In which of the following complexes the CFSE, $\Delta_o$ will be equal to zero?
Match List I with List II
| LIST I | LIST II | ||
|---|---|---|---|
| A. | $$\mathrm{K}_2\left[\mathrm{Ni}(\mathrm{CN})_4\right]$$ | I. | $$sp^3$$ |
| B. | $$\left[\mathrm{Ni}(\mathrm{CO})_4\right]$$ | II. | $$sp^3d^2$$ |
| C. | $$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right] \mathrm{Cl}_3$$ | III. | $$dsp^2$$ |
| D. | $$\mathrm{Na}_3\left[\mathrm{CoF}_6\right]$$ | IV. | $$d^2sp^3$$ |
Choose the correct answer from the options given below:
The coordination environment of $$\mathrm{Ca}^{2+}$$ ion in its complex with $$\mathrm{EDTA}^{4-}$$ is :
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A): The total number of geometrical isomers shown by $$[\mathrm{Co}(\mathrm{en})_2 \mathrm{Cl}_2]^{+}$$ complex ion is three.
Reason (R): $$[\mathrm{Co}(\mathrm{en})_2 \mathrm{Cl}_2]^{+}$$ complex ion has an octahedral geometry.
In the light of the above statements, choose the most appropriate answer from the options given below :
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