Aluminium chloride in acidified aqueous solution forms an ion having geometry

Example of vinylic halide is :

Given below are two statements :

Statement (I) : The gas liberated on warming a salt with dil $$\mathrm{H}_2 \mathrm{SO}_4$$, turns a piece of paper dipped in lead acetate into black, it is a confirmatory test for sulphide ion.

Statement (II) : In statement-I the colour of paper turns black because of formation of lead sulphite. In the light of the above statements, choose the most appropriate answer from the options given below :

The final product A, formed in the following multistep reaction sequence is :

This reduction reaction is known as:

Compound A formed in the following reaction reacts with B gives the product C. Find out A and B.

Which of the following molecule/species is most stable?

What happens to freezing point of benzene when small quantity of napthalene is added to benzene?

Match List I with List II.

Choose the correct answer from the options given below :

Match List I with List II.

Choose the correct answer from the options given below :

The Lassiagne's extract is boiled with dil $$\mathrm{HNO}_3$$ before testing for halogens because,

Given below are two statements :

Statement (I) : The orbitals having same energy are called as degenerate orbitals.

Statement (II) : In hydrogen atom, 3p and 3d orbitals are not degenerate orbitals.

In the light of the above statements, choose the most appropriate answer from the options given below :

Sugar which does not give reddish brown precipitate with Fehling's reagent, is :

In the given reactions, identify the reagent A and reagent B.

Diamagnetic Lanthanoid ions are :

Choose the correct statements from the following :

(A) Ethane-1, 2-diamine is a chelating ligand.

(B) Metallic aluminium is produced by electrolysis of aluminium oxide in presence of cryolite.

(C) Cyanide ion is used as ligand for leaching of silver.

(D) Phosphine act as a ligand in Wilkinson catalyst.

(E) The stability constants of $$\mathrm{Ca}^{2+}$$ and $$\mathrm{Mg}^{2+}$$ are similar with EDTA complexes.

Choose the correct answer from the options given below :

Following is a confirmatory test for aromatic primary amines. Identify reagent (A) and (B).

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : $$\mathrm{CH}_2=\mathrm{CH}-\mathrm{CH}_2-\mathrm{Cl}$$ is an example of allyl halide.

Reason (R) : Allyl halides are the compounds in which the halogen atom is attached to $$\mathrm{sp}^2$$ hybridised carbon atom.

In the light of the above statements, choose the most appropriate answer from the options given below :

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : There is a considerable increase in covalent radius from $$\mathrm{N}$$ to $$\mathrm{P}$$. However from As to Bi only a small increase in covalent radius is observed.

Reason (R) : Covalent and ionic radii in a particular oxidation state increases down the group. In the light of the above statements, choose the most appropriate answer from the options given below:

Structure of 4-Methylpent-2-enal is :

The total number of molecular orbitals formed from $$2 \mathrm{s}$$ and $$2 \mathrm{p}$$ atomic orbitals of a diatomic molecule is __________.

The mass of sodium acetate $$\left(\mathrm{CH}_3 \mathrm{COONa}\right)$$ required to prepare $$250 \mathrm{~mL}$$ of $$0.35 \mathrm{~M}$$ aqueous solution is ________ g. (Molar mass of $$\mathrm{CH}_3 \mathrm{COONa}$$ is $$82.02 \mathrm{~g} \mathrm{~mol}^{-1}$$)

$$0.05 \mathrm{~cm}$$ thick coating of silver is deposited on a plate of $$0.05 \mathrm{~m}^2$$ area. The number of silver atoms deposited on plate are ________ $$\times 10^{23}$$. (At mass $$\mathrm{Ag}=108, \mathrm{~d}=7.9 \mathrm{~g} \mathrm{~cm}^{-3}$$)

The compound formed by the reaction of ethanal with semicarbazide contains _________ number of nitrogen atoms.

