Given below are two statements, one is labelled as Assertion $$\mathbf{A}$$ and the other is labelled as Reason $$\mathbf{R}$$.

Assertion A: The spin only magnetic moment value for $$\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{3-}$$ is $$1.74 \mathrm{BM}$$, whereas for $$\left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{3+}$$ is $$5.92 \mathrm{BM}$$.

Reason $$\mathbf{R}$$ : In both complexes, $$\mathrm{Fe}$$ is present in +3 oxidation state.

In the light of the above statements, choose the correct answer from the options given below:

The standard electrode potential of $$\mathrm{M}^{+} / \mathrm{M}$$ in aqueous solution does not depend on

For the reaction

The correct statement is

The major products A and B from the following reactions are:

Which of the following options are correct for the reaction

$$2\left[\mathrm{Au}(\mathrm{CN})_{2}\right]^{-}(\mathrm{aq})+\mathrm{Zn}(\mathrm{s}) \rightarrow 2 \mathrm{Au}(\mathrm{s})+\left[\mathrm{Zn}(\mathrm{CN})_{4}\right]^{2-}(\mathrm{aq})$$

A. Redox reaction

B. Displacement reaction

C. Decomposition reaction

D. Combination reaction

Choose the correct answer from the options given below:

For a concentrated solution of a weak electrolyte ($$\mathrm{K}_{\text {eq }}=$$ equilibrium constant) $$\mathrm{A}_{2} \mathrm{B}_{3}$$ of concentration '$$c$$', the degree of dissociation '$$\alpha$$' is :

Match List I with List II

Choose the correct answer from the options given below:

The difference between electron gain enthalpies will be maximum between :

The major product formed in the following reaction is

Match List I with List II

Choose the correct answer from the options given below:

Compound $$\mathrm{P}$$ is neutral, $$\mathrm{Q}$$ gives effervescence with $$\mathrm{NaHCO}_{3}$$ while $$\mathrm{R}$$ reacts with Hinsbergs reagent to give solid soluble in $$\mathrm{NaOH}$$. Compound $$\mathrm{P}$$ is

Strong reducing and oxidizing agents among the following, respectively, are :

Match List I with List II

Choose the correct answer from the options given below:

Number of bromo derivatives obtained on treating ethane with excess of $$\mathrm{Br}_{2}$$ in diffused sunlight is ___________

The wavelength of an electron of kinetic energy $$4.50\times10^{-29}$$ J is _________ $$\times 10^{-5}$$ m. (Nearest integer)

Given : mass of electron is $$9\times10^{-31}$$ kg, h $$=6.6\times10^{-34}$$ J s

The number of species from the following which have square pyramidal structure is _________

$$\mathrm{PF}_{5}, \mathrm{BrF}_{4}^{-}, \mathrm{IF}_{5}, \mathrm{BrF}_{5}, \mathrm{XeOF}_{4}, \mathrm{ICl}_{4}^{-}$$

Consider the graph of Gibbs free energy G vs Extent of reaction. The number of statement/s from the following which are true with respect to points (a), (b) and (c) is _________

A. Reaction is spontaneous at (a) and (b)

B. Reaction is at equilibrium at point (b) and non-spontaneous at point (c)

C. Reaction is spontaneous at (a) and non-spontaneous at (c)

D. Reaction is non-spontaneous at (a) and (b)

Mass of Urea $$\left(\mathrm{NH}_{2} \mathrm{CONH}_{2}\right)$$ required to be dissolved in $$1000 \mathrm{~g}$$ of water in order to reduce the vapour pressure of water by $$25 \%$$ is _________ g. (Nearest integer)

Given: Molar mass of N, C, O and H are $$14,12,16$$ and $$1 \mathrm{~g} \mathrm{~mol}^{-1}$$ respectively

The value of $$\log \mathrm{K}$$ for the reaction $$\mathrm{A} \rightleftharpoons \mathrm{B}$$ at $$298 \mathrm{~K}$$ is ___________. (Nearest integer)

Given: $$\Delta \mathrm{H}^{\circ}=-54.07 \mathrm{~kJ} \mathrm{~mol}^{-1}$$

$$\Delta \mathrm{S}^{\circ}=10 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$$

(Take $$2.303 \times 8.314 \times 298=5705$$ )

Number of ambidentate ligands in a representative metal complex $$\left[\mathrm{M}(\mathrm{en})(\mathrm{SCN})_{4}\right]$$ is ___________.

