Which of the following reactions will not produce a racemic product?

In the following reaction A is :

The first and second ionisation enthalpies of a metal are 496 and 4560 kJ mol^–1, respectively. How many moles of HCl and H₂SO₄, respectively, will be needed to react completely with 1 mole of the metal hydroxide ?

Consider the following reactions,


The compound [P] is :

Consider the following reactions


The mass percentage of carbon in A is ______.

10.30 mg of O₂ is dissolved into a liter of sea water of density 1.03 g/mL. The concentration of O₂ in ppm is__________.

The sum of the total number of bonds between chromium and oxygen atoms in chromate and dichromate ions is ____________.

A sample of milk splits after 60 min. at 300 K and after 40 min. at 400 K when the population of lactobacillus acidophilus in it doubles. The activa tion energy (in kJ/ mol) for this process is closest to__________.

(Given, R = 8.3 J mol^–1 K^–1, $$\ln \left( {{3 \over 2}} \right) = 0.4$$, e^–3 = 4.0)

A cylinder containing an ideal gas (0.1 mol of 1.0 dm³) is in thermal equilibrium with a large volume of 0.5 molal aqueous solution of ethylene glycol at its freezing point. If the stoppers S₁ and S₂ (as shown in the figure) are suddenly withdrawn, the volume of the gas in litres after equilibrium is achieved will be____.

(Given, K_f (water) = 2.0 K kg mol^–1,
R = 0.08 dm³ atm K^–1 mol^–1)

The true statement amongst the following is :

The number of sp² hybrid orbitals in a molecule of benzene is :

The isomer(s) of [Co(NH₃)₄Cl₂] that has/have a Cl–Co–Cl angle of 90°, is/are :

The reaction of H₃N₃B₃Cl₃ (A) with LiBH₄ in tetrahydrofuran gives inorganic benzene (B). Further, the reaction of (A) with (C) leads to H₃N₃B₃(Me)₃. Compounds (B) and (C) respectively, are :

A, B and C are three biomolecules. The results of the tests performed on them are given below:

$$ \begin{array}{|l|l|l|l|} \hline & \begin{array}{l} \text { Molisch's } \\ \text { Test } \end{array} & \begin{array}{l} \text { Barfoed } \\ \text { Test } \end{array} & \begin{array}{l} \text { Biuret } \\ \text { Test } \end{array} \\ \hline \text { A } & \text { Positive } & \text { Negative } & \text { Negative } \\ \hline \text { B } & \text { Positive } & \text { Positive } & \text { Negative } \\ \hline \text { C } & \text { Negative } & \text { Negative } & \text { Positive } \\ \hline \end{array} $$

A, B and C are respectively :

5 g of zinc is treated separately with an excess of

(a) dilute hydrochloric acid and
(b) aqueous sodium hydroxide.

The ratio of the volumes of H₂ evolved in these two reactions is :

The solubility product of Cr(OH)₃ at 298 K is 6.0 × 10^–31. The concentration of hydroxide ions in a saturated solution of Cr(OH)₃ will be :

The decreasing order of basicity of the following amines is :

In the figure shown below reactant A (represented by square) is in equilibrium with product B (represented by circle). The equilibrium constant is :

Which of the following has the shortest C-Cl bond?

The correct order of the spin-only magnetic moments of the following complexes is :
(I) [Cr(H₂O)₆]Br₂
(II) Na₄[Fe(CN)₆]
(III) Na₃[Fe(C₂O₄)₃] ($$\Delta $$₀ $$>$$ P)
(IV) (Et₄N)₂[CoCl₄]

Let ƒ and g be differentiable functions on R such that fog is the identity function. If for some a, b $$ \in $$ R, g'(a) = 5 and g(a) = b, then ƒ'(b) is equal to :

In the expansion of $${\left( {{x \over {\cos \theta }} + {1 \over {x\sin \theta }}} \right)^{16}}$$, if $${\ell _1}$$ is the least value of the term independent of x when $${\pi \over 8} \le \theta \le {\pi \over 4}$$ and $${\ell _2}$$ is the least value of the term independent of x when $${\pi \over {16}} \le \theta \le {\pi \over 8}$$, then the ratio $${\ell _2}$$ : $${\ell _1}$$ is equal to :

Let a – 2b + c = 1.