The $$\mathrm{pH}$$ at which $$\mathrm{Mg}(\mathrm{OH})_2\left[\mathrm{~K}_{\mathrm{sp}}=1 \times 10^{-11}\right]$$ begins to precipitate from a solution containing $$0.10 \mathrm{~M} \mathrm{~Mg}^{2+}$$ ions is __________.

$$2 \mathrm{MnO}_4^{-}+\mathrm{bI}^{-}+\mathrm{cH}_2 \mathrm{O} \rightarrow x \mathrm{I}_2+y \mathrm{MnO}_2+z \overline{\mathrm{O}} \mathrm{H}$$

If the above equation is balanced with integer coefficients, the value of $$z$$ is ________.

An ideal gas undergoes a cyclic transformation starting from the point A and coming back to the same point by tracing the path $$\mathrm{A} \rightarrow \mathrm{B} \rightarrow \mathrm{C} \rightarrow \mathrm{A}$$ as shown in the diagram above. The total work done in the process is __________ J.

The rate of First order reaction is $$0.04 \mathrm{~mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1}$$ at 10 minutes and $$0.03 \mathrm{~mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1}$$ at 20 minutes after initiation. Half life of the reaction is _______ minutes.

(Given $$\log 2=0.3010, \log 3=0.4771$$)

On a thin layer chromatographic plate, an organic compound moved by $$3.5 \mathrm{~cm}$$, while the solvent moved by $$5 \mathrm{~cm}$$. The retardation factor of the organic compound is ________ $$\times 10^{-1}$$.

If IUPAC name of an element is "Unununnium" then the element belongs to n^th group of Periodic table. The value of n is ________.

Let $$g: \mathbf{R} \rightarrow \mathbf{R}$$ be a non constant twice differentiable function such that $$\mathrm{g}^{\prime}\left(\frac{1}{2}\right)=\mathrm{g}^{\prime}\left(\frac{3}{2}\right)$$. If a real valued function $$f$$ is defined as $$f(x)=\frac{1}{2}[g(x)+g(2-x)]$$, then

The value of $$\lim _\limits{n \rightarrow \infty} \sum_\limits{k=1}^n \frac{n^3}{\left(n^2+k^2\right)\left(n^2+3 k^2\right)}$$ is :

If the circles $$(x+1)^2+(y+2)^2=r^2$$ and $$x^2+y^2-4 x-4 y+4=0$$ intersect at exactly two distinct points, then

Let $$\overrightarrow{\mathrm{a}}=\mathrm{a}_1 \hat{i}+\mathrm{a}_2 \hat{j}+\mathrm{a}_3 \hat{k}$$ and $$\overrightarrow{\mathrm{b}}=\mathrm{b}_1 \hat{i}+\mathrm{b}_2 \hat{j}+\mathrm{b}_3 \hat{k}$$ be two vectors such that $$|\overrightarrow{\mathrm{a}}|=1, \vec{a} \cdot \vec{b}=2$$ and $$|\vec{b}|=4$$. If $$\vec{c}=2(\vec{a} \times \vec{b})-3 \vec{b}$$, then the angle between $$\vec{b}$$ and $$\vec{c}$$ is equal to:

The maximum area of a triangle whose one vertex is at $$(0,0)$$ and the other two vertices lie on the curve $$y=-2 x^2+54$$ at points $$(x, y)$$ and $$(-x, y)$$, where $$y>0$$, is :

If $$f(x)=\left|\begin{array}{ccc} 2 \cos ^4 x & 2 \sin ^4 x & 3+\sin ^2 2 x \\ 3+2 \cos ^4 x & 2 \sin ^4 x & \sin ^2 2 x \\ 2 \cos ^4 x & 3+2 \sin ^4 x & \sin ^2 2 x \end{array}\right|,$$ then $$\frac{1}{5} f^{\prime}(0)=$$ is equal to :

Let $$(\alpha, \beta, \gamma)$$ be the foot of perpendicular from the point $$(1,2,3)$$ on the line $$\frac{x+3}{5}=\frac{y-1}{2}=\frac{z+4}{3}$$. Then $$19(\alpha+\beta+\gamma)$$ is equal to :