[en = ethylenediamine]

If 5 moles of $$\mathrm{BaCl}_{2}$$ is mixed with 2 moles of $$\mathrm{Na}_{3} \mathrm{PO}_{4}$$, the maximum number of moles of $$\mathrm{Ba}_{3}\left(\mathrm{PO}_{4}\right)_{2}$$ formed is ___________ (Nearest integer)

In ammonium - phosphomolybdate, the oxidation state of Mo is + ___________

Let $$A = \{ x \in R:[x + 3] + [x + 4] \le 3\} ,$$

$$B = \left\{ {x \in R:{3^x}{{\left( {\sum\limits_{r = 1}^\infty {{3 \over {{{10}^r}}}} } \right)}^{x - 3}} < {3^{ - 3x}}} \right\},$$ where [t] denotes greatest integer function. Then,

If the system of equations

$$x+y+a z=b$$

$$2 x+5 y+2 z=6$$

$$x+2 y+3 z=3$$

has infinitely many solutions, then $$2 a+3 b$$ is equal to :

The straight lines $$\mathrm{l_{1}}$$ and $$\mathrm{l_{2}}$$ pass through the origin and trisect the line segment of the line L : $$9 x+5 y=45$$ between the axes. If $$\mathrm{m}_{1}$$ and $$\mathrm{m}_{2}$$ are the slopes of the lines $$\mathrm{l_{1}}$$ and $$\mathrm{l_{2}}$$, then the point of intersection of the line $$\mathrm{y=\left(m_{1}+m_{2}\right)}x$$ with L lies on :

One vertex of a rectangular parallelopiped is at the origin $$\mathrm{O}$$ and the lengths of its edges along $$x, y$$ and $$z$$ axes are $$3,4$$ and $$5$$ units respectively. Let $$\mathrm{P}$$ be the vertex $$(3,4,5)$$. Then the shortest distance between the diagonal OP and an edge parallel to $$\mathrm{z}$$ axis, not passing through $$\mathrm{O}$$ or $$\mathrm{P}$$ is :

The mean and variance of a set of 15 numbers are 12 and 14 respectively. The mean and variance of another set of 15 numbers are 14 and $$\sigma^{2}$$ respectively. If the variance of all the 30 numbers in the two sets is 13 , then $$\sigma^{2}$$ is equal to :

Let $$\mathrm{A}=\left[\mathrm{a}_{\mathrm{ij}}\right]_{2 \times 2}$$, where $$\mathrm{a}_{\mathrm{ij}} \neq 0$$ for all $$\mathrm{i}, \mathrm{j}$$ and $$\mathrm{A}^{2}=\mathrm{I}$$. Let a be the sum of all diagonal elements of $$\mathrm{A}$$ and $$\mathrm{b}=|\mathrm{A}|$$. Then $$3 a^{2}+4 b^{2}$$ is equal to :

Let $$5 f(x)+4 f\left(\frac{1}{x}\right)=\frac{1}{x}+3, x > 0$$. Then $$18 \int_\limits{1}^{2} f(x) d x$$ is equal to :

Let $$I(x)=\int \frac{x^{2}\left(x \sec ^{2} x+\tan x\right)}{(x \tan x+1)^{2}} d x$$. If $$I(0)=0$$, then $$I\left(\frac{\pi}{4}\right)$$ is equal to :

