In which of the following processes, the bond order increases and paramagnetic character changes to diamagnetic one ?

Which of the following statements are not correct?

A. The electron gain enthalpy of $$\mathrm{F}$$ is more negative than that of $$\mathrm{Cl}$$.

B. Ionization enthalpy decreases in a group of periodic table.

C. The electronegativity of an atom depends upon the atoms bonded to it.

D. $$\mathrm{Al}_{2} \mathrm{O}_{3}$$ and $$\mathrm{NO}$$ are examples of amphoteric oxides.

Choose the most appropriate answer from the options given below :

In the following reaction 'X' is

In the reaction given below

'A' is

The mismatched combinations are

A. Chlorophyll - Co

B. Water hardness - EDTA

C. Photography $$-\left[\mathrm{Ag}(\mathrm{CN})_{2}\right]^{-}$$

D. Wilkinson catalyst $$-\left[\left(\mathrm{Ph}_{3} \mathrm{P}\right)_{3} \mathrm{RhCl}\right]$$

E. Chelating ligand - D-Penicillamine

Choose the correct answer from the options given below :

Among the following compounds, the one which shows highest dipole moment is

2-Methyl propyl bromide reacts with $$\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{O}^{-}$$ and gives 'A' whereas on reaction with $$\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}$$ it gives 'B'. The mechanism followed in these reactions and the products 'A' and 'B' respectively are :

The pair of lanthanides in which both elements have high third - ionization energy is :

In the reaction given below

'B' is

In the above reaction, left hand side and right hand side rings are named as '$$\mathrm{A}$$' and 'B' respectively. They undergo ring expansion. The correct statement for this process is:

The products formed in the above reaction are

The energy of an electron in the first Bohr orbit of hydrogen atom is $$-2.18 \times 10^{-18} \mathrm{~J}$$. Its energy in the third Bohr orbit is ____________.

$$\mathrm{KMnO}_{4}$$ is titrated with ferrous ammonium sulphate hexahydrate in presence of dilute $$\mathrm{H}_{2} \mathrm{SO}_{4}$$. Number of water molecules produced for 2 molecules of $$\mathrm{KMnO}_{4}$$ is ___________.

An organic compound gives $$0.220 \mathrm{~g}$$ of $$\mathrm{CO}_{2}$$ and $$0.126 \mathrm{~g}$$ of $$\mathrm{H}_{2} \mathrm{O}$$ on complete combustion. If the $$\%$$ of carbon is 24 then the $$\%$$ of hydrogen is __________ $$\times 10^{-1}$$. ( Nearest integer)

$$\mathrm{t}_{87.5}$$ is the time required for the reaction to undergo $$87.5 \%$$ completion and $$\mathrm{t}_{50}$$ is the time required for the reaction to undergo $$50 \%$$ completion. The relation between $$\mathrm{t}_{87.5}$$ and $$\mathrm{t}_{50}$$ for a first order reaction is $$\mathrm{t}_{87.5}=x \times \mathrm{t}_{50}$$ The value of $$x$$ is ___________. (Nearest integer)

For the given reaction

The total number of possible products formed by tertiary carbocation of A is ____________.

$$20 \mathrm{~mL}$$ of calcium hydroxide was consumed when it was reacted with $$10 \mathrm{~mL}$$ of unknown solution of $$\mathrm{H}_{2} \mathrm{SO}_{4}$$. Also $$20 \mathrm{~mL}$$ standard solution of $$0.5 ~\mathrm{M} ~\mathrm{HCl}$$ containing 2 drops of phenolphthalein was titrated with calcium hydroxide, the mixture showed pink colour when burette displayed the value of $$35.5 \mathrm{~mL}$$ whereas the burette showed $$25.5 \mathrm{~mL}$$ initially. The concentration of $$\mathrm{H}_{2} \mathrm{SO}_{4}$$ is _____________ M. (Nearest integer)