A line passing through the point $$\mathrm{A}(9,0)$$ makes an angle of $$30^{\circ}$$ with the positive direction of $$x$$-axis. If this line is rotated about A through an angle of $$15^{\circ}$$ in the clockwise direction, then its equation in the new position is :

Consider the system of linear equations $$x+y+z=4 \mu, x+2 y+2 \lambda z=10 \mu, x+3 y+4 \lambda^2 z=\mu^2+15$$ where $$\lambda, \mu \in \mathbf{R}$$. Which one of the following statements is NOT correct ?

Let $$f:\left[-\frac{\pi}{2}, \frac{\pi}{2}\right] \rightarrow \mathbf{R}$$ be a differentiable function such that $$f(0)=\frac{1}{2}$$. If the $$\lim _\limits{x \rightarrow 0} \frac{x \int_0^x f(\mathrm{t}) \mathrm{dt}}{\mathrm{e}^{x^2}-1}=\alpha$$, then $$8 \alpha^2$$ is equal to :

If the length of the minor axis of an ellipse is equal to half of the distance between the foci, then the eccentricity of the ellipse is :

Let M denote the median of the following frequency distribution

Then 20M is equal to :

Two integers $$x$$ and $$y$$ are chosen with replacement from the set $$\{0,1,2,3, \ldots, 10\}$$. Then the probability that $$|x-y|>5$$, is :

Let $$A(2,3,5)$$ and $$C(-3,4,-2)$$ be opposite vertices of a parallelogram $$A B C D$$. If the diagonal $$\overrightarrow{\mathrm{BD}}=\hat{i}+2 \hat{j}+3 \hat{k}$$, then the area of the parallelogram is equal to :

Let $$y=y(x)$$ be the solution of the differential equation $$\sec x \mathrm{~d} y+\{2(1-x) \tan x+x(2-x)\} \mathrm{d} x=0$$ such that $$y(0)=2$$. Then $$y(2)$$ is equal to:

If $$z=x+i y, x y \neq 0$$, satisfies the equation $$z^2+i \bar{z}=0$$, then $$\left|z^2\right|$$ is equal to :

If $$2 \sin ^3 x+\sin 2 x \cos x+4 \sin x-4=0$$ has exactly 3 solutions in the interval $$\left[0, \frac{\mathrm{n} \pi}{2}\right], \mathrm{n} \in \mathrm{N}$$, then the roots of the equation $$x^2+\mathrm{n} x+(\mathrm{n}-3)=0$$ belong to :

If the domain of the function $$f(x)=\cos ^{-1}\left(\frac{2-|x|}{4}\right)+\left\{\log _e(3-x)\right\}^{-1}$$ is $$[-\alpha, \beta)-\{\gamma\}$$, then $$\alpha+\beta+\gamma$$ is equal to :

Let $$S_n$$ denote the sum of first $$n$$ terms of an arithmetic progression. If $$S_{20}=790$$ and $$S_{10}=145$$, then $$\mathrm{S}_{15}-\mathrm{S}_5$$ is :

The area (in square units) of the region bounded by the parabola $$y^2=4(x-2)$$ and the line $$y=2 x-8$$, is :

A group of 40 students appeared in an examination of 3 subjects - Mathematics, Physics and Chemistry. It was found that all students passed in atleast one of the subjects, 20 students passed in Mathematics, 25 students passed in Physics, 16 students passed in Chemistry, atmost 11 students passed in both Mathematics and Physics, atmost 15 students passed in both Physics and Chemistry, atmost 15 students passed in both Mathematics and Chemistry. The maximum number of students passed in all the three subjects is _________.

Let $$y=y(x)$$ be the solution of the differential equation $$\left(1-x^2\right) \mathrm{d} y=\left[x y+\left(x^3+2\right) \sqrt{3\left(1-x^2\right)}\right] \mathrm{d} x, -1< x<1, y(0)=0$$. If $$y\left(\frac{1}{2}\right)=\frac{\mathrm{m}}{\mathrm{n}}, \mathrm{m}$$ and $$\mathrm{n}$$ are co-prime numbers, then $$\mathrm{m}+\mathrm{n}$$ is equal to __________.

The value of $$9 \int_\limits0^9\left[\sqrt{\frac{10 x}{x+1}}\right] \mathrm{d} x$$, where $$[t]$$ denotes the greatest integer less than or equal to $$t$$, is

Let $$\alpha, \beta \in \mathbf{N}$$ be roots of the equation $$x^2-70 x+\lambda=0$$, where $$\frac{\lambda}{2}, \frac{\lambda}{3} \notin \mathbf{N}$$. If $$\lambda$$ assumes the minimum possible value, then $$\frac{(\sqrt{\alpha-1}+\sqrt{\beta-1})(\lambda+35)}{|\alpha-\beta|}$$ is equal to :

$$\text { Number of integral terms in the expansion of }\left\{7^{\left(\frac{1}{2}\right)}+11^{\left(\frac{1}{6}\right)}\right\}^{824} \text { is equal to _________. }$$

Let the latus rectum of the hyperbola $$\frac{x^2}{9}-\frac{y^2}{b^2}=1$$ subtend an angle of $$\frac{\pi}{3}$$ at the centre of the hyperbola. If $$\mathrm{b}^2$$ is equal to $$\frac{l}{\mathrm{~m}}(1+\sqrt{\mathrm{n}})$$, where $$l$$ and $$\mathrm{m}$$ are co-prime numbers, then $$\mathrm{l}^2+\mathrm{m}^2+\mathrm{n}^2$$ is equal to ________.

If $$\mathrm{d}_1$$ is the shortest distance between the lines $$x+1=2 y=-12 z, x=y+2=6 z-6$$ and $$\mathrm{d}_2$$ is the shortest distance between the lines $$\frac{x-1}{2}=\frac{y+8}{-7}=\frac{z-4}{5}, \frac{x-1}{2}=\frac{y-2}{1}=\frac{z-6}{-3}$$, then the value of $$\frac{32 \sqrt{3} \mathrm{~d}_1}{\mathrm{~d}_2}$$ is :

Let $$\alpha=1^2+4^2+8^2+13^2+19^2+26^2+\ldots$$ upto 10 terms and $$\beta=\sum_\limits{n=1}^{10} n^4$$. If $$4 \alpha-\beta=55 k+40$$, then $$\mathrm{k}$$ is equal to __________.

Let $$\mathrm{A}=\{1,2,3, \ldots, 7\}$$ and let $$\mathrm{P}(\mathrm{A})$$ denote the power set of $$\mathrm{A}$$. If the number of functions $$f: \mathrm{A} \rightarrow \mathrm{P}(\mathrm{A})$$ such that $$\mathrm{a} \in f(\mathrm{a}), \forall \mathrm{a} \in \mathrm{A}$$ is $$\mathrm{m}^{\mathrm{n}}, \mathrm{m}$$ and $$\mathrm{n} \in \mathrm{N}$$ and $$\mathrm{m}$$ is least, then $$\mathrm{m}+\mathrm{n}$$ is equal to _________.

If the function

$$f(x)= \begin{cases}\frac{1}{|x|}, & |x| \geqslant 2 \\ \mathrm{a} x^2+2 \mathrm{~b}, & |x|<2\end{cases}$$

is differentiable on $$\mathbf{R}$$, then $$48(a+b)$$ is equal to __________.

The ratio of the magnitude of the kinetic energy to the potential energy of an electron in the 5^th excited state of a hydrogen atom is :

The work function of a substance is $$3.0 \mathrm{~eV}$$. The longest wavelength of light that can cause the emission of photoelectrons from this substance is approximately;

Primary coil of a transformer is connected to $$220 \mathrm{~V}$$ ac. Primary and secondary turns of the transforms are 100 and 10 respectively. Secondary coil of transformer is connected to two series resistances shown in figure. The output voltage $$\left(V_0\right)$$ is :

A particle of mass $$\mathrm{m}$$ is projected with a velocity '$$\mathrm{u}$$' making an angle of $$30^{\circ}$$ with the horizontal. The magnitude of angular momentum of the projectile about the point of projection when the particle is at its maximum height $$\mathrm{h}$$ is :

The diffraction pattern of a light of wavelength $$400 \mathrm{~nm}$$ diffracting from a slit of width $$0.2 \mathrm{~mm}$$ is focused on the focal plane of a convex lens of focal length $$100 \mathrm{~cm}$$. The width of the $$1^{\text {st }}$$ secondary maxima will be :

A series L.R circuit connected with an ac source $$E=(25 \sin 1000 t) V$$ has a power factor of $$\frac{1}{\sqrt{2}}$$. If the source of emf is changed to $$\mathrm{E}=(20 \sin 2000 \mathrm{t}) \mathrm{V}$$, the new power factor of the circuit will be :

The electrostatic potential due to an electric dipole at a distance '$$r$$' varies as :

A particle is placed at the point $$A$$ of a frictionless track $$A B C$$ as shown in figure. It is gently pushed towards right. The speed of the particle when it reaches the point B is :

(Take $$g=10 \mathrm{~m} / \mathrm{s}^2$$).

Two thermodynamical processes are shown in the figure. The molar heat capacity for process A and B are $$\mathrm{C}_{\mathrm{A}}$$ and $$\mathrm{C}_{\mathrm{B}}$$. The molar heat capacity at constant pressure and constant volume are represented by $$\mathrm{C_P}$$ and $$\mathrm{C_V}$$, respectively. Choose the correct statement.

The electric field of an electromagnetic wave in free space is represented as $$\overrightarrow{\mathrm{E}}=\mathrm{E}_0 \cos (\omega \mathrm{t}-\mathrm{kz}) \hat{i}$$. The corresponding magnetic induction vector will be :

At which temperature the r.m.s. velocity of a hydrogen molecule equal to that of an oxygen molecule at $$47^{\circ} \mathrm{C}$$ ?

Match List I with List II.

Choose the correct answer from the options given below :

A potential divider circuit is shown in figure. The output voltage V$$_0$$ is :

A Zener diode of breakdown voltage $$10 \mathrm{~V}$$ is used as a voltage regulator as shown in the figure. The current through the Zener diode is :

Two insulated circular loop A and B of radius '$$a$$' carrying a current of '$$\mathrm{I}$$' in the anti clockwise direction as shown in the figure. The magnitude of the magnetic induction at the centre will be :

All surfaces shown in figure are assumed to be frictionless and the pulleys and the string are light. The acceleration of the block of mass $$2 \mathrm{~kg}$$ is :

An electric toaster has resistance of $$60 \Omega$$ at room temperature $$\left(27^{\circ} \mathrm{C}\right)$$. The toaster is connected to a $$220 \mathrm{~V}$$ supply. If the current flowing through it reaches $$2.75 \mathrm{~A}$$, the temperature attained by toaster is around : ( if $$\alpha=2 \times 10^{-4}$$/$$^\circ \mathrm{C}$$)

A spherical body of mass $$100 \mathrm{~g}$$ is dropped from a height of $$10 \mathrm{~m}$$ from the ground. After hitting the ground, the body rebounds to a height of $$5 \mathrm{~m}$$. The impulse of force imparted by the ground to the body is given by : (given, $$\mathrm{g}=9.8 \mathrm{~m} / \mathrm{s}^2$$)

Young's modules of material of a wire of length '$$L$$' and cross-sectional area $$A$$ is $$Y$$. If the length of the wire is doubled and cross-sectional area is halved then Young's modules will be :

The gravitational potential at a point above the surface of earth is $$-5.12 \times 10^7 \mathrm{~J} / \mathrm{kg}$$ and the acceleration due to gravity at that point is $$6.4 \mathrm{~m} / \mathrm{s}^2$$. Assume that the mean radius of earth to be $$6400 \mathrm{~km}$$. The height of this point above the earth's surface is :

The horizontal component of earth's magnetic field at a place is $$3.5 \times 10^{-5} \mathrm{~T}$$. A very long straight conductor carrying current of $$\sqrt{2} \mathrm{~A}$$ in the direction from South east to North West is placed. The force per unit length experienced by the conductor is __________ $$\times 10^{-6} \mathrm{~N} / \mathrm{m}$$.

Two cells are connected in opposition as shown. Cell $$\mathrm{E}_1$$ is of $$8 \mathrm{~V}$$ emf and $$2 \Omega$$ internal resistance; the cell $$\mathrm{E}_2$$ is of $$2 \mathrm{~V}$$ emf and $$4 \Omega$$ internal resistance. The terminal potential difference of cell $$\mathrm{E}_2$$ is __________ V.

A electron of hydrogen atom on an excited state is having energy $$\mathrm{E}_{\mathrm{n}}=-0.85 \mathrm{~eV}$$. The maximum number of allowed transitions to lower energy level is _________.

A capacitor of capacitance $$\mathrm{C}$$ and potential $$\mathrm{V}$$ has energy $$\mathrm{E}$$. It is connected to another capacitor of capacitance $$2 \mathrm{C}$$ and potential $$2 \mathrm{~V}$$. Then the loss of energy is $$\frac{x}{3} \mathrm{E}$$, where $$x$$ is _______.

The distance between object and its two times magnified real image as produced by a convex lens is $$45 \mathrm{~cm}$$. The focal length of the lens used is _______ cm.

In a closed organ pipe, the frequency of fundamental note is $$30 \mathrm{~Hz}$$. A certain amount of water is now poured in the organ pipe so that the fundamental frequency is increased to $$110 \mathrm{~Hz}$$. If the organ pipe has a cross-sectional area of $$2 \mathrm{~cm}^2$$, the amount of water poured in the organ tube is __________ g. (Take speed of sound in air is $$330 \mathrm{~m} / \mathrm{s}$$)

Consider a Disc of mass $$5 \mathrm{~kg}$$, radius $$2 \mathrm{~m}$$, rotating with angular velocity of $$10 \mathrm{~rad} / \mathrm{s}$$ about an axis perpendicular to the plane of rotation. An identical disc is kept gently over the rotating disc along the same axis. The energy dissipated so that both the discs continue to rotate together without slipping is ________ J.

The displacement and the increase in the velocity of a moving particle in the time interval of $$t$$ to $$(t+1) \mathrm{s}$$ are $$125 \mathrm{~m}$$ and $$50 \mathrm{~m} / \mathrm{s}$$, respectively. The distance travelled by the particle in $$(\mathrm{t}+2)^{\mathrm{th}} \mathrm{s}$$ is _________ m.

Each of three blocks $$\mathrm{P}, \mathrm{Q}$$ and $$\mathrm{R}$$ shown in figure has a mass of $$3 \mathrm{~kg}$$. Each of the wires $$\mathrm{A}$$ and $$\mathrm{B}$$ has cross-sectional area $$0.005 \mathrm{~cm}^2$$ and Young's modulus $$2 \times 10^{11} \mathrm{~N} \mathrm{~m}^{-2}$$. Neglecting friction, the longitudinal strain on wire $$B$$ is ________ $$\times 10^{-4}$$. (Take $$\mathrm{g}=10 \mathrm{~m} / \mathrm{s}^2$$)

A ceiling fan having 3 blades of length $$80 \mathrm{~cm}$$ each is rotating with an angular velocity of 1200 $$\mathrm{rpm}$$. The magnetic field of earth in that region is $$0.5 \mathrm{G}$$ and angle of dip is $$30^{\circ}$$. The emf induced across the blades is $$\mathrm{N} \pi \times 10^{-5} \mathrm{~V}$$. The value of $$\mathrm{N}$$ is _________.