The correct statements among I to III are :
(I) Valence bond theory cannot explain the color exhibited by transition metal complexes.
(II) Valence bond theory can predict quantitatively the magnetic properties of transtition metal complexes.
(III) Valence bond theory cannot distinguish ligands as weak and strong field ones.

A solution of Ni(NO₃)₂ is electrolysed between platinum electrodes using 0.1 Faraday electricity. How many mole of Ni will be deposited at the cathode?

The peptide that gives positive ceric ammonium nitrate and carbylamine tests is :

The correct statements among I to III regarding group 13 element oxides are,
(I) Boron trioxide is acidic.
(II) Oxides of aluminium and gallium are amphoteric.
(III) Oxides of indium and thalliumare basic.

Increasing order of reactivity of the following compounds for S_N1 substitution is:

Which of the following potential energy (PE) diagrams represents the S_N1 reaction?

Consider the given plot of enthalpy of the following reaction between A and B.
A+ B $$ \to $$ C + D
Identify the incorrect statement.

Among the following species, the diamagnetic molecule is

The maximum possible denticities of a ligand given below towards a common transition and inner-transition metal ion, respectively, are :

In the following reaction Rate of the reaction is the highest for :

The maximum number of possible oxidation states of actinoides are shown by :

Which one of the following about an electron occupying the 1s orbital in a hydrogen atom is incorrect ?

(The Bohr radius is represented by a₀)

HF has highest boiling point among hydrogen halides, because it has :

In an acid-base titration, 0.1 M HCl solution was added to the NaOH solution of unknown strength. Which of the following correctly shows the change of pH of the titraction mixture in this experiment?

What would be the molality of 20% (mass/ mass) aqueous solution of KI?
(molar mass of KI = 166 g mol^–1)

p-Hydroxybenzophenone upon reaction with bromine in carbon tetrachloride gives:

Hinsberg's reagent is :

The major products A and B for the following reactions are, respectively:

During compression of a spring the work done is 10kJ and 2kJ escaped to the surroundings as heat. The change in internal energy, $$\Delta $$U(inkJ) is :

Molal depression constant for a solvent is 4.0 kg mol^–1. The depression in the freezing point of the solvent for 0.03 mol kg^–1 solution of K₂SO₄ is :
(Assume complete dissociation of the electrolyte)

The major product of the following reaction is:

If the sum and product of the first three term in an A.P. are 33 and 1155, respectively, then a value of its 11^th term is :-

If $$\cos x{{dy} \over {dx}} - y\sin x = 6x$$, (0 < x < $${\pi \over 2}$$)
and $$y\left( {{\pi \over 3}} \right)$$ = 0 then $$y\left( {{\pi \over 6}} \right)$$ is equal to :-

If f : R $$ \to $$ R is a differentiable function and f(2) = 6,
then $$\mathop {\lim }\limits_{x \to 2} {{\int\limits_6^{f\left( x \right)} {2tdt} } \over {\left( {x - 2} \right)}}$$ is :-

The value of sin 10º sin30º sin50º sin70º is :-

The mean and the median of the following ten numbers in increasing order 10, 22, 26, 29, 34, x, 42, 67, 70, y are 42 and 35 respectively, then $${y \over x}$$ is equal to

Two newspapers A and B are published in a city. It is known that 25% of the city populations reads A and 20% reads B while 8% reads both A and B. Further, 30% of those who read A but not B look into advertisements and 40% of those who read B but not A also look into advertisements, while 50% of those who read both A and B look into advertisements. Then the percentage of the population who look into advertisement is :-

If m is chosen in the quadratic equation

(m² + 1) x² – 3x + (m² + 1)² = 0

such that the sum of its roots is greatest, then the absolute difference of the cubes of its roots is :-

If the function $$f(x) = \left\{ {\matrix{ {a|\pi - x| + 1,x \le 5} \cr {b|x - \pi | + 3,x > 5} \cr } } \right.$$
is continuous at x = 5, then the value of a – b is :-

The area (in sq. units) of the region
A = {(x, y) : $${{y{}^2} \over 2}$$ $$ \le $$ x $$ \le $$ y + 4} is :-

$$\int {{e^{\sec x}}}$$ $$(\sec x\tan xf(x) + \sec x\tan x + se{x^2}x)dx$$
= e^secxf(x) + C then a possible choice of f(x) is :-

The total number of matrices
$$A = \left( {\matrix{ 0 & {2y} & 1 \cr {2x} & y & { - 1} \cr {2x} & { - y} & 1 \cr } } \right)$$
(x, y $$ \in $$ R,x $$ \ne $$ y) for which A^TA = 3I₃ is :-

A rectangle is inscribed in a circle with a diameter lying along the line 3y = x + 7. If the two adjacent vertices of the rectangle are (–8, 5) and (6, 5), then the area of the rectangle (in sq. units) is :

The domain of the definition of the function

$$f(x) = {1 \over {4 - {x^2}}} + {\log _{10}}({x^3} - x)$$ is

If $$f(x) = [x] - \left[ {{x \over 4}} \right]$$ ,x $$ \in $$ 4 , where [x] denotes the greatest integer function, then

If a unit vector $$\overrightarrow a $$ makes angles $$\pi $$/3 with $$\widehat i$$ , $$\pi $$/ 4 with $$\widehat j$$ and $$\theta $$$$ \in $$(0, $$\pi $$) with $$\widehat k$$, then a value of $$\theta $$ is :-

The vertices B and C of a $$\Delta $$ABC lie on the line,

$${{x + 2} \over 3} = {{y - 1} \over 0} = {z \over 4}$$ such that BC = 5 units.

Then the area (in sq. units) of this triangle, given that the point A(1, –1, 2), is :

If the two lines x + (a – 1) y = 1 and 2x + a²y = 1 (a$$ \in $$R – {0, 1}) are perpendicular, then the distance of their point of intersection from the origin is :

Let z $$ \in $$ C be such that |z| < 1.

If $$\omega = {{5 + 3z} \over {5(1 - z)}}$$z, then :

A water tank has the shape of an inverted right circular cone, whose semi-vertical angle is $${\tan ^{ - 1}}\left( {{1 \over 2}} \right)$$. Water is poured into it at a constant rate of 5 cubic meter per minute. The the rate (in m/min.), at which the level of water is rising at the instant when the depth of water in the tank is 10m; is :-

If the system of equations 2x + 3y – z = 0, x + ky – 2z = 0 and 2x – y + z = 0 has a non-trival solution (x, y, z), then $${x \over y} + {y \over z} + {z \over x} + k$$ is equal to :-

The value of the integral $$\int\limits_0^1 {x{{\cot }^{ - 1}}(1 - {x^2} + {x^4})dx} $$ is :-

The parallel combination of two air filled parallel plate capacitors of capacitance C and nC is connected to a battery of voltage, V. When the capacitors are fully charged, the battery is removed and after that a dielectric material of dielectric constant K is placed between the two plates of the first capacitor. The new potential difference of the combined system is :-

Two materials having coefficients of thermal conductivity '3K' and 'K' and thickness 'd' and '3d', respectively, are joined to form a slab as shown in the figure. The temperatures of the outer surfaces are '$$\theta $$₂' and '$$\theta $$₁' respectively, ($$\theta $$₂ > $$\theta $$₁). The temperature at the interface is :-

In a conductor, if the number of conduction electrons per unit volume is 8.5 × 10²⁸ m^–3 and mean free time is 25ƒs (femto second), it's approximate resistivity is :-
(m_e = 9.1 × 10^–31 kg)

A particle of mass 'm' is moving with speed '2v' and collides with a mass '2m' moving with speed 'v' in the same direction. After collision, the first mass is stopped completely while the second one splits into two particles each of mass 'm', which move at angle 45° with respect to the origianl direction. The speed of each of the moving particle will be :-

A thin smooth rod of length L and mass M is rotating freely with angular speed $$\omega $$₀ about an axis perpendicular to the rod and passing through its center. Two beads of mass m and negligible size are at the center of the rod initially. The beads are free to slide along the rod. The angular speed of the system , when the beads reach the opposite ends of the rod, will be :-

The logic gate equivalent to the given logic circuit is :-

A metal wire of resistance 3 $$\Omega $$ is elongated to make a uniform wire of double its previous length. This new wire is now bent and the ends joined to make a circle. If two points on this circle make an angle 60° at the centre, the equivalent resistance between these two points will be :-

Two coils 'P' and 'Q' are separated by some distance. When a current of 3 A flows through coil 'P', a magnetic flux of 10^–3 Wb passes through 'Q'. No current is passed through 'Q'. When no current passes through 'P' and a current of 2 A passes through 'Q', the flux through 'P' is :-

