The increasing basicity order of the following compounds is :

Which of the following compounds is not aromatic ?

The tests performed on compound X and their inferences are :

	Test	Inference
(a)	2, 4 - DNP test	Coloured precipitate
(b)	Idoform test	Yellow precipitate
(c)	Azo-dye test	No dye formation

Compound 'X' is :

The products formed in the reaction of cumene with O₂ followed by treatment with dil. HCl are :

The correct sequence of amino acids present in the tripeptide given below is :

Consider the following reversible chemical reactions :



The relation between K₁ and K₂ is :

The major product obtained in the following reaction is :

The major product of the following reaction is :

The major product of the following reaction is :

The major product in the following reaction is :

If the standard electrode potential for a cell is 2 V at 300 K, the equilibrium constant (K) for the reaction

Zn(s) + Cu²⁺ (aq) $$\rightleftharpoons$$ Zn²⁺(aq) + Cu(s)

at 300 K is approximately,

(R = 8 JK^$$-$$1mol^$$-$$1, F = 96000 C mol^$$-$$1)

Homoleptic octahedral complexes of a metal ion 'M³⁺' with three monodenate ligands L₁, L₂ and L₃ adsorb wavelenths in the region of green, blue and red respectively. The increasing order of the ligands strength is :

A solution containing 62 g ethylene glycol in 250 g water is cooled to $$-$$ 10^oC. If K_f for water is 1.86 K kg mol^$$-$$1 , the amount of water (in g) separated as ice is :

When the first electron gain enthalpy $$\left( {{\Delta _{eg}}H} \right)$$ of oxygen is $$-$$ 141 kJ/mol, its second electron gain enthalpy is :

The transition element that has lowest enthalpy of atomisation, is :

Which of the following combination of statements is true regarding the interpretation of the atomic orbitals ?

(a) An electron in an orbital of high angular momentum stays away from the nucleus than an electron in the orbital of lower angular momentum.

(b) For a given value of the principal quantum number, the size of the orbit is inversely proportional to the azimuthal quantum number.

(c) According to wave mechanics, the ground state angular momentum is equal to $${h \over {2\pi }}$$.

(d) The plot of $$\psi $$ vs r for various azimuthal quantum numbers, shows peak shifting towards higher r value.

In which of the following process, the bond order has increased and paramagnetic character has charged to diamagnetic ?

For the reaction, 2A + B $$ \to $$ products, when the concentrations of A and B both were doubled, the rate of the reaction increased from 0.3 mol L^$$-$$1s^$$-$$1 to 2.4 mol L^$$-$$1s^$$-$$1. When the concentration of A alone is doubled, the rate increased from 0.3 mol L^$$-$$1s^$$-$$1 to 0.6 mol L^$$-$$1s^$$-$$1.

The pH of rain water, is approximately :

The complex that has highest crystal field splitting energy ($$\Delta $$), is :

The correct match between Item I and Item II is :

Item - I		Item - II
(A)	Benzaldehyde	(P)	Mobile phase
(B)	Alumina	(Q)	Adsorbent
(C)	Acetonitrile	(R)	Adsorbate

For the following reaction, in the mass of water produced from 445 g of C₅₇H₁₁₀O₆ is :

2C₅₇H₁₁₀O₆(s) + 163 O₂(g) $$ \to $$ 114 CO₂(g) + 110 H₂O(l)

The entropy change associated with the conversion of 1 kg of ice at 273 K to water vapours at 383 K is :

(Specific heat of water liquid and water vapour are 4.2 kJ K^$$-$$1 kg^$$-$$1 and 2.0 kJ K^$$-$$1 kg^$$-$$1; heat of liquid fusion and vapourisation of water are 334 kJ^$$-$$1 and 2491 kJ kg^$$-$$1, respectively). (log 273 = 2.436, log 373 = 2.572, log 383 = 2.583)

Let a, b and c be the 7^th, 11^th and 13^th terms respectively of a non-constant A.P. If these are also three consecutive terms of a G.P., then $${a \over c}$$ equal to :

If   $$\int\limits_0^{{\pi \over 3}} {{{\tan \theta } \over {\sqrt {2k\,\sec \theta } }}} \,d\theta = 1 - {1 \over {\sqrt 2 }},\left( {k > 0} \right),$$ then value of k is :

Let A(4, $$-$$ 4) and B(9, 6) be points on the parabola, y² = 4x. Let C be chosen on the arc AOB of the parabola, where O is the origin, such that the area of $$\Delta $$ACB is maximum. Then, the area (in sq. units) of $$\Delta $$ACB, is :

If the lines x = ay + b, z = cy + d and x = a'z + b', y = c'z + d' are perpendicular, then :

A hyperbola has its centre at the origin, passes through the point (4, 2) and has transverse axis of length 4 along the x-axis. Then the eccentricity of the hyperbola is :

The number of natural numbers less than 7,000 which can be formed by using the digits 0, 1, 3, 7, 9 (repitition of digits allowed) is equal to :

If   x $$=$$ 3 tan t and y $$=$$ 3 sec t, then the value of $${{{d^2}y} \over {d{x^2}}}$$ at t $$ = {\pi \over 4},$$ is :

Let f be a differentiable function from

R to R such that $$\left| {f\left( x \right) - f\left( y \right)} \right| \le 2{\left| {x - y} \right|^{{3 \over 2}}},$$   

for all  $$x,y \in $$ R.

If   $$f\left( 0 \right) = 1$$  

then   $$\int\limits_0^1 {{f^2}} \left( x \right)dx$$  is equal to :

If   $$f\left( x \right) = \int {{{5{x^8} + 7{x^6}} \over {{{\left( {{x^2} + 1 + 2{x^7}} \right)}^2}}}} \,dx,\,\left( {x \ge 0} \right),$$

$$f\left( 0 \right) = 0,$$    then the value of $$f(1)$$ is :

If   $$A = \left[ {\matrix{ {{e^t}} & {{e^{ - t}}\cos t} & {{e^{ - t}}\sin t} \cr {{e^t}} & { - {e^{ - t}}\cos t - {e^{ - t}}\sin t} & { - {e^{ - t}}\sin t + {e^{ - t}}co{\mathop{\rm s}\nolimits} t} \cr {{e^t}} & {2{e^{ - t}}\sin t} & { - 2{e^{ - t}}\cos t} \cr } } \right]$$

then A is :

A data consists of n observations : x₁, x₂, . . . . . . ., x_n.    

If     $$\sum\limits_{i = 1}^n {{{\left( {{x_i} + 1} \right)}^2}} = 9n$$    and

$$\sum\limits_{i = 1}^n {{{\left( {{x_i} - 1} \right)}^2}} = 5n,$$

then the standard deviation of this data is :

Let the equations of two sides of a triangle be 3x $$-$$ 2y + 6 = 0 and 4x + 5y $$-$$ 20 = 0. If the orthocentre of this triangle is at (1, 1), then the equation of its third side is :

Let S be the set of all triangles in the xy-plane, each having one vertex at the origin and the other two vertices lie on coordinate axes with integral coordinates. If each triangle in S has area 50 sq. units, then the number of elements in the set S is :

If both the roots of the quadratic equation x² $$-$$ mx + 4 = 0 are real and distinct and they lie in the interval [1, 5], then m lies in the interval :

Let z₀ be a root of the quadratic equation, x² + x + 1 = 0, If z = 3 + 6iz$$_0^{81}$$ $$-$$ 3iz$$_0^{93}$$, then arg z is equal to :

If the system of linear equations
x $$-$$ 4y + 7z = g
       3y $$-$$ 5z = h
$$-$$2x + 5y $$-$$ 9z = k
is consistent, then :

The area of the region

A = {(x, y) : 0 $$ \le $$ y $$ \le $$x |x| + 1  and  $$-$$1 $$ \le $$ x $$ \le $$1} in sq. units, is :

Let f : [0,1] $$ \to $$ R be such that f(xy) = f(x).f(y), for all x, y $$ \in $$ [0, 1], and f(0) $$ \ne $$ 0. If y = y(x) satiesfies the differential equation, $${{dy} \over {dx}}$$ = f(x) with y(0) = 1, then y$$\left( {{1 \over 4}} \right)$$ + y$$\left( {{3 \over 4}} \right)$$ is equal to :

If  x = sin^$$-$$1(sin10) and y = cos^$$-$$1(cos10), then y $$-$$ x is equal to :

For each x$$ \in $$R, let [x] be the greatest integer less than or equal to x.