Let $$\vec{a}=2 \hat{i}+3 \hat{j}+4 \hat{k}, \vec{b}=\hat{i}-2 \hat{j}-2 \hat{k}$$ and $$\vec{c}=-\hat{i}+4 \hat{j}+3 \hat{k}$$. If $$\vec{d}$$ is a vector perpendicular to both $$\vec{b}$$ and $$\vec{c}$$, and $$\vec{a} \cdot \vec{d}=18$$, then $$|\vec{a} \times \vec{d}|^{2}$$ is equal to :

Let $$a_{1}, a_{2}, a_{3}, \ldots, a_{\mathrm{n}}$$ be $$\mathrm{n}$$ positive consecutive terms of an arithmetic progression. If $$\mathrm{d} > 0$$ is its common difference, then

$$\lim_\limits{n \rightarrow \infty} \sqrt{\frac{d}{n}}\left(\frac{1}{\sqrt{a_{1}}+\sqrt{a_{2}}}+\frac{1}{\sqrt{a_{2}}+\sqrt{a_{3}}}+\ldots \ldots \ldots+\frac{1}{\sqrt{a_{n-1}}+\sqrt{a_{n}}}\right)$$ is

The sum of all the roots of the equation $$\left|x^{2}-8 x+15\right|-2 x+7=0$$ is :

If the ratio of the fifth term from the beginning to the fifth term from the end in the expansion of $$\left(\sqrt[4]{2}+\frac{1}{\sqrt[4]{3}}\right)^{\mathrm{n}}$$ is $$\sqrt{6}: 1$$, then the third term from the beginning is :

If $$2 x^{y}+3 y^{x}=20$$, then $$\frac{d y}{d x}$$ at $$(2,2)$$ is equal to :

Let $$y=y(x)$$ be a solution of the differential equation $$(x \cos x) d y+(x y \sin x+y \cos x-1) d x=0,0 < x < \frac{\pi}{2}$$. If $$\frac{\pi}{3} y\left(\frac{\pi}{3}\right)=\sqrt{3}$$, then $$\left|\frac{\pi}{6} y^{\prime \prime}\left(\frac{\pi}{6}\right)+2 y^{\prime}\left(\frac{\pi}{6}\right)\right|$$ is equal to ____________.

If the area of the region $$S=\left\{(x, y): 2 y-y^{2} \leq x^{2} \leq 2 y, x \geq y\right\}$$ is equal to $$\frac{n+2}{n+1}-\frac{\pi}{n-1}$$, then the natural number $$n$$ is equal to ___________.

Let the point $$(p, p+1)$$ lie inside the region $$E=\left\{(x, y): 3-x \leq y \leq \sqrt{9-x^{2}}, 0 \leq x \leq 3\right\}$$. If the set of all values of $$\mathrm{p}$$ is the interval $$(a, b)$$, then $$b^{2}+b-a^{2}$$ is equal to ___________.

Let $$a \in \mathbb{Z}$$ and $$[\mathrm{t}]$$ be the greatest integer $$\leq \mathrm{t}$$. Then the number of points, where the function $$f(x)=[a+13 \sin x], x \in(0, \pi)$$ is not differentiable, is __________.

Let $$\mathrm{A}=\{1,2,3,4, \ldots ., 10\}$$ and $$\mathrm{B}=\{0,1,2,3,4\}$$. The number of elements in the relation $$R=\left\{(a, b) \in A \times A: 2(a-b)^{2}+3(a-b) \in B\right\}$$ is ___________.

A circle passing through the point $$P(\alpha, \beta)$$ in the first quadrant touches the two coordinate axes at the points $$A$$ and $$B$$. The point $$P$$ is above the line $$A B$$. The point $$Q$$ on the line segment $$A B$$ is the foot of perpendicular from $$P$$ on $$A B$$. If $$P Q$$ is equal to 11 units, then the value of $$\alpha \beta$$ is ___________.