If $$f(x)=\left| {\matrix{ {x + a} & {x + 2} & {x + 1} \cr {x + b} & {x + 3} & {x + 2} \cr {x + c} & {x + 4} & {x + 3} \cr } } \right|$$, then:

If z be a complex number satisfying |Re(z)| + |Im(z)| = 4, then |z| cannot be :

If $$\int {{{d\theta } \over {{{\cos }^2}\theta \left( {\tan 2\theta + \sec 2\theta } \right)}}} = \lambda \tan \theta + 2{\log _e}\left| {f\left( \theta \right)} \right| + C$$

where C is a constant of integration, then the ordered pair ($$\lambda $$, ƒ($$\theta $$)) is equal to :

If $${{dy} \over {dx}} = {{xy} \over {{x^2} + {y^2}}}$$; y(1) = 1; then a value of x satisfying y(x) = e is :

Let a function ƒ : [0, 5] $$ \to $$ R be continuous, ƒ(1) = 3 and F be defined as :

$$F(x) = \int\limits_1^x {{t^2}g(t)dt} $$ , where $$g(t) = \int\limits_1^t {f(u)du} $$

Then for the function F, the point x = 1 is :

If 10 different balls are to be placed in 4 distinct boxes at random, then the probability that two of these boxes contain exactly 2 and 3 balls is :

Let a_n be the n^th term of a G.P. of positive terms.

$$\sum\limits_{n = 1}^{100} {{a_{2n + 1}} = 200} $$ and $$\sum\limits_{n = 1}^{100} {{a_{2n}} = 100} $$,

then $$\sum\limits_{n = 1}^{200} {{a_n}} $$ is equal to :

If A = {x $$ \in $$ R : |x| < 2} and B = {x $$ \in $$ R : |x – 2| $$ \ge $$ 3}; then :

If $$x = \sum\limits_{n = 0}^\infty {{{\left( { - 1} \right)}^n}{{\tan }^{2n}}\theta } $$ and $$y = \sum\limits_{n = 0}^\infty {{{\cos }^{2n}}\theta } $$

for 0 < $$\theta $$ < $${\pi \over 4}$$, then :

Given : $$f(x) = \left\{ {\matrix{ {x\,\,\,\,\,,} & {0 \le x < {1 \over 2}} \cr {{1 \over 2}\,\,\,\,,} & {x = {1 \over 2}} \cr {1 - x\,\,\,,} & {{1 \over 2} < x \le 1} \cr } } \right.$$

and $$g(x) = \left( {x - {1 \over 2}} \right)^2,x \in R$$

Then the area (in sq. units) of the region bounded by the curves, y = ƒ(x) and y = g(x) between the lines, 2x = 1 and 2x = $$\sqrt 3 $$, is :

Let a, b $$ \in $$ R, a $$ \ne $$ 0 be such that the equation, ax² – 2bx + 5 = 0 has a repeated root $$\alpha $$, which is also a root of the equation, x² – 2bx – 10 = 0. If $$\beta $$ is the other root of this equation, then $$\alpha $$² + $$\beta $$² is equal to :

A random variable X has the following probability distribution :

X:	1	2	3	4	5
P(X):	K2	2K	K	2K	5K2

Then P(X > 2) is equal to :

If $$x = 2\sin \theta - \sin 2\theta $$ and $$y = 2\cos \theta - \cos 2\theta $$,
$$\theta \in \left[ {0,2\pi } \right]$$, then $${{{d^2}y} \over {d{x^2}}}$$ at $$\theta $$ = $$\pi $$ is :

Let [t] denote the greatest integer $$ \le $$ t and $$\mathop {\lim }\limits_{x \to 0} x\left[ {{4 \over x}} \right] = A$$.
Then the function, f(x) = [x²]sin($$\pi $$x) is discontinuous, when x is equal to :

The following system of linear equations
7x + 6y – 2z = 0
3x + 4y + 2z = 0
x – 2y – 6z = 0, has

If the curves, x² – 6x + y² + 8 = 0 and
x² – 8y + y² + 16 – k = 0, (k > 0) touch each other at a point, then the largest value of k is ______.

