Match List I with List II:

Choose the correct answer from the options given below:

Two solutions A and B are prepared by dissolving 1 g of non-volatile solutes X and Y, respectively in 1 kg of water. The ratio of depression in freezing points for A and B is found to be 1 : 4. The ratio of molar masses of X and Y is

$${K_{{a_1}}}$$, $${K_{{a_2}}}$$ and $${K_{{a_3}}}$$ are the respective ionization constants for the following reactions (a), (b) and (c).

(a) $${H_2}{C_2}{O_4} \mathbin{\lower.3ex\hbox{$\buildrel\textstyle\rightarrow\over {\smash{\leftarrow}\vphantom{_{\vbox to.5ex{\vss}}}}$}} {H^ + } + H{C_2}O_4^ - $$

(b) $$H{C_2}O_4^ - \mathbin{\lower.3ex\hbox{$\buildrel\textstyle\rightarrow\over {\smash{\leftarrow}\vphantom{_{\vbox to.5ex{\vss}}}}$}} {H^ + } + {C_2}O_4^{2 - }$$

(c) $${H_2}{C_2}O_4^{} \mathbin{\lower.3ex\hbox{$\buildrel\textstyle\rightarrow\over {\smash{\leftarrow}\vphantom{_{\vbox to.5ex{\vss}}}}$}} 2{H^ + } + {C_2}O_4^{2 - }$$

The relationship between $${K_{{a_1}}}$$, $${K_{{a_2}}}$$ and $${K_{{a_3}}}$$ is given as :

The molar conductivity of a conductivity cell filled with 10 moles of 20 mL NaCl solution is $${\Lambda _{m1}}$$ and that of 20 moles another identical cell heaving 80 mL NaCl solution is $${\Lambda _{m2}}$$. The conductivities exhibited by these two cells are same. The relationship between $${\Lambda _{m2}}$$ and $${\Lambda _{m1}}$$ is

The first ionization enthalpies of Be, B, N and O follow the order

The correct order of energy of absorption for the following metal complexes is :

A : [Ni(en)₃]²⁺ , B : [Ni(NH₃)₆]²⁺ , C : [Ni(H₂O)₆]²⁺

Match List I with List II:

Choose the correct answer from the options given below :

Major product of the following reaction is

What is the major product of the following reaction?

Arrange the following in decreasing acidic strength.

$$C{H_3} - C{H_2} - CN\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{Ether}^{C{H_3}MgBr}} A\buildrel {{H_3}{O^ + }} \over \longrightarrow B\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{HCl}^{Zn - Hg}} C$$

The correct structure of C is

Glycosidic linkage between C₁ of $$\alpha$$-glucose and C₂ of $$\beta$$-fructose is found in

In base vs. acid titration, at the end point methyl orange is present as

56.0 L of nitrogen gas is mixed with excess hydrogen gas and it is found that 20 L of ammonia gas is produced. The volume of unused nitrogen gas is found to be _________ L.

When the excited electron of a H atom from n = 5 drops to the ground state, the maximum number of emission lines observed are _____________.

While performing a thermodynamics experiment, a student made the following observations.

HCl + NaOH $$\to$$ NaCl + H₂O $$\Delta$$H = $$-$$57.3 kJ mol^$$-$$1

CH₃COOH + NaOH $$\to$$ CH₃COONa + H₂O $$\Delta$$H = $$-$$55.3 kJ mol^$$-$$1

The enthalpy of ionization of CH₃COOH as calculated by the student is _____________ kJ mol^$$-$$1. (nearest integer)

For the decomposition of azomethane.

CH₃N₂CH₃(g) $$\to$$ CH₃CH₃(g) + N₂(g), a first order reaction, the variation in partial pressure with time at 600 K is given as

The half life of the reaction is __________ $$\times$$ 10^$$-$$5 s. [Nearest integer]

The sum of number of lone pairs of electrons present on the central atoms of XeO₃, XeOF₄ and XeF₆, is ______________

The spin-only magnetic moment value of M³⁺ ion (in gaseous state) from the pairs Cr³⁺ / Cr²⁺, Mn³⁺ / Mn²⁺, Fe³⁺ / Fe²⁺ and Co³⁺ / Co²⁺ that has negative standard electrode potential, is ____________ B.M. [Nearest integer]

A sample of 4.5 mg of an unknown monohydric alcohol, R-OH was added to methylmagnesium iodide. A gas is evolved and is collected and its volume measured to be 3.1 mL. The molecular weight of the unknown alcohol is __________ g/mol. [Nearest integer]

The separation of two coloured substances was done by paper chromatography. The distances travelled by solvent front, substance A and substance B from the base line are 3.25 cm, 2.08 cm and 1.05 cm, respectively. The ratio of R_f values of A to B is _____________.