The number of ways of giving 20 distinct oranges to 3 children such that each child gets at least one orange is ___________.

A particle is moving with constant speed in a circular path. When the particle turns by an angle $$90^{\circ}$$, the ratio of instantaneous velocity to its average velocity is $$\pi: x \sqrt{2}$$. The value of $$x$$ will be -

The induced emf can be produced in a coil by

A. moving the coil with uniform speed inside uniform magnetic field

B. moving the coil with non uniform speed inside uniform magnetic field

C. rotating the coil inside the uniform magnetic field

D. changing the area of the coil inside the uniform magnetic field

Choose the correct answer from the options given below:

Name the logic gate equivalent to the diagram attached

Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R

Assertion A : When a body is projected at an angle $$45^{\circ}$$, it's range is maximum.

Reason R : For maximum range, the value of $$\sin 2 \theta$$ should be equal to one.

In the light of the above statements, choose the correct answer from the options given below:

A source supplies heat to a system at the rate of $$1000 \mathrm{~W}$$. If the system performs work at a rate of $$200 \mathrm{~W}$$. The rate at which internal energy of the system increases is

A small ball of mass $$\mathrm{M}$$ and density $$\rho$$ is dropped in a viscous liquid of density $$\rho_{0}$$. After some time, the ball falls with a constant velocity. What is the viscous force on the ball ?

A small block of mass $$100 \mathrm{~g}$$ is tied to a spring of spring constant $$7.5 \mathrm{~N} / \mathrm{m}$$ and length $$20 \mathrm{~cm}$$. The other end of spring is fixed at a particular point A. If the block moves in a circular path on a smooth horizontal surface with constant angular velocity $$5 ~\mathrm{rad} / \mathrm{s}$$ about point $$\mathrm{A}$$, then tension in the spring is -

Given below are two statements : one is labelled as Assertion $$\mathbf{A}$$ and the other is labelled as Reason $$\mathbf{R}$$.

Assertion A : Earth has atmosphere whereas moon doesn't have any atmosphere.

Reason R : The escape velocity on moon is very small as compared to that on earth.

In the light of the above statements, choose the correct answer from the options given below:

The kinetic energy of an electron, $$\alpha$$-particle and a proton are given as $$4 \mathrm{~K}, 2 \mathrm{~K}$$ and $$\mathrm{K}$$ respectively. The de-Broglie wavelength associated with electron $$(\lambda \mathrm{e}), \alpha$$-particle $$((\lambda \alpha)$$ and the proton $$(\lambda p)$$ are as follows:

A monochromatic light wave with wavelength $$\lambda_{1}$$ and frequency $$v_{1}$$ in air enters another medium. If the angle of incidence and angle of refraction at the interface are $$45^{\circ}$$ and $$30^{\circ}$$ respectively, then the wavelength $$\lambda_{2}$$ and frequency $$v_{2}$$ of the refracted wave are:

A long straight wire of circular cross-section (radius a) is carrying steady current I. The current I is uniformly distributed across this cross-section. The magnetic field is

A planet has double the mass of the earth. Its average density is equal to that of the earth. An object weighing $$\mathrm{W}$$ on earth will weigh on that planet:

A mass $$m$$ is attached to two strings as shown in figure. The spring constants of two springs are $$\mathrm{K}_{1}$$ and $$\mathrm{K}_{2}$$. For the frictionless surface, the time period of oscillation of mass $$m$$ is :

Two resistances are given as $$\mathrm{R}_{1}=(10 \pm 0.5) \Omega$$ and $$\mathrm{R}_{2}=(15 \pm 0.5) \Omega$$. The percentage error in the measurement of equivalent resistance when they are connected in parallel is -

For the plane electromagnetic wave given by $$E=E_{0} \sin (\omega t-k x)$$ and $$B=B_{0} \sin (\omega t-k x)$$, the ratio of average electric energy density to average magnetic energy density is