Let $$\overrightarrow a $$, $$\overrightarrow b $$ and $$\overrightarrow c $$ be three vectors such that $$\left| {\overrightarrow a } \right| = \sqrt 3 $$, $$\left| {\overrightarrow b } \right| = 5,\overrightarrow b .\overrightarrow c = 10$$ and the angle between $$\overrightarrow b $$ and $$\overrightarrow c $$ is $${\pi \over 3}$$. If $${\overrightarrow a }$$ is perpendicular to the vector $$\overrightarrow b \times \overrightarrow c $$ , then $$\left| {\overrightarrow a \times \left( {\overrightarrow b \times \overrightarrow c } \right)} \right|$$ is equal to _____.

The number of terms common to the two A.P.'s 3, 7, 11, ....., 407 and 2, 9, 16, ....., 709 is ______.

Starting at temperature 300 K, one mole of an
ideal diatomic gas ($$\gamma $$ = 1.4) is first compressed
adiabatically from volume V₁ to V₂ = $${{{V_1}} \over {16}}$$. It is
then allowed to expand isobarically to volume 2V₂. If all the processes are the quasi-static then
the final temperature of the gas (in ^oK) is (to the nearest integer) _____.

An electric field $$\overrightarrow E = 4x\widehat i - \left( {{y^2} + 1} \right)\widehat j$$ N/C
passes through the box shown in figure. The
flux of the electric field through surfaces ABCD
and BCGF are marked as $${\phi _I}$$ and $${\phi _{II}}$$
respectively. The difference between $$\left( {{\phi _I} - {\phi _{II}}} \right)$$ is (in Nm²/C) _______.

In a Young's double slit experiment 15 fringes are observed on a small portion of the screen when light of wavelength 500 nm is used. Ten fringes are observed on the same section of the screen when another light source of wavelength $$\lambda $$ is used. Then the value of $$\lambda $$ is (in nm) __________.

The circuit shown below is working as a 8 V dc regulated voltage source. When 12 V is used as input, the power dissipated (in mW) in each diode is; (considering both zener diodes are identical) _________.

In a meter bridge experiment S is a standard resistance. R is a resistance wire. It is found that balancing length is $$l$$ = 25 cm. If R is replaced by a wire of half length and half diameter that of R of same material, then the balancing distance $$l'$$ (in cm) will now be________.

Two steel wires having same length are suspended from a ceiling under the same load. If the ratio of their energy stored per unit volume is 1 : 4, the ratio of their diameters is:

For the four sets of three measured physical quantities as given below. Which of the following options is correct ?
(i) A₁ = 24.36, B₁ = 0.0724, C₁ = 256.2
(ii) A₂ = 24.44, B₂ = 16.082, C₂ = 240.2
(iii) A₃ = 25.2, B₃ = 19.2812, C₃ = 236.183
(iv) A₄ = 25, B₄ = 236.191, C₄ = 19.5

Planet A has mass M and radius R. Planet B has half the mass and half the radius of Planet A. If the escape velocities from the Planets A and B are v_A and v_B, respectively, then $${{{v_A}} \over {{v_B}}} = {n \over 4}$$. The value of n is :

An electron of mass m and magnitude of charge |e| initially at rest gets accelerated by a constant electric field E. The rate of change of de-Broglie wavelength of this electron at time t ignoring relativistic effects is :

A uniformly thick wheel with moment of inertia I and radius R is free to rotate about its centre of mass (see fig). A massless string is wrapped over its rim and two blocks of masses m₁ and m₂ (m₁ $$ > $$ m₂) are attached to the ends of the string. The system is released from rest. The angular speed of the wheel when m₁ descents by a distance h is :

Two identical capacitors A and B, charged to the same potential 5V are connected in two different circuits as shown below at time t = 0. If the charge on capacitors A and B at time t = CR is Q_A and Q_B respectively, then (Here e is the base of natural logarithm)

The energy required to ionise a hydrogen like ion in its ground state is 9 Rydbergs. What is the wavelength of the radiation emitted when the electron in this ion jumps from the second excited state to the ground state ?

Two gases-argon (atomic radius 0.07 nm, atomic weight 40) and xenon (atomic radius 0.1 nm, atomic weight 140) have the same number density and are at the same temperature. The raito of their respective mean free times is closest to :

An electron gun is placed inside a long solenoid of radius R on its axis. The solenoid has n turns/length and carries a current I. The electron gun shoots an electron along the radius of the solenoid with speed v. If the electron does not hit the surface of the solenoid, maximum possible value of v is (all symbols have their standard meaning) :

A particle of mass m is projected with a speed u from the ground at an angle $$\theta = {\pi \over 3}$$ w.r.t. horizontal (x-axis). When it has reached its maximum height, it collides completely inelastically with another particle of the same mass and velocity $$u\widehat i$$ . The horizontal distance covered by the combined mass before reaching the ground is:

A particle starts from the origin at t = 0 with an
initial velocity of 3.0 $$\widehat i$$ m/s and moves in the
x-y plane with a constant acceleration $$\left( {6\widehat i + 4\widehat j} \right)$$ m/s² . The x-coordinate of the particle at the instant when its y-coordinate is 32 m is D meters. The value of D is :-

There is a small source of light at some depth below the surface of water (refractive index = $${4 \over 3}$$) in a tank of large cross sectional surface area. Neglecting any reflection from the bottom and absorption by water, percentage of light that emerges out of surface is (nearly) :
[Use the fact that surface area of a spherical cap of height h and radius of curvature r is 2$$\pi $$rh]:

A small circular loop of conducting wire has radius a and carries current I. It is placed in a uniform magnetic field B perpendicular to its plane such that when rotated slightly about its diameter and released, it starts performing simple harmonic motion of time period T. If the mass of the loop is m then :

The current i in the network is :

A small spherical droplet of density d is floating exactly half immersed in a liquid of density $$\rho $$ and surface tension T. The radius of the droplet is (take note that the surface tension applies an upward force on the droplet) :

In LC circuit the inductance L = 40 mH and
capacitance C = 100 $$\mu $$F. If a voltage
V(t) = 10sin(314t) is applied to the circuit, the
current in the circuit is given as :

A plane electromagnetic wave is propagating along the direction $${{\widehat i + \widehat j} \over {\sqrt 2 }}$$ , with its polarization along the direction $$\widehat k$$ . The correct form of the magnetic field of the wave would be (here B₀ is an appropriate constant) :

A rod of length L has non-uniform linear mass
density given by $$\rho $$(x) = $$a + b{\left( {{x \over L}} \right)^2}$$ , where a
and b are constants and 0 $$ \le $$ x $$ \le $$ L. The value
of x for the centre of mass of the rod is at :

A wire of length L and mass per unit length 6.0 × 10^–3 kgm^–1 is put under tension of 540 N. Two consecutive frequencies that it resonates at are : 420 Hz and 490 Hz. Then L in meters is :

A spring mass system (mass m, spring constant k and natural length $$l$$) rest in equilibrium on a horizontal disc. The free end of the spring is fixed at the centre of the disc. If the disc together with spring mass system, rotates about it's axis with an angular velocity $$\omega $$, (k $$ \gg m{\omega ^2}$$) the relative change in the length of the spring is best given by the option :