Then $$\mathop {\lim }\limits_{x \to {0^ - }} \,\,{{x\left( {\left[ x \right] + \left| x \right|} \right)\sin \left[ x \right]} \over {\left| x \right|}}$$ is equal to :

Let  $$\overrightarrow a = \widehat i + \widehat j + \sqrt 2 \widehat k,$$   $$\overrightarrow b = {b_1}\widehat i + {b_2}\widehat j + \sqrt 2 \widehat k$$,    $$\overrightarrow c = 5\widehat i + \widehat j + \sqrt 2 \widehat k$$   be three vectors such that the projection vector of $$\overrightarrow b $$ on $$\overrightarrow a $$ is $$\overrightarrow a $$.
If   $$\overrightarrow a + \overrightarrow b $$   is perpendicular to $$\overrightarrow c $$ , then $$\left| {\overrightarrow b } \right|$$ is equal to :

An urn contains 5 red and 2 green balls. A ball is drawn at random from the urn. If the drawn ball is green, then a red ball is added to the urn and if the drawn ball is red, then a green ball is added to the urn; the original ball is not returned to the urn. Now, a second ball is drawn at random from it. The probability that the second ball is red, is :

The number of all possible positive integral values of $$\alpha $$  for which the roots of the quadratic equation, 6x² $$-$$ 11x + $$\alpha $$ = 0 are rational numbers is :

Let A = {x $$ \in $$ R : x is not a positive integer}.

Define a function $$f$$ : A $$ \to $$  R   as  $$f(x)$$ = $${{2x} \over {x - 1}}$$,

then $$f$$ is :

A parallel plate capacitor with square plates is filled with four dielecytrics of dielectrics constants K₁, K₂, K₃, K₄ arranged as shown in the figure. The effective dielectric constant K will be :

In the given circuit the the internal resistance of the 18 V cell is negligible. If R₁ = 400 $$\Omega $$, R₃ = 100 $$\Omega $$ and R₄ = 500 $$\Omega $$ and the reading of an ideal voltmeter across R₄ is 5V, then the value of R₂ will be :

A rod of length 50 cm is pivoted at one end. It is raised such that if makes an angle of 30^o from the horizontal as shown and released from rest. Its angular speed when it passes through the horizontal (in rad s^$$-$$1) will be (g = 10 ms^$$-$$2)

Ge and Si diodes start conducting at 0.3 V and 0.7 V respectively. In the following figure if Ge diode connection are reversed, the value of V₀ changes by : (assume that the Ge diode has large breakdown voltage)

A series AC circuit containing an inductor (20 mH), a capacitor (120 $$\mu $$F) and a resistor (60 $$\Omega $$) is driven by an AC source of 24V/50 Hz. The energy dissipated in the circuit in 60 s is :

The magnetic field associated with a light wave is given, at the origin, by B = B₀ [sin(3.14 $$ \times $$ 10⁷)ct + sin(6.28 $$ \times $$ 10⁷)ct]. If this light falls on a silver plate having a work function of 4.7 eV, what will be the maximum kinetic energy of the photo electrons ?
(Take c = 3 $$ \times $$ 10⁸ ms^$$-$$1, h = 6.6 $$ \times $$ 10^$$-$$34J-s)

In a car race on straight road, car A takes a time t less than car B at the finish and passes finishing point with a speed '$$\upsilon $$' more than that of car B. Both the cars start from rest and travel with constant acceleration a₁ and a₂ respectively. Then '$$\upsilon $$' is equal to :

The pitch and the number of divisions, on the circular scale, for a given screw gauge are 0.5 mm and 100 respectively. When the screw gauge is fully tightened without any object, the zero of its circular scale lies 3 divisions below the mean line.

The readings of the main scale and the circular scale, for a thin sheet, are 5.5 mm and 48 respectively, the thickness of this sheet is :

Charge is distributed within a sphere of radius R with a volume charge density $$\rho \left( r \right) = {A \over {{r^2}}}{e^{ - {{2r} \over s}}},$$ where A and a are constants. If Q is the total charge of this charge distribution, the radius R is :

A rod of mass 'M' and length '2L' is suspended at its middle by a wire. It exhibits torsional oscillations; If two masses each of 'm' are attached at distance 'L/2' from its centre on both sides, it reduces the oscillation frequency by 20%. The value of radio m/M is close to :

One of the two identical conducting wires of length L is bent in the form of a circular loop and the other one into a circular coil of N identical turns. If the same current is passed in both, the radio of the magnetic field at the central of the loop (B_L) to that at the center of the coil (B_C), i.e. $${{{B_L}} \over {{B_C}}}$$ will be :

Two plane mirrors are inclined to each other such that a ray of light incident on the first mirror (M₁) and parallel to the second mirror (M₂) is finally reflected from the second mirror (M₂) parallel to the first mirror (M₁). The angle between the two mirrors will be :

In a Young's double slit experiment, the slits are placed 0.320 mm apart. Light of wavelength $$\lambda $$ = 500 nm is incident on the slits. The total number of bright fringes that are observed in the angular range $$-$$ 30^o$$ \le $$$$\theta $$$$ \le $$30^o is :

A 15 g mass of nitrogen gas is enclosed in a vessel at a temperature 27^oC. Amount of heat transferred to the gas, so that rms velocity of molecules is doubled, is about : [Take R = 8.3 J/K mole]

A mass of 10 kg is suspended vertically by a rope from the roof. When a horizontal force is applied on the rope at some point. the rope deviated at an angle of 45^o at the roof point. If the suspended mass is at equilibrium, the magnitude of the force applied is (g = 10 ms^$$-$$2

A particle is executing simple harmonic motion (SHM) of amplitude A, along the x-axis, about x = 0. When its potential Energy (PE) equals kinetic energy (KE), the position of the particle will be :

The energy required to take a satellite to a height 'h' above Earth surface (radius of Earth = 6.4 $$ \times $$ 10³ km) is E₁ and kinetic energy required for the satellite to be in a circular orbit at this height is E₂. The value of h for which E₁ and E₂ are equal, is

The top of a water tank is open to air and its water level is mainted. It is giving out 0.74 m³ water per minute through a circular opening of 2 cm radius in its wall. The depth of the center of the opening from the level of water in the tank is close to :

Expression for time in terms of G(universal gravitional constant), h (Planck constant) and c (speed of light) is proportional to :

A particle having the same charge as of electron moves in a ciurcular path of radius 0.5 cm under the influence of a magnetic field 0f 0.5 T. If an electric field of 100 V/m makes it to move in a straight path, then the mass of the particle is (Given charge of electron = 1.6 $$ \times $$ 10$$-$$¹⁹C)

Two point charges q₁$$\left( {\sqrt {10} \mu C} \right)$$ and q₂($$-$$ 25 $$\mu $$C) are placed on the x-axis at x = 1 m and x = 4 m respectively. The electric field (in V/m) at a point y = 3 m on y-axis is,
[take $${1 \over {4\pi { \in _0}}}$$ = 9 $$ \times $$ 10⁹ Nm²C^$$-$$2]

The energy associated with electric field is (U_E) and with magnetic field is (U_B) for an electromagnetic wave in free space. Then :

A force acts on a 2 kg object so that its position is given as a function of time as x = 3t² + 5. What is the work done by this force in first 5 seconds ?

A power transmission line feeds input power at 2300 V to a srep down transformer with its primary windings having 4000 turns. The output power is delivered at 230 V by the transformer. If the current in the primary of the transformer is 5A and its efficiency is 90%, the output current would be :

The position co-ordinates of a particle moving in a 3-D coordinate system is given by
x = a cos$$\omega $$t
y = a sin$$\omega $$t and
z = a$$\omega $$t

The speed of the particle is :