The total number of monobromo derivatives formed by the alkanes with molecular formula C₅H₁₂ is (excluding stereo isomers) __________.

For $$z \in \mathbb{C}$$ if the minimum value of $$(|z-3 \sqrt{2}|+|z-p \sqrt{2} i|)$$ is $$5 \sqrt{2}$$, then a value Question: of $$p$$ is _____________.

The number of real values of $$\lambda$$, such that the system of linear equations

2x $$-$$ 3y + 5z = 9

x + 3y $$-$$ z = $$-$$18

3x $$-$$ y + ($$\lambda$$² $$-$$ | $$\lambda$$ |)z = 16

has no solutions, is

The number of bijective functions $$f:\{1,3,5,7, \ldots, 99\} \rightarrow\{2,4,6,8, \ldots .100\}$$, such that $$f(3) \geq f(9) \geq f(15) \geq f(21) \geq \ldots . . f(99)$$, is ____________.

The remainder when $$(11)^{1011}+(1011)^{11}$$ is divided by 9 is

$$\lim\limits_{x \rightarrow \frac{\pi}{4}} \frac{8 \sqrt{2}-(\cos x+\sin x)^{7}}{\sqrt{2}-\sqrt{2} \sin 2 x}$$ is equal to

If $$A$$ and $$B$$ are two events such that $$P(A)=\frac{1}{3}, P(B)=\frac{1}{5}$$ and $$P(A \cup B)=\frac{1}{2}$$, then $$P\left(A \mid B^{\prime}\right)+P\left(B \mid A^{\prime}\right)$$ is equal to :

Let $$[t]$$ denote the greatest integer less than or equal to $$t$$. Then the value of the integral $$\int_{-3}^{101}\left([\sin (\pi x)]+e^{[\cos (2 \pi x)]}\right) d x$$ is equal to

Let the point $$P(\alpha, \beta)$$ be at a unit distance from each of the two lines $$L_{1}: 3 x-4 y+12=0$$, and $$L_{2}: 8 x+6 y+11=0$$. If $$P$$ lies below $$L_{1}$$ and above $${ }{L_{2}}$$, then $$100(\alpha+\beta)$$ is equal to :

If the ellipse $$\frac{x^{2}}{a^{2}}+\frac{y^{2}}{b^{2}}=1$$ meets the line $$\frac{x}{7}+\frac{y}{2 \sqrt{6}}=1$$ on the $$x$$-axis and the line $$\frac{x}{7}-\frac{y}{2 \sqrt{6}}=1$$ on the $$y$$-axis, then the eccentricity of the ellipse is :

Let the foci of the ellipse $$\frac{x^{2}}{16}+\frac{y^{2}}{7}=1$$ and the hyperbola $$\frac{x^{2}}{144}-\frac{y^{2}}{\alpha}=\frac{1}{25}$$ coincide. Then the length of the latus rectum of the hyperbola is :

The shortest distance between the lines $$\frac{x+7}{-6}=\frac{y-6}{7}=z$$ and $$\frac{7-x}{2}=y-2=z-6$$ is :

Let $$\vec{a}=\hat{i}-\hat{j}+2 \hat{k}$$ and let $$\vec{b}$$ be a vector such that $$\vec{a} \times \vec{b}=2 \hat{i}-\hat{k}$$ and $$\vec{a} \cdot \vec{b}=3$$. Then the projection of $$\vec{b}$$ on the vector $$\vec{a}-\vec{b}$$ is :

If the mean deviation about median for the numbers 3, 5, 7, 2k, 12, 16, 21, 24, arranged in the ascending order, is 6 then the median is :

$$2 \sin \left(\frac{\pi}{22}\right) \sin \left(\frac{3 \pi}{22}\right) \sin \left(\frac{5 \pi}{22}\right) \sin \left(\frac{7 \pi}{22}\right) \sin \left(\frac{9 \pi}{22}\right)$$ is equal to :

Let $$A=\{1,2,3,4,5,6,7\}$$. Define $$B=\{T \subseteq A$$ : either $$1 \notin T$$ or $$2 \in T\}$$ and $$C=\{T \subseteq A: T$$ the sum of all the elements of $$T$$ is a prime number $$\}$$. Then the number of elements in the set $$B \cup C$$ is ________________.

Let $$f(x)$$ be a quadratic polynomial with leading coefficient 1 such that $$f(0)=p, p \neq 0$$, and $$f(1)=\frac{1}{3}$$. If the equations $$f(x)=0$$ and $$f \circ f \circ f \circ f(x)=0$$ have a common real root, then $$f(-3)$$ is equal to ________________.

Let $$A=\left[\begin{array}{lll} 1 & a & a \\ 0 & 1 & b \\ 0 & 0 & 1 \end{array}\right], a, b \in \mathbb{R}$$. If for some

$$n \in \mathbb{N}, A^{n}=\left[\begin{array}{ccc} 1 & 48 & 2160 \\ 0 & 1 & 96 \\ 0 & 0 & 1 \end{array}\right] $$ then $$n+a+b$$ is equal to ____________.

