A binary liquid solution is prepared by mixing n-heptane and ethanol. Which one of the following statements is correct regarding the behaviour of the solution ?

The number of stereoisomers possible for a compound of the molecular formula CH₃ - CH = CH - CH(OH) - Me is :

The alkene that exhibits geometrical isomerism is :

The IUPAC name of neopentane is

Arrange the carbanions, $${(C{H_3})_3}\overline C $$, $$\overline C C{l_3}$$ , $${(C{H_3})_2}\overline C H$$, $${C_6}{H_5}\overline C H{}_2$$ in order of their decreasing stability :

Solid Ba(NO₃)₂ is gradually dissolved in a 1.0 $$\times$$ 10^-4 M Na₂CO₃ solution. At what concentration of Ba²⁺ will a precipitate begin to form ?
(K_sp for BaCO₃ = 5.1 $$\times$$ 10⁻⁹ )

On the basis of the following thermochemical data :
($$\Delta _fG^oH^+_{(aq)}$$ = 0)

H₂O(l) $$\to$$ H⁺(aq) + OH^-(aq); $$\Delta H$$ = 57.32 kJ
H₂(g) + $${1 \over 2} O_2(g) \to$$ H₂O(l); $$\Delta H$$ = -286.20 kJ

The value of enthalpy of formation of OH⁻ ion at 25^oC is :

Two liquids X and Y form an ideal solution. At 300K, vapour pressure of the solution containing 1 mol of X and 3 mol of Y is 550 mm Hg. At the same temperature, if 1 mol of Y is further added to this solution, vapour pressure of the solution increases by 10 mm Hg. Vapour pressure (in mm Hg) of X and Y in their pure states will be, respectively :

In Cannizzaro reaction given below
2PhCHO $$\buildrel {\mathop {:OH}\limits^{\left( - \right)} } \over \longrightarrow $$ PhCH₂OH + $$PhC\mathop O\limits^{..} $$₂^(-)
the slowest step is :

The set representing the correct order of ionic radius is :

The two functional groups present in a typical carbohydrate are

Which of the following on heating with aqueous KOH, produces acetaldehyde ?

A liquid was mixed with ethanol and a drop of concentrated H₂SO₄ was added. A compound with a fruity smell was formed. The liquid was :

The major product obtained on interaction of phenol with sodium hydroxide and carbon dioxide is :

Which of the following has an optical isomer ?

Which of the following pairs represents linkage isomers ?

Knowing that the Chemistry of lanthanoids (Ln) is dominated by its +3 oxidation state, which of the following statements is incorrect?

In context with the transition elements, which of the following statements is incorrect ?

The half life period of a first order chemical reaction is 6.93 minutes. The time required for the completion of 99% of the chemical reaction will be (log 2=0.301) :

In a fuel cell methanol is used as fuel and oxygen gas is used as an oxidizer. The reaction is
CH₃OH(l) + 3/2O₂ $$\to$$ CO₂ (g) + 2H₂O (l)
At 298K standard Gibb’s energies of formation for CH₃OH(l), H₂O(l) and CO₂ (g) are -166.2, -237.2 and -394.4 kJ mol⁻¹ respectively. If standard enthalpy of combustion of methanol is -726 kJ mol⁻¹, efficiency of the fuel cell will be

Given : $$E_{F{e^{3 + }}/Fe}^o$$ = -0.036V; $$E_{F{e^{2 + }}/Fe}^o$$ = -0.439 V
The value of standard electrode potential for the change,
Fe³⁺ (aq) + e^- $$\to$$ Fe²⁺ (aq) will be

Using MO theory, predict which of the following species has the shortest bond length?

In which of the following arrangements, the sequence is not strictly according to the property written against it

In an atom, an electron is moving with a speed of 600 m/s with an accuracy of 0.005%. Certainity with which the position of the electron can be located is (h = 6.6 $$\times$$ 10^-34 kg m²s^-1, mass of electron, e_m = 9.1 $$\times$$ 10^-31 kg)

Calculate the wavelength (in nanometer) associated with a proton moving at 1.0 x 10³ ms⁻¹ (Mass of proton = 1.67 $$\times$$ 10^-27 kg and h = 6.63 $$\times$$ 10^-34 Js) :

Statement - 1 : The variance of first n even natural numbers is $${{{n^2} - 1} \over 4}$$

Statement - 2 : The sum of first n natural numbers is $${{n\left( {n + 1} \right)} \over 2}$$ and the sum of squares of first n natural numbers is $${{n\left( {n + 1} \right)\left( {2n + 1} \right)} \over 6}$$

If the mean deviation of number 1, 1 + d, 1 + 2d,........, 1 + 100d from their mean is 255, then the d is equal to

For real x, let f(x) = x³ + 5x + 1, then

Let $$f\left( x \right) = {\left( {x + 1} \right)^2} - 1,x \ge - 1$$

Statement - 1 : The set $$\left\{ {x:f\left( x \right) = {f^{ - 1}}\left( x \right)} \right\} = \left\{ {0, - 1} \right\}$$.