Solution of $$12 \mathrm{~g}$$ of non-electrolyte (A) prepared by dissolving it in $$1000 \mathrm{~mL}$$ of water exerts the same osmotic pressure as that of $$0.05 ~\mathrm{M}$$ glucose solution at the same temperature. The empirical formula of $$\mathrm{A}$$ is $$\mathrm{CH}_{2} \mathrm{O}$$. The molecular mass of $$\mathrm{A}$$ is __________ g. (Nearest integer)

A metal surface of $$100 \mathrm{~cm}^{2}$$ area has to be coated with nickel layer of thickness $$0.001 \mathrm{~mm}$$. A current of $$2 \mathrm{~A}$$ was passed through a solution of $$\mathrm{Ni}\left(\mathrm{NO}_{3}\right)_{2}$$ for '$$\mathrm{x}$$' seconds to coat the desired layer. The value of $$\mathrm{x}$$ is __________. (Nearest integer) ( $$\rho_{\mathrm{Ni}}$$ (density of Nickel) is $$10 \mathrm{~g} \mathrm{~mL}$$, Molar mass of Nickel is $$60 \mathrm{~g} \mathrm{~mol}^{-1}$$ $$\left.\mathrm{F}=96500 ~\mathrm{C} ~\mathrm{mol}^{-1}\right)$$

$$\mathrm{A}_{2}+\mathrm{B}_{2} \rightarrow 2 \mathrm{AB} . \Delta H_{f}^{0}=-200 \mathrm{~kJ} \mathrm{~mol}^{-1}$$

$$\mathrm{AB}, \mathrm{A}_{2}$$ and $$\mathrm{B}_{2}$$ are diatomic molecules. If the bond enthalpies of $$\mathrm{A}_{2}, \mathrm{~B}_{2}$$ and $$\mathrm{AB}$$ are in the ratio $$1: 0.5: 1$$, then the bond enthalpy of $$\mathrm{A}_{2}$$ is ____________ $$\mathrm{kJ} ~\mathrm{mol}^{-1}$$ (Nearest integer)

$$25.0 \mathrm{~mL}$$ of $$0.050 ~\mathrm{M} ~\mathrm{Ba}\left(\mathrm{NO}_{3}\right)_{2}$$ is mixed with $$25.0 \mathrm{~mL}$$ of $$0.020 ~\mathrm{M} ~\mathrm{NaF} . \mathrm{K}_{\mathrm{Sp}}$$ of $$\mathrm{BaF}_{2}$$ is $$0.5 \times 10^{-6}$$ at $$298 \mathrm{~K}$$. The ratio of $$\left[\mathrm{Ba}^{2+}\right]\left[\mathrm{F}^{-}\right]^{2}$$ and $$\mathrm{K}_{\mathrm{sp}}$$ is ___________.

(Nearest integer)

The area of the region enclosed by the curve $$f(x)=\max \{\sin x, \cos x\},-\pi \leq x \leq \pi$$ and the $$x$$-axis is

Let $$\mathrm{PQ}$$ be a focal chord of the parabola $$y^{2}=36 x$$ of length 100 , making an acute angle with the positive $$x$$-axis. Let the ordinate of $$\mathrm{P}$$ be positive and $$\mathrm{M}$$ be the point on the line segment PQ such that PM : MQ = 3 : 1. Then which of the following points does NOT lie on the line passing through M and perpendicular to the line $$\mathrm{PQ}$$?

Let $$\vec{a}=\hat{i}+4 \hat{j}+2 \hat{k}, \vec{b}=3 \hat{i}-2 \hat{j}+7 \hat{k}$$ and $$\vec{c}=2 \hat{i}-\hat{j}+4 \hat{k}$$. If a vector $$\vec{d}$$ satisfies $$\vec{d} \times \vec{b}=\vec{c} \times \vec{b}$$ and $$\vec{d} \cdot \vec{a}=24$$, then $$|\vec{d}|^{2}$$ is equal to :

For the system of linear equations

$$2 x+4 y+2 a z=b$$

$$x+2 y+3 z=4$$

$$2 x-5 y+2 z=8$$

which of the following is NOT correct?