A wooden block floating in a bucket of water has 4/5 of its volume submerged. When certain amount of an oil is poured into the bucket, it is found that the block is just under the oil surface with half of its volume under water and half in oil. The density of oil relative to that of water is :-

Moment of inertia of a body about a given axis is 1.5 kg m². Initially the body is at rest. In order to produce a rotational kinetic energy of 1200 J, the angular accleration of 20 rad/s² must be applied about the axis for a duration of :-

A test particle is moving in a circular orbit in the gravitational field produced by a mass density $$\rho (r) = {K \over {{r^2}}}$$ . Identify the correct relation between the radius R of the particle's orbit and its period T

A very long solenoid of radius R is carrying current I(t) = kte^–at(k > 0), as a function of time (t $$ \ge $$ 0). counter clockwise current is taken to be positive. A circular conducting coil of radius 2R is placed in the equatorial plane of the solenoid and concentric with the solenoid. The current induced in the outer coil is correctly depicted, as a function of time, by :-

The position vector of a particle changes with time according to the relation $$\overrightarrow r (t) = 15{t^2}\widehat i + (4 - 20{t^2})\widehat j$$
What is the magnitude of the acceleration at t = 1 ?

A massless spring (k = 800 N/m), attached with a mass (500 g) is completely immersed in 1 kg of water. The spring is stretched by 2 cm and released so that it starts vibrating. What would be the order of magnitude of the change in the temperature of water when the vibrations stop completely ? (Assume that the water container and spring receive negligible heat and specific heat of mass = 400 J/kg K, specific heat of water = 4184 J/kg K)

A wedge of mass M = 4m lies on a frictionless plane. A particle of mass m approaches the wedge with speed v. There is no friction between the particle and the plane or between the particle and the wedge. The maximum height climbed by the particle on the wedge is given by :-

Diameter of the objective lens of a telescope is 250 cm. For light of wavelength 600nm. coming from a distant object, the limit of resolution of the telescope is close to :-

A He⁺ ion is in its first excited state. Its ionization energy is :-

A moving coil galvanometer has a coil with 175 turns and area 1 cm². It uses a torsion band of torsion constant 10^–6 N-m/rad. The coil is placed in a maganetic field B parallel to its plane. The coil deflects by 1° for a current of 1 mA. The value of B (in Tesla) is approximately :-

The specific heats, C_P and C_V of a gas of diatomic molecules, A, are given (in units of J mol^–1 K^–1) by 29 and 22, respectively. Another gas of diatomic molecules, B, has the corresponding values 30 and 21. If they are treated as ideal gases, then :-

A thin convex lens L (refractive index = 1.5) is placed on a plane mirror M. When a pin is placed at A, such that OA = 18 cm, its real inverted image is formed at A itself, as shown in figure. When a liquid of refractive index μ1 is put between the lens and the mirror, The pin has to be moved to A', such that OA' = 27 cm, to get its inverted real image at A' itself. The value of μ₁ will be :-

50 W/m² energy density of sunlight is normally incident on the surface of a solar panel. Some part of incident energy (25%) is reflected from the surface and the rest is absorbed. The force exerted on 1m² surface area will be close to (c = 3 × 108 m/s) :-

The area of a square is 5.29 cm². The area of 7 such squares taking into account the significant figures is :-

A particle 'P' is formed due to a completely inelastic collision of particles 'x' and 'y' having de-Broglie wavelengths '$$\lambda $$_x' and '$$\lambda $$_y' respectively. If x and y were moving in opposite directions, then the de-Broglie wavelength of 'P' is :-

A convex lens of focal length 20 cm produces images of the same magnification 2 when an object is kept at two distances x₁ and x₂ (x₁ > x₂) from the lens. The ratio of x₁ and x₂ is :-

The position of a particle as a function of time t, is given by
x(t) = at + bt² – ct³
where a, b and c are constants. When the particle attains zero acceleration, then its velocity will be :

The resistance of a galvanometer is 50 ohm and the maximum current which can be passed through it is 0.002 A. What resistance must be connected to it in order to convert it into an ammeter of range 0 – 0.5 A ?

A string 2.0 m long and fixed at its ends is driven by a 240 Hz vibrator. The string vibrates in its third harmonic mode. The speed of the wave and its fundamental frequency is :-

Four point charges –q, +q, +q and –q are placed on y-axis at y = –2d, y = –d, y = +d and y = +2d, respectively. The magnitude of the electric field E at a point on the x-axis at x = D, with D >> d, will behave as :-