Statement - 2 : $$f$$ is a bijection.

If $$\,\left| {z - {4 \over z}} \right| = 2,$$ then the maximum value of $$\,\left| z \right|$$ is equal to :

Let $$y$$ be an implicit function of $$x$$ defined by $${x^{2x}} - 2{x^x}\cot \,y - 1 = 0$$. Then $$y'(1)$$ equals

One ticket is selected at random from $$50$$ tickets numbered $$00, 01, 02, ...., 49.$$ Then the probability that the sum of the digits on the selected ticket is $$8$$, given that the product of these digits is zer, equals :

$$\int\limits_0^\pi {\left[ {\cot x} \right]dx,} $$ where $$\left[ . \right]$$ denotes the greatest integer function, is equal to:

The area of the region bounded by the parabola $${\left( {y - 2} \right)^2} = x - 1,$$ the tangent of the parabola at the point $$(2, 3)$$ and the $$x$$-axis is :

Let $$a, b, c$$ be such that $$b\left( {a + c} \right) \ne 0$$ if

$$\left| {\matrix{ a & {a + 1} & {a - 1} \cr { - b} & {b + 1} & {b - 1} \cr c & {c - 1} & {c + 1} \cr } } \right| + \left| {\matrix{ {a + 1} & {b + 1} & {c - 1} \cr {a - 1} & {b - 1} & {c + 1} \cr {{{\left( { - 1} \right)}^{n + 2}}a} & {{{\left( { - 1} \right)}^{n + 1}}b} & {{{\left( { - 1} \right)}^n}c} \cr } } \right| = 0$$

then the value of $$n$$ :

Given $$P\left( x \right) = {x^4} + a{x^3} + b{x^2} + cx + d$$ such that $$x=0$$ is the only
real root of $$P'\,\left( x \right) = 0.$$ If $$P\left( { - 1} \right) < P\left( 1 \right),$$ then in the interval $$\left[ { - 1,1} \right]:$$

Let $$f\left( x \right) = x\left| x \right|$$ and $$g\left( x \right) = \sin x.$$
Statement-1: gof is differentiable at $$x=0$$ and its derivative is continuous at that point.
Statement-2: gof is twice differentiable at $$x=0$$.

The ellipse $${x^2} + 4{y^2} = 4$$ is inscribed in a rectangle aligned with the coordinate axex, which in turn is inscribed in another ellipse that passes through the point $$(4,0)$$. Then the equation of the ellipse is :

Three distinct points A, B and C are given in the 2 -dimensional coordinates plane such that the ratio of the distance of any one of them from the point $$(1, 0)$$ to the distance from the point $$(-1, 0)$$ is equal to $${1 \over 3}$$. Then the circumcentre of the triangle ABC is at the point :

The lines $$p\left( {{p^2} + 1} \right)x - y + q = 0$$ and $$\left( {{p^2} + 1} \right){}^2x + \left( {{p^2} + 1} \right)y + 2q$$ $$=0$$ are perpendicular to a common line for :

The shortest distance between the line $$y - x = 1$$ and the curve $$x = {y^2}$$ is :

The remainder left out when $${8^{2n}} - {\left( {62} \right)^{2n + 1}}$$ is divided by 9 is :

From 6 different novels and 3 different dictionaries, 4 novels and 1 dictionary are to be selected and arranged in a row on a shelf so that the dictionary is always in the middle. Then the number of such arrangement is :

If the roots of the equation $$b{x^2} + cx + a = 0$$ imaginary, then for all real values of $$x$$, the expression $$3{b^2}{x^2} + 6bcx + 2{c^2}$$ is :

Let A and B denote the statements

A: $$\cos \alpha + \cos \beta + \cos \gamma = 0$$

B: $$\sin \alpha + \sin \beta + \sin \gamma = 0$$

If $$\cos \left( {\beta - \gamma } \right) + \cos \left( {\gamma - \alpha } \right) + \cos \left( {\alpha - \beta } \right) = - {3 \over 2},$$ then:

The projections of a vector on the three coordinate axis are $$6,-3,2$$ respectively. The direction cosines of the vector are :

If $A, B$ and $C$ are three sets such that $A \cap B=A \cap C$ and $A \cup B=A \cup C$, then :

The logic circuit shown below has the input waveforms $$'A'$$ and $$'B'$$ as shown. Pick out the correct output waveform.