Let $$y=y_{1}(x)$$ and $$y=y_{2}(x)$$ be the solution curves of the differential equation $$\frac{d y}{d x}=y+7$$ with initial conditions $$y_{1}(0)=0$$ and $$y_{2}(0)=1$$ respectively. Then the curves $$y=y_{1}(x)$$ and $$y=y_{2}(x)$$ intersect at

A coin is biased so that the head is 3 times as likely to occur as tail. This coin is tossed until a head or three tails occur. If $$\mathrm{X}$$ denotes the number of tosses of the coin, then the mean of $$\mathrm{X}$$ is :

The set of all $$a \in \mathbb{R}$$ for which the equation $$x|x-1|+|x+2|+a=0$$ has exactly one real root, is :

$$\int_\limits{0}^{\infty} \frac{6}{e^{3 x}+6 e^{2 x}+11 e^{x}+6} d x=$$

Let $$s_{1}, s_{2}, s_{3}, \ldots, s_{10}$$ respectively be the sum to 12 terms of 10 A.P. s whose first terms are $$1,2,3, \ldots .10$$ and the common differences are $$1,3,5, \ldots \ldots, 19$$ respectively. Then $$\sum_\limits{i=1}^{10} s_{i}$$ is equal to :

Let $$B=\left[\begin{array}{lll}1 & 3 & \alpha \\ 1 & 2 & 3 \\ \alpha & \alpha & 4\end{array}\right], \alpha > 2$$ be the adjoint of a matrix $$A$$ and $$|A|=2$$. Then $$\left[\begin{array}{ccc}\alpha & -2 \alpha & \alpha\end{array}\right] B\left[\begin{array}{c}\alpha \\ -2 \alpha \\ \alpha\end{array}\right]$$ is equal to :

Fractional part of the number $$\frac{4^{2022}}{15}$$ is equal to

For $$x \in \mathbb{R}$$, two real valued functions $$f(x)$$ and $$g(x)$$ are such that, $$g(x)=\sqrt{x}+1$$ and $$f \circ g(x)=x+3-\sqrt{x}$$. Then $$f(0)$$ is equal to

For the differentiable function $$f: \mathbb{R}-\{0\} \rightarrow \mathbb{R}$$, let $$3 f(x)+2 f\left(\frac{1}{x}\right)=\frac{1}{x}-10$$, then $$\left|f(3)+f^{\prime}\left(\frac{1}{4}\right)\right|$$ is equal to

$$\max _\limits{0 \leq x \leq \pi}\left\{x-2 \sin x \cos x+\frac{1}{3} \sin 3 x\right\}=$$

The number of symmetric matrices of order 3, with all the entries from the set $$\{0,1,2,3,4,5,6,7,8,9\}$$ is :

Let the mean of the data

be 5. If $$m$$ and $$\sigma^{2}$$ are respectively the mean deviation about the mean and the variance of the data, then $$\frac{3 \alpha}{m+\sigma^{2}}$$ is equal to __________

Let $$w=z \bar{z}+k_{1} z+k_{2} i z+\lambda(1+i), k_{1}, k_{2} \in \mathbb{R}$$. Let $$\operatorname{Re}(w)=0$$ be the circle $$\mathrm{C}$$ of radius 1 in the first quadrant touching the line $$y=1$$ and the $$y$$-axis. If the curve $$\operatorname{Im}(w)=0$$ intersects $$\mathrm{C}$$ at $$\mathrm{A}$$ and $$\mathrm{B}$$, then $$30(A B)^{2}$$ is equal to __________

The number of seven digit positive integers formed using the digits $$1,2,3$$ and $$4$$ only and sum of the digits equal to $$12$$ is ___________.

If $$S=\left\{x \in \mathbb{R}: \sin ^{-1}\left(\frac{x+1}{\sqrt{x^{2}+2 x+2}}\right)-\sin ^{-1}\left(\frac{x}{\sqrt{x^{2}+1}}\right)=\frac{\pi}{4}\right\}$$, then $$\sum_\limits{x \in s}\left(\sin \left(\left(x^{2}+x+5\right) \frac{\pi}{2}\right)-\cos \left(\left(x^{2}+x+5\right) \pi\right)\right)$$ is equal to ____________.

Let for $$x \in \mathbb{R}, S_{0}(x)=x, S_{k}(x)=C_{k} x+k \int_{0}^{x} S_{k-1}(t) d t$$, where

$$C_{0}=1, C_{k}=1-\int_{0}^{1} S_{k-1}(x) d x, k=1,2,3, \ldots$$ Then $$S_{2}(3)+6 C_{3}$$ is equal to ____________.

Let $$\vec{a}=3 \hat{i}+\hat{j}-\hat{k}$$ and $$\vec{c}=2 \hat{i}-3 \hat{j}+3 \hat{k}$$. If $$\vec{b}$$ is a vector such that $$\vec{a}=\vec{b} \times \vec{c}$$ and $$|\vec{b}|^{2}=50$$, then $$|72-| \vec{b}+\left.\vec{c}\right|^{2} \mid$$ is equal to __________.

Let $$\alpha$$ be the constant term in the binomial expansion of $$\left(\sqrt{x}-\frac{6}{x^{\frac{3}{2}}}\right)^{n}, n \leq 15$$. If the sum of the coefficients of the remaining terms in the expansion is 649 and the coefficient of $$x^{-n}$$ is $$\lambda \alpha$$, then $$\lambda$$ is equal to _____________.

Which graph represents the difference between total energy and potential energy of a particle executing SHM vs it's distance from mean position ?

A bullet of $$10 \mathrm{~g}$$ leaves the barrel of gun with a velocity of $$600 \mathrm{~m} / \mathrm{s}$$. If the barrel of gun is $$50 \mathrm{~cm}$$ long and mass of gun is $$3 \mathrm{~kg}$$, then value of impulse supplied to the gun will be :

A planet having mass $$9 \mathrm{Me}$$ and radius $$4 \mathrm{R}_{\mathrm{e}}$$, where $$\mathrm{Me}$$ and $$\mathrm{Re}$$ are mass and radius of earth respectively, has escape velocity in $$\mathrm{km} / \mathrm{s}$$ given by:

(Given escape velocity on earth $$\mathrm{V}_{\mathrm{e}}=11.2 \times 10^{3} \mathrm{~m} / \mathrm{s}$$ )

The figure shows a liquid of given density flowing steadily in horizontal tube of varying cross - section. Cross sectional areas at $$\mathrm{A}$$ is $$1.5 \mathrm{~cm}^{2}$$, and $$\mathrm{B}$$ is $$25 \mathrm{~mm}^{2}$$, if the speed of liquid at $$\mathrm{B}$$ is $$60 \mathrm{~cm} / \mathrm{s}$$ then $$\left(\mathrm{P}_{\mathrm{A}}-\mathrm{P}_{\mathrm{B}}\right)$$ is :

(Given $$\mathrm{P}_{\mathrm{A}}$$ and $$\mathrm{P}_{\mathrm{B}}$$ are liquid pressures at $$\mathrm{A}$$ and $$\mathrm{B}$$% points.

density $$\rho=1000 \mathrm{~kg} \mathrm{~m}^{-3}$$

$$\mathrm{A}$$ and $$\mathrm{B}$$ are on the axis of tube

A vessel of depth '$$d$$' is half filled with oil of refractive index $$n_{1}$$ and the other half is filled with water of refractive index $$n_{2}$$. The apparent depth of this vessel when viewed from above will be-

The difference between threshold wavelengths for two metal surfaces $$\mathrm{A}$$ and $$\mathrm{B}$$ having work function $$\phi_{A}=9 ~\mathrm{eV}$$ and $$\phi_{B}=4 \cdot 5 ~\mathrm{eV}$$ in $$\mathrm{nm}$$ is:

$$\{$$ Given, hc $$=1242 ~\mathrm{eV} \mathrm{nm}\}$$

The rms speed of oxygen molecule in a vessel at particular temperature is $$\left(1+\frac{5}{x}\right)^{\frac{1}{2}} v$$, where $$v$$ is the average speed of the molecule. The value of $$x$$ will be:

$$\left(\right.$$ Take $$\left.\pi=\frac{22}{7}\right)$$

The source of time varying magnetic field may be

(A) a permanent magnet

(B) an electric field changing linearly with time

(C) direct current

(D) a decelerating charge particle

(E) an antenna fed with a digital signal

Choose the correct answer from the options given below:

Two charges each of magnitude $$0.01 ~\mathrm{C}$$ and separated by a distance of $$0.4 \mathrm{~mm}$$ constitute an electric dipole. If the dipole is placed in an uniform electric field '$$\vec{E}$$' of 10 dyne/C making $$30^{\circ}$$ angle with $$\vec{E}$$, the magnitude of torque acting on dipole is:

A disc is rolling without slipping on a surface. The radius of the disc is $$R$$. At $$t=0$$, the top most point on the disc is $$\mathrm{A}$$ as shown in figure. When the disc completes half of its rotation, the displacement of point A from its initial position is

$$_{92}^{238}A \to _{90}^{234}B + _2^4D + Q$$

In the given nuclear reaction, the approximate amount of energy released will be:

[Given, mass of $${ }_{92}^{238} \mathrm{~A}=238.05079 \times 931.5 ~\mathrm{MeV} / \mathrm{c}^{2},$$

mass of $${ }_{90}^{234} B=234 \cdot 04363 \times 931 \cdot 5 ~\mathrm{MeV} / \mathrm{c}^{2},$$

mass of $$\left.{ }_{2}^{4} D=4 \cdot 00260 \times 931 \cdot 5 ~\mathrm{MeV} / \mathrm{c}^{2}\right]$$

Under isothermal condition, the pressure of a gas is given by $$\mathrm{P}=a \mathrm{~V}^{-3}$$, where $$a$$ is a constant and $$\mathrm{V}$$ is the volume of the gas. The bulk modulus at constant temperature is equal to

Two trains 'A' and 'B' of length '$$l$$' and '$$4 l$$' are travelling into a tunnel of length '$$\mathrm{L}$$' in parallel tracks from opposite directions with velocities $$108 \mathrm{~km} / \mathrm{h}$$ and $$72 \mathrm{~km} / \mathrm{h}$$, respectively. If train 'A' takes $$35 \mathrm{~s}$$ less time than train 'B' to cross the tunnel then. length '$$L$$' of tunnel is :

(Given $$\mathrm{L}=60 l$$ )

Which of the following Maxwell's equation is valid for time varying conditions but not valid for static conditions :

Different combination of 3 resistors of equal resistance $$\mathrm{R}$$ are shown in the figures. The increasing order for power dissipation is:

For the following circuit and given inputs A and B, choose the correct option for output '$$Y$$'

A body of mass $$(5 \pm 0.5) ~\mathrm{kg}$$ is moving with a velocity of $$(20 \pm 0.4) ~\mathrm{m} / \mathrm{s}$$. Its kinetic energy will be

The ratio of powers of two motors is $$\frac{3 \sqrt{x}}{\sqrt{x}+1}$$, that are capable of raising $$300 \mathrm{~kg}$$ water in 5 minutes and $$50 \mathrm{~kg}$$ water in 2 minutes respectively from a well of $$100 \mathrm{~m}$$ deep. The value of $$x$$ will be

Two bodies are having kinetic energies in the ratio 16 : 9. If they have same linear momentum, the ratio of their masses respectively is :

When a resistance of $$5 ~\Omega$$ is shunted with a moving coil galvanometer, it shows a full scale deflection for a current of $$250 \mathrm{~mA}$$, however when $$1050 ~\Omega$$ resistance is connected with it in series, it gives full scale deflection for 25 volt. The resistance of galvanometer is ____________ $$\Omega$$.

A fish rising vertically upward with a uniform velocity of $$8 \mathrm{~ms}^{-1}$$, observes that a bird is diving vertically downward towards the fish with the velocity of $$12 \mathrm{~ms}^{-1}$$. If the refractive index of water is $$\frac{4}{3}$$, then the actual velocity of the diving bird to pick the fish, will be __________ $$\mathrm{ms}^{-1}$$.

The radius of $$2^{\text {nd }}$$ orbit of $$\mathrm{He}^{+}$$ of Bohr's model is $$r_{1}$$ and that of fourth orbit of $$\mathrm{Be}^{3+}$$ is represented as $$r_{2}$$. Now the ratio $$\frac{r_{2}}{r_{1}}$$ is $$x: 1$$. The value of $$x$$ is ___________.

A potential $$\mathrm{V}_{0}$$ is applied across a uniform wire of resistance $$R$$. The power dissipation is $$P_{1}$$. The wire is then cut into two equal halves and a potential of $$V_{0}$$ is applied across the length of each half. The total power dissipation across two wires is $$P_{2}$$. The ratio $$P_{2}: \mathrm{P}_{1}$$ is $$\sqrt{x}: 1$$. The value of $$x$$ is ___________.

In the given figure, an inductor and a resistor are connected in series with a battery of emf E volt. $$\frac{E^{a}}{2 b} \mathrm{~J} / s$$ represents the maximum rate at which the energy is stored in the magnetic field (inductor). The numerical value of $$\frac{b}{a}$$ will be __________.

At a given point of time the value of displacement of a simple harmonic oscillator is given as $$\mathrm{y}=\mathrm{A} \cos \left(30^{\circ}\right)$$. If amplitude is $$40 \mathrm{~cm}$$ and kinetic energy at that time is $$200 \mathrm{~J}$$, the value of force constant is $$1.0 \times 10^{x} ~\mathrm{Nm}^{-1}$$. The value of $$x$$ is ____________.

A thin infinite sheet charge and an infinite line charge of respective charge densities $$+\sigma$$ and $$+\lambda$$ are placed parallel at $$5 \mathrm{~m}$$ distance from each other. Points 'P' and 'Q' are at $$\frac{3}{\pi}$$ m and $$\frac{4}{\pi}$$ m perpendicular distances from line charge towards sheet charge, respectively. '$$\mathrm{E}_{\mathrm{P}}$$' and '$$\mathrm{E}_{\mathrm{Q}}$$' are the magnitudes of resultant electric field intensities at point 'P' and 'Q', respectively. If $$\frac{E_{p}}{E_{0}}=\frac{4}{a}$$ for $$2|\sigma|=|\lambda|$$, then the value of $$a$$ is ___________.

A solid sphere is rolling on a horizontal plane without slipping. If the ratio of angular momentum about axis of rotation of the sphere to the total energy of moving sphere is $$\pi: 22$$ then, the value of its angular speed will be ____________ $$\mathrm{rad} / \mathrm{s}$$.

The elastic potential energy stored in a steel wire of length $$20 \mathrm{~m}$$ stretched through $$2 \mathrm{~cm}$$ is $$80 \mathrm{~J}$$. The cross sectional area of the wire is __________ $$\mathrm{mm}^{2}$$.

$$\left(\right.$$ Given, $$\left.y=2.0 \times 10^{11} \mathrm{Nm}^{-2}\right)$$