1
JEE Main 2025 (Online) 7th April Evening Shift
MCQ (Single Correct Answer)
+4
-1

Given below are two statements :

1 M aqueous solutions of each of Cu(NO3)2, AgNO3, Hg2(NO3)2, Mg(NO3)2 are electrolysed using inert electrodes. Given: E0Ag+/Ag = 0.80 V, E0Hg22+/Hg = 0.79 V, E0Cu2+/Cu = 0.24 V and E0Mg2+/Mg = -2.37 V.

Statement (I) : With increasing voltage, the sequence of deposition of metals on the cathode will be Ag, Hg and Cu.

Statement (II) : Magnesium will not be deposited at the cathode instead oxygen gas will be evolved at the cathode.

In the light of the above statements, choose the most appropriate answer from the options given below :

A

Both Statement I and Statement II are incorrect

B

Statement I is incorrect but Statement II is correct

C

Statement I is correct but Statement II is incorrect

D

Both Statement I and Statement II are correct

2
JEE Main 2025 (Online) 7th April Evening Shift
MCQ (Single Correct Answer)
+4
-1

The extra stability of half-filled subshell is due to :

(A) Symmetrical distribution of electrons

(B) Smaller coulombic repulsion energy

(C) The presence of electrons with the same spin in non-degenerate orbitals

(D) Larger exchange energy

(E) Relatively smaller shielding of electrons by one another

Indentify the correct statements :

A
(B), (D) and (E) only
B
$(A),(B),(D)$ and (E) only
C
(B), (C) and (D) only
D
$(A),(B)$ and (D) only
3
JEE Main 2025 (Online) 7th April Evening Shift
MCQ (Single Correct Answer)
+4
-1

'X' is the number of acidic oxides among VO2, V2O3, CrO3, V2O5 and Mn2O7. The primary valency of cobalt in
[Co(H2NCH2CH2NH2)3]2(SO4)3 is Y. The value of X + Y is _________.

A

3

B

4

C

2

D

5

4
JEE Main 2025 (Online) 7th April Evening Shift
MCQ (Single Correct Answer)
+4
-1

The correct statement amongst the following is :

A

The standard state of a pure gas is the pure gas at a pressure of 1 bar and temperature 273 K.

B

$\Delta_f H^{\circ}_{500}$ is zero for $O_2(g)$.

C

$\Delta_f H^{\circ}_{298}$ is zero for $O(g)$.

D

The term 'standard state' implies that the temperature is 0°C.

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