Output is

A $$p$$-$$n$$ junction $$(D)$$ shown in the figure can act as a rectifier. An alternating current source $$(V)$$ is connected in the circuit.

The current $$(I)$$ in the resistor $$(R)$$ can be shown by :

The above is a plot of binding energy per nucleon $${E_b},$$ against the nuclear mass $$M;A,B,C,D,E,F$$ correspond to different nuclei. Consider four reactions :
$$\eqalign{ & \left( i \right)\,\,\,\,\,\,\,\,\,\,A + B \to C + \varepsilon \,\,\,\,\,\,\,\,\,\,\left( {ii} \right)\,\,\,\,\,\,\,\,\,\,C \to A + B + \varepsilon \,\,\,\,\,\,\,\,\,\, \cr & \left( {iii} \right)\,\,\,\,\,\,D + E \to F + \varepsilon \,\,\,\,\,\,\,\,\,\,\left( {iv} \right)\,\,\,\,\,\,\,\,\,F \to D + E + \varepsilon ,\,\,\,\,\,\,\,\,\,\, \cr} $$

where $$\varepsilon $$ is the energy released? In which reactions is $$\varepsilon $$ positive?

The surface of a metal is illuminated with the light of $$400$$ $$nm.$$ The kinetic energy of the ejected photoelectrons was found to be $$1.68$$ $$eV.$$ The work function of the metal is : $$\left( {hc = 1240eV.nm} \right)$$

The transition from the state $$n=4$$ to $$n=3$$ in a hydrogen like atom result in ultra violet radiation. Infrared radiation will be obtained in the transition from :

A transparent solid cylindrical rod has a refractive index of $${2 \over {\sqrt 3 }}.$$ It is surrounded by air. A light ray is incident at the mid-point of one end of the rod as shown in the figure.

The incident angle $$\theta $$ for which the light ray grazes along the wall of the rod is :

An inductor of inductance $$L=400$$ $$mH$$ and resistors of resistance $${R_1} = 2\Omega $$ and $${R_2} = 2\Omega $$ are connected to a battery of $$emf$$ $$12$$ $$V$$ as shown in the figure. The internal resistance of the battery is negligible. The switch $$S$$ is closed at $$t=0.$$ The potential drop across $$L$$ as a function of time is :

In an optics experiment, with the position of the object fixed, a student varies the position of a convex lens and for each position, the screen is adjusted to get a clear image of the object. A graph between the object distance $$u$$ and the image distance $$v,$$ from the lens, is plotted using the same scale for the two axes. A straight line passing through the origin and making an angle of $${45^ \circ }$$ with the $$x$$-axis meets the experimental curve at $$P.$$ The coordinates of $$P$$ will be :

A mixture of light, consisting of wavelength $$590$$ $$nm$$ and an unknown wavelength, illuminates Young's double slit and gives rise to two overlapping interference patterns on the screen. The central maximum of both lights coincide. Further, it is observed that the third bright fringe of known light coincides with the $$4$$th bright fringe of the unknown light. From this data, the wavelength of the unknown light is :

A current loop $$ABCD$$ is held fixed on the plane of the paper as shown in the figure. The arcs $$BC$$ (radius $$= b$$) and $$DA$$ (radius $$=a$$) of the loop are joined by two straight wires $$AB$$ and $$CD$$. A steady current $$I$$ is flowing in the loop. Angle made by $$AB$$ and $$CD$$ at the origin $$O$$ is $${30^ \circ }.$$ Another straight thin wire steady current $${I_1}$$ flowing out of the plane of the paper is kept at the origin.

Due to the presence of the current $${I_1}$$ at the origin:

A current loop $$ABCD$$ is held fixed on the plane of the paper as shown in the figure. The arcs $$BC$$ (radius $$= b$$) and $$DA$$ (radius $$=a$$) of the loop are joined by two straight wires $$AB$$ and $$CD$$. A steady current $$I$$ is flowing in the loop. Angle made by $$AB$$ and $$CD$$ at the origin $$O$$ is $${30^ \circ }.$$ Another straight thin wire steady current $${I_1}$$ flowing out of the plane of the paper is kept at the origin.

