Which of the following pair of molecules contain odd electron molecule and an expanded octet molecule?

$$ \mathrm{N}_{2(\mathrm{~g})}+3 \mathrm{H}_{2(\mathrm{~g})} \rightleftharpoons 2 \mathrm{NH}_{3(\mathrm{~g})} $$

$$20 \mathrm{~g} \quad ~~~5 \mathrm{~g}$$

Consider the above reaction, the limiting reagent of the reaction and number of moles of $$\mathrm{NH}_{3}$$ formed respectively are :

The first ionization enthalpy of Na, Mg and Si, respectively, are : 496, 737 and $$786 \mathrm{~kJ} \mathrm{~mol}^{-1}$$. The first ionization enthalpy ($$\mathrm{kJ} \,\mathrm{mol}^{-1}$$) of $$\mathrm{Al}$$ is :

The reaction of zinc with excess of aqueous alkali, evolves hydrogen gas and gives :

Number of lone pairs of electrons in the central atom of $$\mathrm{SCl}_{2}, \mathrm{O}_{3}, \mathrm{ClF}_{3}$$ and $$\mathrm{SF}_{6}$$, respectively, are :

In following pairs, the one in which both transition metal ions are colourless is :

In neutral or faintly alkaline medium, $$\mathrm{KMnO}_{4}$$ being a powerful oxidant can oxidize, thiosulphate almost quantitatively, to sulphate. In this reaction overall change in oxidation state of manganese will be :

Which among the following is the strongest Bronsted base?

Which among the following pairs of the structures will give different products on ozonolysis? (Consider the double bonds in the structures are rigid and not delocalized.)

Considering the above reactions, the compound 'A' and compound 'B' respectively are :

Consider the above reaction sequence, the Product 'C' is :

Consider the above reaction, the compound 'A' is :

Which among the following represent reagent 'A'?

Consider the following reaction sequence:

The product 'B' is :

A compound 'X' is acidic and it is soluble in NaOH solution, but insoluble in NaHCO₃ solution. Compound 'X' also gives violet colour with neutral FeCl₃ solution. The compound 'X' is :

Resistance of a conductivity cell (cell constant $$129 \mathrm{~m}^{-1}$$) filled with $$74.5 \,\mathrm{ppm}$$ solution of $$\mathrm{KCl}$$ is $$100 \,\Omega$$ (labelled as solution 1). When the same cell is filled with $$\mathrm{KCl}$$ solution of $$149 \,\mathrm{ppm}$$, the resistance is $$50 \,\Omega$$ (labelled as solution 2). The ratio of molar conductivity of solution 1 and solution 2 is i.e. $$\frac{\wedge_{1}}{\wedge_{2}}=x \times 10^{-3}$$. The value of $$x$$ is __________. (Nearest integer)

Given, molar mass of $$\mathrm{KCl}$$ is $$74.5 \mathrm{~g} \mathrm{~mol}^{-1}$$.

The minimum uncertainty in the speed of an electron in an one dimensional region of length $$2 \mathrm{a}_{\mathrm{o}}$$ (Where $$\mathrm{a}_{\mathrm{o}}=$$ Bohr radius $$52.9 \,\mathrm{pm}$$) is _________ $$\mathrm{km} \,\mathrm{s}^{-1}$$.

(Given : Mass of electron = 9.1 $$\times$$ 10^$$-$$31 kg, Planck's constant h = 6.63 $$\times$$ 10^$$-$$34 Js)

When 600 mL of 0.2 M HNO₃ is mixed with $$400 \mathrm{~mL}$$ of 0.1 M NaOH solution in a flask, the rise in temperature of the flask is ___________ $$\times 10^{-2}{ }\,^{\circ} \mathrm{C}$$.

(Enthalpy of neutralisation $$=57 \mathrm{~kJ} \mathrm{~mol}^{-1}$$ and Specific heat of water $$=4.2 \,\mathrm{JK}^{-1} \mathrm{~g}^{-1}$$) (Neglect heat capacity of flask)

If $$\mathrm{O}_{2}$$ gas is bubbled through water at $$303 \mathrm{~K}$$, the number of millimoles of $$\mathrm{O}_{2}$$ gas that dissolve in 1 litre of water is __________. (Nearest Integer)

(Given : Henry's Law constant for $$\mathrm{O}_{2}$$ at $$303 \mathrm{~K}$$ is $$46.82 \,\mathrm{k}$$ bar and partial pressure of $$\mathrm{O}_{2}=0.920$$ bar)

(Assume solubility of $$\mathrm{O}_{2}$$ in water is too small, nearly negligible)

If the solubility product of PbS is 8 $$\times$$ 10^$$-$$28, then the solubility of PbS in pure water at 298 K is x $$\times$$ 10^$$-$$16 mol L^$$-$$1. The value of x is __________. (Nearest Integer)

[Given : $$\sqrt2$$ = 1.41]

The reaction between X and Y is first order with respect to X and zero order with respect to Y.

Examine the data of table and calculate ratio of numerical values of M and L. (Nearest Integer)

In a linear tetrapeptide (Constituted with different amino acids), (number of amino acids) $$-$$ (number of peptide bonds) is ________.

In bromination of Propyne, with Bromine, 1, 1, 2, 2-tetrabromopropane is obtained in 27% yield. The amount of 1, 1, 2, 2-tetrabromopropane obtained from 1 g of Bromine in this reaction is ___________ $$\times$$ 10^$$-$$1 g. (Nearest integer)

(Molar Mass : Bromine = 80 g/mol)

$$\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{3-}$$ should be an inner orbital complex. Ignoring the pairing energy, the value of crystal field stabilization energy for this complex is $$(-)$$ ____________ $$\Delta_{0}$$. (Nearest integer)

Let R be a relation from the set $$\{1,2,3, \ldots, 60\}$$ to itself such that $$R=\{(a, b): b=p q$$, where $$p, q \geqslant 3$$ are prime numbers}. Then, the number of elements in R is :

If $$z=2+3 i$$, then $$z^{5}+(\bar{z})^{5}$$ is equal to :

Let A and B be two $$3 \times 3$$ non-zero real matrices such that AB is a zero matrix. Then

If $$\frac{1}{(20-a)(40-a)}+\frac{1}{(40-a)(60-a)}+\ldots+\frac{1}{(180-a)(200-a)}=\frac{1}{256}$$, then the maximum value of $$\mathrm{a}$$ is :

If $$\lim\limits_{x \rightarrow 0} \frac{\alpha \mathrm{e}^{x}+\beta \mathrm{e}^{-x}+\gamma \sin x}{x \sin ^{2} x}=\frac{2}{3}$$, where $$\alpha, \beta, \gamma \in \mathbf{R}$$, then which of the following is NOT correct?

The integral $$\int\limits_{0}^{\frac{\pi}{2}} \frac{1}{3+2 \sin x+\cos x} \mathrm{~d} x$$ is equal to :

Let the solution curve $$y=y(x)$$ of the differential equation $$\left(1+\mathrm{e}^{2 x}\right)\left(\frac{\mathrm{d} y}{\mathrm{~d} x}+y\right)=1$$ pass through the point $$\left(0, \frac{\pi}{2}\right)$$. Then, $$\lim\limits_{x \rightarrow \infty} \mathrm{e}^{x} y(x)$$ is equal to :

Let a line L pass through the point of intersection of the lines $$b x+10 y-8=0$$ and $$2 x-3 y=0, \mathrm{~b} \in \mathbf{R}-\left\{\frac{4}{3}\right\}$$. If the line $$\mathrm{L}$$ also passes through the point $$(1,1)$$ and touches the circle $$17\left(x^{2}+y^{2}\right)=16$$, then the eccentricity of the ellipse $$\frac{x^{2}}{5}+\frac{y^{2}}{\mathrm{~b}^{2}}=1$$ is :

Let the circumcentre of a triangle with vertices A(a, 3), B(b, 5) and C(a, b), ab > 0 be P(1,1). If the line AP intersects the line BC at the point Q$$\left(k_{1}, k_{2}\right)$$, then $$k_{1}+k_{2}$$ is equal to :

Let $$\hat{a}$$ and $$\hat{b}$$ be two unit vectors such that the angle between them is $$\frac{\pi}{4}$$. If $$\theta$$ is the angle between the vectors $$(\hat{a}+\hat{b})$$ and $$(\hat{a}+2 \hat{b}+2(\hat{a} \times \hat{b}))$$, then the value of $$164 \,\cos ^{2} \theta$$ is equal to :

If $$f(\alpha)=\int\limits_{1}^{\alpha} \frac{\log _{10} \mathrm{t}}{1+\mathrm{t}} \mathrm{dt}, \alpha>0$$, then $$f\left(\mathrm{e}^{3}\right)+f\left(\mathrm{e}^{-3}\right)$$ is equal to :

The area of the region

$$\left\{(x, y):|x-1| \leq y \leq \sqrt{5-x^{2}}\right\}$$ is equal to :

Let the focal chord of the parabola $$\mathrm{P}: y^{2}=4 x$$ along the line $$\mathrm{L}: y=\mathrm{m} x+\mathrm{c}, \mathrm{m}>0$$ meet the parabola at the points M and N. Let the line L be a tangent to the hyperbola $$\mathrm{H}: x^{2}-y^{2}=4$$. If O is the vertex of P and F is the focus of H on the positive x-axis, then the area of the quadrilateral OMFN is :

The number of points, where the function $$f: \mathbf{R} \rightarrow \mathbf{R}$$,

$$f(x)=|x-1| \cos |x-2| \sin |x-1|+(x-3)\left|x^{2}-5 x+4\right|$$, is NOT differentiable, is :

Let $$S=\{1,2,3, \ldots, 2022\}$$. Then the probability, that a randomly chosen number n from the set S such that $$\mathrm{HCF}\,(\mathrm{n}, 2022)=1$$, is :

Let $$f(x)=3^{\left(x^{2}-2\right)^{3}+4}, x \in \mathrm{R}$$. Then which of the following statements are true?

$$\mathrm{P}: x=0$$ is a point of local minima of $$f$$

$$\mathrm{Q}: x=\sqrt{2}$$ is a point of inflection of $$f$$

$$R: f^{\prime}$$ is increasing for $$x>\sqrt{2}$$

Let the mean and the variance of 20 observations $$x_{1}, x_{2}, \ldots, x_{20}$$ be 15 and 9 , respectively. For $$\alpha \in \mathbf{R}$$, if the mean of $$\left(x_{1}+\alpha\right)^{2},\left(x_{2}+\alpha\right)^{2}, \ldots,\left(x_{20}+\alpha\right)^{2}$$ is 178 , then the square of the maximum value of $$\alpha$$ is equal to ________.

Let $$a_{1}, a_{2}, a_{3}, \ldots$$ be an A.P. If $$\sum\limits_{r=1}^{\infty} \frac{a_{r}}{2^{r}}=4$$, then $$4 a_{2}$$ is equal to _________.

Let the ratio of the fifth term from the beginning to the fifth term from the end in the binomial expansion of $$\left(\sqrt[4]{2}+\frac{1}{\sqrt[4]{3}}\right)^{\mathrm{n}}$$, in the increasing powers of $$\frac{1}{\sqrt[4]{3}}$$ be $$\sqrt[4]{6}: 1$$. If the sixth term from the beginning is $$\frac{\alpha}{\sqrt[4]{3}}$$, then $$\alpha$$ is equal to _________.

The number of matrices of order $$3 \times 3$$, whose entries are either 0 or 1 and the sum of all the entries is a prime number, is __________.

Let p and p + 2 be prime numbers and let

$$ \Delta=\left|\begin{array}{ccc} \mathrm{p} ! & (\mathrm{p}+1) ! & (\mathrm{p}+2) ! \\ (\mathrm{p}+1) ! & (\mathrm{p}+2) ! & (\mathrm{p}+3) ! \\ (\mathrm{p}+2) ! & (\mathrm{p}+3) ! & (\mathrm{p}+4) ! \end{array}\right| $$

Then the sum of the maximum values of $$\alpha$$ and $$\beta$$, such that $$\mathrm{p}^{\alpha}$$ and $$(\mathrm{p}+2)^{\beta}$$ divide $$\Delta$$, is __________.

Let $$S=\{4,6,9\}$$ and $$T=\{9,10,11, \ldots, 1000\}$$. If $$A=\left\{a_{1}+a_{2}+\ldots+a_{k}: k \in \mathbf{N}, a_{1}, a_{2}, a_{3}, \ldots, a_{k}\right.$$ $$\epsilon S\}$$, then the sum of all the elements in the set $$T-A$$ is equal to __________.

Let the mirror image of a circle $$c_{1}: x^{2}+y^{2}-2 x-6 y+\alpha=0$$ in line $$y=x+1$$ be $$c_{2}: 5 x^{2}+5 y^{2}+10 g x+10 f y+38=0$$. If $$\mathrm{r}$$ is the radius of circle $$\mathrm{c}_{2}$$, then $$\alpha+6 \mathrm{r}^{2}$$ is equal to ________.

Given below are two statements : One is labelled as Assertion (A) and other is labelled as Reason (R).

Assertion (A) : Time period of oscillation of a liquid drop depends on surface tension (S), if density of the liquid is $$\rho$$ and radius of the drop is r, then $$\mathrm{T}=\mathrm{K} \sqrt{\rho \mathrm{r}^{3} / \mathrm{S}^{3 / 2}}$$ is dimensionally correct, where K is dimensionless.

Reason (R) : Using dimensional analysis we get R.H.S. having different dimension than that of time period.

In the light of above statements, choose the correct answer from the options given below.

A ball is thrown up vertically with a certain velocity so that, it reaches a maximum height h. Find the ratio of the times in which it is at height $$\frac{h}{3}$$ while going up and coming down respectively.

If $$\mathrm{t}=\sqrt{x}+4$$, then $$\left(\frac{\mathrm{d} x}{\mathrm{~d} t}\right)_{\mathrm{t}=4}$$ is :

A smooth circular groove has a smooth vertical wall as shown in figure. A block of mass m moves against the wall with a speed v. Which of the following curve represents the correct relation between the normal reaction on the block by the wall (N) and speed of the block (v) ?

A ball is projected with kinetic energy E, at an angle of $$60^{\circ}$$ to the horizontal. The kinetic energy of this ball at the highest point of its flight will become :

Two bodies of mass $$1 \mathrm{~kg}$$ and $$3 \mathrm{~kg}$$ have position vectors $$\hat{i}+2 \hat{j}+\hat{k}$$ and $$-3 \hat{i}-2 \hat{j}+\hat{k}$$ respectively. The magnitude of position vector of centre of mass of this system will be similar to the magnitude of vector :

Given below are two statements : One is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A): Clothes containing oil or grease stains cannot be cleaned by water wash.

Reason (R): Because the angle of contact between the oil/grease and water is obtuse.

In the light of the above statements, choose the correct answer from the option given below.

If the length of a wire is made double and radius is halved of its respective values. Then, the Young's modulus of the material of the wire will :

The time period of oscillation of a simple pendulum of length L suspended from the roof of a vehicle, which moves without friction down an inclined plane of inclination $$\alpha$$, is given by :

A spherically symmetric charge distribution is considered with charge density varying as

$$\rho(r)= \begin{cases}\rho_{0}\left(\frac{3}{4}-\frac{r}{R}\right) & \text { for } r \leq R \\ \text { zero } & \text { for } r>R\end{cases}$$

Where, $$r(r < R)$$ is the distance from the centre O (as shown in figure). The electric field at point P will be:

Given below are two statements.

Statement I : Electric potential is constant within and at the surface of each conductor.

Statement II : Electric field just outside a charged conductor is perpendicular to the surface of the conductor at every point.

In the light of the above statements, choose the most appropriate answer from the options given below.

Two metallic wires of identical dimensions are connected in series. If $$\sigma_{1}$$ and $$\sigma_{2}$$ are the conductivities of the these wires respectively, the effective conductivity of the combination is :

An alternating emf $$\mathrm{E}=440 \sin 100 \pi \mathrm{t}$$ is applied to a circuit containing an inductance of $$\frac{\sqrt{2}}{\pi} \mathrm{H}$$. If an a.c. ammeter is connected in the circuit, its reading will be :

A coil of inductance 1 H and resistance $$100 \,\Omega$$ is connected to a battery of 6 V. Determine approximately :

(a) The time elapsed before the current acquires half of its steady - state value.

(b) The energy stored in the magnetic field associated with the coil at an instant 15 ms after the circuit is switched on. (Given $$\ln 2=0.693, \mathrm{e}^{-3 / 2}=0.25$$)

Match List - I with List - II :

Choose the correct answer from the options given below :

The kinetic energy of emitted electron is E when the light incident on the metal has wavelength $$\lambda$$. To double the kinetic energy, the incident light must have wavelength:

Find the ratio of energies of photons produced due to transition of an electron of hydrogen atom from its (i) second permitted energy level to the first level, and (ii) the highest permitted energy level to the first permitted level.

A travelling microscope has 20 divisions per $$\mathrm{cm}$$ on the main scale while its vernier scale has total 50 divisions and 25 vernier scale divisions are equal to 24 main scale divisions, what is the least count of the travelling microscope?

In an experiment to find out the diameter of wire using screw gauge, the following observations were noted :

(A) Screw moves $$0.5 \mathrm{~mm}$$ on main scale in one complete rotation

(B) Total divisions on circular scale $$=50$$

(C) Main scale reading is $$2.5 \mathrm{~mm}$$

(D) $$45^{\text {th }}$$ division of circular scale is in the pitch line

(E) Instrument has 0.03 mm negative error

Then the diameter of wire is :

An object is projected in the air with initial velocity u at an angle $$\theta$$. The projectile motion is such that the horizontal range R, is maximum. Another object is projected in the air with a horizontal range half of the range of first object. The initial velocity remains same in both the case. The value of the angle of projection, at which the second object is projected, will be _________ degree.

If the acceleration due to gravity experienced by a point mass at a height h above the surface of earth is same as that of the acceleration due to gravity at a depth $$\alpha \mathrm{h}\left(\mathrm{h}<<\mathrm{R}_{\mathrm{e}}\right)$$ from the earth surface. The value of $$\alpha$$ will be _________.

(use $$\left.\mathrm{R}_{\mathrm{e}}=6400 \mathrm{~km}\right)$$

The pressure $$\mathrm{P}_{1}$$ and density $$\mathrm{d}_{1}$$ of diatomic gas $$\left(\gamma=\frac{7}{5}\right)$$ changes suddenly to $$\mathrm{P}_{2}\left(>\mathrm{P}_{1}\right)$$ and $$\mathrm{d}_{2}$$ respectively during an adiabatic process. The temperature of the gas increases and becomes ________ times of its initial temperature. (given $$\frac{\mathrm{d}_{2}}{\mathrm{~d}_{1}}=32$$)

One mole of a monoatomic gas is mixed with three moles of a diatomic gas. The molecular specific heat of mixture at constant volume is $$\frac{\alpha^{2}}{4} \mathrm{R} \,\mathrm{J} / \mathrm{mol} \,\mathrm{K}$$; then the value of $$\alpha$$ will be _________. (Assume that the given diatomic gas has no vibrational mode).

The current I flowing through the given circuit will be __________A.

A closely wounded circular coil of radius 5 cm produces a magnetic field of $$37.68 \times 10^{-4} \mathrm{~T}$$ at its center. The current through the coil is _________A.

[Given, number of turns in the coil is 100 and $$\pi=3.14$$]

Two light beams of intensities 4I and 9I interfere on a screen. The phase difference between these beams on the screen at point A is zero and at point B is $$\pi$$. The difference of resultant intensities, at the point A and B, will be _________ I.

A wire of length $$314 \mathrm{~cm}$$ carrying current of $$14 \mathrm{~A}$$ is bent to form a circle. The magnetic moment of the coil is ________ A $$-\mathrm{m}^{2}$$. [Given $$\pi=3.14$$]

The X-Y plane be taken as the boundary between two transparent media $$\mathrm{M}_{1}$$ and $$\mathrm{M}_{2}$$. $$\mathrm{M}_{1}$$ in $$Z \geqslant 0$$ has a refractive index of $$\sqrt{2}$$ and $$M_{2}$$ with $$Z<0$$ has a refractive index of $$\sqrt{3}$$. A ray of light travelling in $$\mathrm{M}_{1}$$ along the direction given by the vector $$\overrightarrow{\mathrm{P}}=4 \sqrt{3} \hat{i}-3 \sqrt{3} \hat{j}-5 \hat{k}$$, is incident on the plane of separation. The value of difference between the angle of incident in $$\mathrm{M}_{1}$$ and the angle of refraction in $$\mathrm{M}_{2}$$ will be __________ degree.

If the potential barrier across a p-n junction is $$0.6 \mathrm{~V}$$. Then the electric field intensity, in the depletion region having the width of $$6 \times 10^{-6} \mathrm{~m}$$, will be __________ $$\times 10^{5} \mathrm{~N} / \mathrm{C}$$.