 2021 (Online) 27th August Evening Shift
35
Deuterium resembles hydrogen in properties but :
JEE Main 2021 (Online) 27th August Morning Shift
36
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : Heavy water is used for the study of reaction mechanism.

Reason (R) : The rate of reaction for the cleavage of O - H bond is slower than that of O - D bond.

Choose the most appropriate answer from the options given below :
JEE Main 2021 (Online) 26th August Evening Shift
37
Which one of the following methods is most suitable for preparing deionized water?
JEE Main 2021 (Online) 26th August Morning Shift
38
The number of neutrons and electrons, respectively, present in the radioactive isotope of hydrogen is :
JEE Main 2021 (Online) 27th July Evening Shift
39
At 298.2 K the relationship between enthalpy of bond dissociation (in kJ mol$$-$$1) for hydrogen (EH) and its isotope, deuterium (ED), is best described by :
JEE Main 2021 (Online) 25th July Morning Shift
40
The water having more dissolved O2 is :
JEE Main 2021 (Online) 22th July Evening Shift
41
The single largest industrial application of dihydrogen is :
JEE Main 2021 (Online) 20th July Evening Shift
42
Given below are two statements : One is labelled as Assertion A and other is labelled as Reason R.

Assertion A : The dihedral angles in H2O2 in gaseous phase is 90.2$$^\circ$$ and in solid phase is 111.5$$^\circ$$.

Reason R : The change in dihedral angle in solid and gaseous phase is due to the difference in the intermolecular forces.

Choose the most appropriate answer from the options given below for A and R.
JEE Main 2021 (Online) 20th July Morning Shift
43
In basic medium, H2O2 exhibits which of the following reactions?

(A) Mn2+ $$ \to $$ Mn4+

(B) I2 $$ \to $$ I$$-$$

(C) PbS $$ \to $$ PbSO4

Choose the most appropriate answer from the options given below :
JEE Main 2021 (Online) 18th March Evening Shift
44
The functional groups that are responsible for the ion-exchange property of cation and anion exchange resins, respectively, are :
JEE Main 2021 (Online) 17th March Evening Shift
45
The INCORRECT statement(s) about heavy water is (are)

(A) used as a moderator in nuclear reactor

(B) obtained as a by-product in fertilizer industry

(C) used for the study of reaction mechanism

(D) has a higher dielectric constant than water

Choose the correct answer from the options given below :
JEE Main 2021 (Online) 17th March Morning Shift
46
The correct statements about H2O2 are :

(A) used in the treatment of effluents.

(B) used as both oxidising and reducing agents.

(C) the two hydroxyl groups lie in the same plane.

(D) miscible with water.

Choose the correct answer from the options given below :
JEE Main 2021 (Online) 16th March Evening Shift
47
Given below are two statements :

Statement I : H2O2 can act as both oxidising and reducing agent in basic medium.

Statement II : In the hydrogen economy, the energy is transmitted in the form of dihydrogen.

In the light of the above statements, choose the correct answer from the options given below :
JEE Main 2021 (Online) 16th March Morning Shift
48
Statements about heavy water are given below :

A. Heavy water is used in exchange reactions for the study of reaction mechanisms.

B. Heavy water is prepared by exhaustive electrolysis of water.

(C) Heavy water has higher boiling point than ordinary water.

(D) Viscosity of H2O is greater than D2O.

Choose the most appropriate answer from the options given below :
JEE Main 2021 (Online) 26th February Morning Shift
49
Water does not produce CO on reacting with :
JEE Main 2021 (Online) 25th February Evening Shift
50
Which of the following equation depicts the oxidizing nature of H2O2?
JEE Main 2021 (Online) 25th February Morning Shift
51
Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R.

Assertion A : Hydrogen is the most abundant element in the Universe, but it is not the most abundant gas in the troposphere.

Reason R : Hydrogen is the lightest element.

In the light of the above statements, choose the correct answer from the options given below :
JEE Main 2021 (Online) 24th February Evening Shift
52
(A) HOCI + H2O2 → H3O+ + Cl- + O2

(B) I2 + H2O2 + 2OH- → 2I- + 2H2O + O2

Choose the correct option.
JEE Main 2021 (Online) 24th February Morning Shift
53
Dihydrogen of high purity (> 99.95%) is obtained through :
JEE Main 2020 (Online) 6th September Evening Slot
54
The one that is NOT suitable for the removal of permanent hardness of water is :
JEE Main 2020 (Online) 5th September Evening Slot
55
Hydrogen peroxide, in the pure state, is :
JEE Main 2020 (Online) 5th September Evening Slot
56
The equation that represents the water-gas shift reaction is :
JEE Main 2020 (Online) 5th September Morning Slot
57
If the boiling point of H2O is 373 K, the boiling point of H2S will be :
JEE Main 2020 (Online) 3rd September Morning Slot
58
Amongst the following, the form of water with the lowest ionic conductance at 298 K is :
JEE Main 2020 (Online) 9th January Evening Slot
59
Among the statements (a) - (d), the correct ones are :
(a) Decomposition of hydrogen peroxide gives dioxygen.
(b) Like hydrogen peroxide, compounds, such as KCIO3, Pb(NO3)2 and NaNO3 when heated liberate dioxygen.
(c) 2-Ethylanthraquinone is useful for the industrial preparation of hydrogen peroxide.
(d) Hydrogen peroxide is used for the manufacture of sodium perborate.
JEE Main 2020 (Online) 7th January Evening Slot
60
In comparison to the zeolite process for the removal of permanent hardness, the synthetic resins method is :
JEE Main 2020 (Online) 7th January Morning Slot
61
The temporary hardness of a water sample is due to compound X. Boiling this sample converts X to compound Y. X and Y, respectively, are :
JEE Main 2019 (Online) 12th April Evening Slot
62
The metal that gives hydrogen gas upon treatment with both acid as well as base is :
JEE Main 2019 (Online) 12th April Morning Slot
63
The correct statements among (a) to (d) are :
(a) saline hydrides produce H2 gas when reacted with H2O.
(b) reaction of LiAlH4 with BF3 leads to B2H6.
(c) PH3 and CH4 are electron - rich and electron - precise hydrides, respectively.
(d) HF and CH4 are called as molecular
JEE Main 2019 (Online) 10th April Evening Slot
64
The synonym for water gas when used in the production of methanol is :
JEE Main 2019 (Online) 10th April Morning Slot
65
The number of water molecule(s) not coordinated to copper ion directly in CuSO4.5H2O, is :
JEE Main 2019 (Online) 9th April Morning Slot
66
The strength of 11.2 volume solution of H2O2 is : [Given that molar mass of H = 1 g mol–1 and O = 16 g mol–1]
JEE Main 2019 (Online) 8th April Evening Slot
67
100 mL of a water sample contains 0.81 g of calcium bicrabonate and 0.73 g of magnesium bicarbonate. The hardness of this water sample expressed in terms of equivalents of CaCO3 is : (Molar mass of calcium bicarbonate is 162 g mol–1 and magnesium bicarbonate is 146 g mol–1)
JEE Main 2019 (Online) 8th April Morning Slot
68
The volume strength of 1M H2O2 is : (Molar mass of H2O2 = 34 g mol–1)
JEE Main 2019 (Online) 12th January Evening Slot
69
NaH is an example of :
JEE Main 2019 (Online) 11th January Morning Slot
70
The correct statements among (a) to (d) regarding H2 as a fuel are :

(a)   It produces less pollutants than petrol.

(b)   A cylinder of compressed dihydrogen weighs $$ \sim $$ 30 times more than a petrol tank producing the same amount of energy.

(c)   Dihydrogen is stored in tanks of metal alloys like NaNi5.

(d)   On combustion, values of energy released per gram of liquid dihydrogen and LPG are 50 and 142 KJ, respectively.
JEE Main 2019 (Online) 11th January Morning Slot
71
The chemical nature of hydrogen peroxide is :
JEE Main 2019 (Online) 10th January Morning Slot
72
The total number of isotopes of hydrogen and number of radioactive isotopes among them, respectively, are :
JEE Main 2019 (Online) 10th January Morning Slot
73
The temporary hardness of water is due to :
JEE Main 2019 (Online) 9th January Evening Slot
74
The isotopes of hydrogen are :
JEE Main 2019 (Online) 9th January Morning Slot
75
Hydrogen peroxide oxidises [Fe(CN)6]4- to [Fe(CN)6]3- in acidic medium but reduces [Fe(CN)6]3- to [Fe(CN)6]4- in alkaline medium. The other products formed are, respectively :
JEE Main 2018 (Offline)
76
In which of the following reactions, hydrogen peroxide acts as an oxidizing agent ?
JEE Main 2017 (Online) 8th April Morning Slot
77
Identify the reaction which does not liberate hydrogen :
JEE Main 2016 (Online) 10th April Morning Slot
78
Identify the incorrect statement regarding heavy water :
JEE Main 2016 (Online) 9th April Morning Slot
79
Which one of the following statements about water is FALSE?
JEE Main 2016 (Offline)
80
From the following statements regarding H2O2, choose the incorrect statement :
JEE Main 2015 (Offline)
81
Very pure hydrogen (99.9%) can be made by which of the following processes?
AIEEE 2012
82
In context with the industrial preparation of hydrogen from water gas (CO + H2), which of the following is the correct statement?
AIEEE 2008
83
Which of the following statements in relation to the hydrogen atom is correct?
AIEEE 2005
84
Which one of the following process will produce hard water?
AIEEE 2003
85
Which of the following could act as a propellant for rockets?
AIEEE 2003

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