The magnitude of the magnetic field $$(B)$$ due to the loop $$ABCD$$ at the origin $$(O)$$ is :

Two points $$P$$ and $$Q$$ are maintained at the potentials of $$10$$ $$V$$ and $$-4$$ $$V$$, respectively. The work done in moving $$100$$ electrons from $$P$$ to $$Q$$ is :

Consider a rubber ball freely falling from a height $$h=4.9$$ $$m$$ onto a horizontal elastic plate. Assume that the duration of collision is negligible and the collision with the plate is totally elastic.

Then the velocity as a function of time and the height as a function of time will be :

(This question contains Statement-1 and Statement-2. Of the four choices given after the statements, choose the one that best describes the two statements.)

Statement-1 : For a charged particle moving from point $$P$$ to point $$Q$$, the net work done by an electrostatic field on the particle is independent of the path connecting point $$P$$ to point $$Q.$$
Statement-2 : The net work done by a conservative force on an object moving along a closed loop is zero.

A charge $$Q$$ is placed at each of the opposite corners of a square. A charge $$q$$ is placed at each of the other two corners. If the net electrical force on $$Q$$ is zero, then $$Q/q$$ equals:

Let $$P\left( r \right) = {Q \over {\pi {R^4}}}r$$ be the change density distribution for a solid sphere of radius $$R$$ and total charge $$Q$$. For a point $$'p'$$ inside the sphere at distance $${r_1}$$ from the center of the sphere, the magnitude of electric field is :

Three sound waves of equal amplitudes have frequencies $$\left( {v - 1} \right),\,v,\,\left( {v + 1} \right).$$ They superpose to give beats. The number of beats produced per second will be :

If $$x,$$ $$v$$ and $$a$$ denote the displacement, the velocity and the acceleration of a particle executing simple harmonic motion of time period $$T,$$ then, which of the following does not change with time?

Two moles of helium gas are taken over the cycle $$ABCD$$, as shown in the $$P$$-$$T$$ diagram.

The net work done on the gas in the cycle $$ABCDA$$ is:

Two moles of helium gas are taken over the cycle $$ABCD,$$ as shown in the $$P$$-$$T$$ diagram.

The work done on the gas in taking it from $$D$$ to $$A$$ is :

Two moles of helium gas are taken over the cycle $$ABCD,$$ as shown in the $$P$$-$$T$$ diagram.

Assuming the gas to be ideal the work done on the gas in taking it from $$A$$ to $$B$$ is :

A long metallic bar is carrying heat from one of its ends to the other end under steady-state. The variation of temperature $$\theta $$ along the length $$x$$ of the bar from its hot end is best described by which of the following figures?

One $$kg$$ of a diatomic gas is at a pressure of $$8 \times {10^4}\,N/{m^2}.$$ The density of the gas is $$4kg/{m^3}$$. What is the energy of the gas due to its thermal motion ?

Statement - 1: The temperature dependence of resistance is usually given as $$R = {R_0}\left( {1 + \alpha \,\Delta t} \right).$$ The resistance of wire changes from $$100\Omega $$ to $$150\Omega $$ when its temperature is increased from $${27^ \circ }C$$ to $${227^ \circ }C$$. This implies that $$\alpha = 2.5 \times {10^{ - 3}}/C.$$

Statement - 2: $$R = {R_0}\left( {1 + \alpha \,\Delta t} \right)$$ is valid only when the change in the temperature $$\Delta T$$ is small and $$\Delta T = \left( {R - {R_0}} \right) < < {R_0}.$$

Two wires are made of the same material and have the same volume. However wire $$1$$ has cross-sectional area $$A$$ and wire $$2$$ has cross-sectional area $$3A.$$ If the length of wire $$1$$ increases by $$\Delta x$$ on applying force $$F,$$ how much force is needed to stretch wire $$2$$ by the same amount?

The height at which the acceleration due to gravity becomes $${g \over 9}$$ (where $$g=$$ the acceleration due to gravity on the surface of the earth) in terms of $$R,$$ the radius of the earth, is:

A thin uniform rod of length $$l$$ and mass $$m$$ is swinging freely about a horizontal axis passing through its end. Its maximum angular speed is $$\omega $$. Its center of mass rises to a maximum height of:

A particle has an initial velocity $$3\widehat i + 4\widehat j$$ and an acceleration of $$0.4\widehat i + 0.3\widehat j$$. Its speed after 10 s is:

In an experiment the angles are required to be measured using an instrument, 29 divisions of the main scale exactly coincide with the 30 divisions of the vernier scale. If the smallest division of the main scale is half-a degree(=$$0.5^\circ $$), then the least count of the instrument is: