1
JEE Main 2025 (Online) 7th April Morning Shift
MCQ (Single Correct Answer)
+4
-1

An octahedral complex having molecular composition $\mathrm{Co} \cdot 5 \mathrm{NH}_3 \cdot \mathrm{Cl}^2 . \mathrm{SO}_4$ has two isomers A and B. The solution of A gives a white precipitate with $\mathrm{AgNO}_3$ solution and the solution of B gives white precipitate with $\mathrm{BaCl}_2$ solution. The type of isomerism exhibited by the complex is,

A
Co-ordinate isomerism
B
Ionisation isomerism
C
Geometrical isomerism
D
Linkage isomerism
2
JEE Main 2025 (Online) 4th April Evening Shift
MCQ (Single Correct Answer)
+4
-1

' $X$ ' is the number of electrons in $t_{2 g}$ orbitals of the most stable complex ion among $\left[\mathrm{Fe}\left(\mathrm{NH}_3\right)_6\right]^{3+},\left[\mathrm{FeCl}_6\right]^{3-}, \quad\left[\mathrm{Fe}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]^{3-}$ and $\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}$. The nature of oxide of vanadium of the type $\mathrm{V}_2 \mathrm{O}_{\mathrm{X}}$ is :

A
Amphoteric
B
Acidic
C
Basic
D
Neutral
3
JEE Main 2025 (Online) 4th April Evening Shift
MCQ (Single Correct Answer)
+4
-1

The correct order of $\left[\mathrm{FeF}_6\right]^{3-},\left[\mathrm{CoF}_6\right]^{3-},\left[\mathrm{Ni}(\mathrm{CO})_4\right]$ and $\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}$ complex species based on the number of unpaired electrons present is:

A
$\left[\mathrm{CoF}_6\right]^{3-}>\left[\mathrm{FeF}_6\right]^{3-}>\left[\mathrm{Ni}(\mathrm{CO})_4\right]>\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}$
B
$\left[\mathrm{FeF}_6\right]^{3-}>\left[\mathrm{CoF}_6\right]^{3-}>\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}>\left[\mathrm{Ni}(\mathrm{CO})_4\right]$
C
$\left[\mathrm{FeF}_6\right]^{3-}>\left[\mathrm{CoF}_6\right]^{3-}>\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}=\left[\mathrm{Ni}(\mathrm{CO})_4\right]$
D
$\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}>\left[\mathrm{FeF}_6\right]^{3-}>\left[\mathrm{CoF}_6\right]^{3-}>\left[\mathrm{Ni}(\mathrm{CO})_4\right]$
4
JEE Main 2025 (Online) 4th April Morning Shift
MCQ (Single Correct Answer)
+4
-1

Which one of the following complexes will have $\Delta_{\mathrm{o}}=0$ and $\mu=5.96$ B.M?

A
$\left[\mathrm{FeF}_6\right]^{4-}$
B
$\left[\mathrm{Mn}(\mathrm{SCN})_6\right]^{4-}$
C
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}$
D
$\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{4-}$
JEE Main Subjects
EXAM MAP
Medical
NEETAIIMS
Graduate Aptitude Test in Engineering
GATE CSEGATE ECEGATE EEGATE MEGATE CEGATE PIGATE IN
Civil Services
UPSC Civil Service
Defence
NDA
Staff Selection Commission
SSC CGL Tier I
CBSE
Class 12