The resistivity $$(\rho)$$ of semiconductor varies with temperature. Which of the following curve represents the correct behaviour :

The energy levels of an hydrogen atom are shown below. The transition corresponding to emission of shortest wavelength is :

The number of air molecules per cm$$^3$$ increased from $$3\times10^{19}$$ to $$12\times10^{19}$$. The ratio of collision frequency of air molecules before and after the increase in number respectively is:

For a uniformly charged thin spherical shell, the electric potential (V) radially away from the centre (O) of shell can be graphically represented as -

The radius of fifth orbit of the $$\mathrm{Li}^{++}$$ is __________ $$\times 10^{-12} \mathrm{~m}$$.

Take: radius of hydrogen atom $$ = 0.51\,\mathop A\limits^o $$

Two identical solid spheres each of mass $$2 \mathrm{~kg}$$ and radii $$10 \mathrm{~cm}$$ are fixed at the ends of a light rod. The separation between the centres of the spheres is $$40 \mathrm{~cm}$$. The moment of inertia of the system about an axis perpendicular to the rod passing through its middle point is __________ $$\times 10^{-3} \mathrm{~kg}~\mathrm{m}^{2}$$

A steel rod has a radius of $$20 \mathrm{~mm}$$ and a length of $$2.0 \mathrm{~m}$$. A force of $$62.8 ~\mathrm{kN}$$ stretches it along its length. Young's modulus of steel is $$2.0 \times 10^{11} \mathrm{~N} / \mathrm{m}^{2}$$. The longitudinal strain produced in the wire is _____________ $$\times 10^{-5}$$

Two identical circular wires of radius $$20 \mathrm{~cm}$$ and carrying current $$\sqrt{2} \mathrm{~A}$$ are placed in perpendicular planes as shown in figure. The net magnetic field at the centre of the circular wires is __________ $$\times 10^{-8} \mathrm{~T}$$.

(Take $$\pi=3.14$$)

A pole is vertically submerged in swimming pool, such that it gives a length of shadow $$2.15 \mathrm{~m}$$ within water when sunlight is incident at angle of $$30^{\circ}$$ with the surface of water. If swimming pool is filled to a height of $$1.5 \mathrm{~m}$$, then the height of the pole above the water surface in centimeters is $$\left(n_{w}=4 / 3\right)$$ ____________.

A particle of mass $$10 \mathrm{~g}$$ moves in a straight line with retardation $$2 x$$, where $$x$$ is the displacement in SI units. Its loss of kinetic energy for above displacement is $$\left(\frac{10}{x}\right)^{-n}$$ J. The value of $$\mathrm{n}$$ will be __________

The length of a metallic wire is increased by $$20 \%$$ and its area of cross section is reduced by $$4 \%$$. The percentage change in resistance of the metallic wire is __________.

A parallel plate capacitor with plate area $$\mathrm{A}$$ and plate separation $$\mathrm{d}$$ is filled with a dielectric material of dielectric constant $$K=4$$. The thickness of the dielectric material is $$x$$, where $$x < d$$.

Let $$\mathrm{C}_{1}$$ and $$\mathrm{C}_{2}$$ be the capacitance of the system for $$\chi=\frac{1}{3} d$$ and $$\mathcal{X}=\frac{2 d}{3}$$, respectively. If $$\mathrm{C}_{1}=2 \mu \mathrm{F}$$ the value of $$\mathrm{C}_{2}$$ is __________ $$\mu \mathrm{F}$$

An ideal transformer with purely resistive load operates at $$12 ~\mathrm{kV}$$ on the primary side. It supplies electrical energy to a number of nearby houses at $$120 \mathrm{~V}$$. The average rate of energy consumption in the houses served by the transformer is 60 $$\mathrm{kW}$$. The value of resistive load $$(\mathrm{Rs})$$ required in the secondary circuit will be ___________ $$\mathrm{m} \Omega$$.