The sum of the maximum and minimum values of the function $$f(x)=|5 x-7|+\left[x^{2}+2 x\right]$$ in the interval $$\left[\frac{5}{4}, 2\right]$$, where $$[t]$$ is the greatest integer $$\leq t$$, is ______________.

Let $$y=y(x)$$ be the solution of the differential equation

$$\frac{d y}{d x}=\frac{4 y^{3}+2 y x^{2}}{3 x y^{2}+x^{3}}, y(1)=1$$.

If for some $$n \in \mathbb{N}, y(2) \in[n-1, n)$$, then $$n$$ is equal to _____________.

Let $$f$$ be a twice differentiable function on $$\mathbb{R}$$. If $$f^{\prime}(0)=4$$ and $$f(x) + \int\limits_0^x {(x - t)f'(t)dt = \left( {{e^{2x}} + {e^{ - 2x}}} \right)\cos 2x + {2 \over a}x} $$, then $$(2 a+1)^{5}\, a^{2}$$ is equal to _______________.

Let $${a_n} = \int\limits_{ - 1}^n {\left( {1 + {x \over 2} + {{{x^2}} \over 3} + \,\,.....\,\, + \,\,{{{x^{n - 1}}} \over n}} \right)dx} $$ for every n $$\in$$ N. Then the sum of all the elements of the set {n $$\in$$ N : a_n $$\in$$ (2, 30)} is ____________.

Let the area enclosed by the x-axis, and the tangent and normal drawn to the curve $$4{x^3} - 3x{y^2} + 6{x^2} - 5xy - 8{y^2} + 9x + 14 = 0$$ at the point ($$-$$2, 3) be A. Then 8A is equal to ______________.

Let $$x = \sin (2{\tan ^{ - 1}}\alpha )$$ and $$y = \sin \left( {{1 \over 2}{{\tan }^{ - 1}}{4 \over 3}} \right)$$. If $$S = \{ a \in R:{y^2} = 1 - x\} $$, then $$\sum\limits_{\alpha \in S}^{} {16{\alpha ^3}} $$ is equal to _______________.

The electric current in a circular coil of 2 turns produces a magnetic induction B₁ at its centre. The coil is unwound and in rewound into a circular coil of 5 tuns and the same current produces a magnetic induction B₂ at its centre. The ratio of $${{{B_2}} \over {{B_1}}}$$ is

A drop of liquid of density $$\rho$$ is floating half immersed in a liquid of density $${\sigma}$$ and surface tension $$7.5 \times 10^{-4}$$ Ncm^$$-$$1. The radius of drop in $$\mathrm{cm}$$ will be :

(g = 10 ms^$$-$$2)

Two billiard balls of mass 0.05 kg each moving in opposite directions with 10 ms^$$-$$1 collide and rebound with the same speed. If the time duration of contact is t = 0.005 s, then what is the force exerted on the ball due to each other?

For a free body diagram shown in the figure, the four forces are applied in the 'x' and 'y' directions. What additional force must be applied and at what angle with positive x-axis so that the net acceleration of body is zero?

Capacitance of an isolated conducting sphere of radius R₁ becomes n times when it is enclosed by a concentric conducting sphere of radius R₂ connected to earth. The ratio of their radii $$\left( {{{{R_2}} \over {{R_1}}}} \right)$$ is :

The ratio of wavelengths of proton and deuteron accelerated by potential V_p and V_d is 1 : $$\sqrt2$$. Then the ratio of V_p to V_d will be :

For an object placed at a distance 2.4 m from a lens, a sharp focused image is observed on a screen placed at a distance 12 cm from the lens. A glass plate of refractive index 1.5 and thickness 1 cm is introduced between lens and screen such that the glass plate plane faces parallel to the screen. By what distance should the object be shifted so that a sharp focused image is observed again on the screen?

Light wave travelling in air along x-direction is given by $${E_y} = 540\sin \pi \times {10^4}(x - ct)\,V{m^{ - 1}}$$. Then, the peak value of magnetic field of wave will be (Given c = 3 $$\times$$ 10⁸ ms^$$-$$1)

When you walk through a metal detector carrying a metal object in your pocket, it raises an alarm. This phenomenon works on :

A current of 15 mA flows in the circuit as shown in figure. The value of potential difference between the points A and B will be:

The length of a seconds pendulum at a height h = 2R from earth surface will be:

(Given R = Radius of earth and acceleration due to gravity at the surface of earth, g = $$\pi$$² ms^$$-$$2)

Sound travels in a mixture of two moles of helium and n moles of hydrogen. If rms speed of gas molecules in the mixture is $$\sqrt2$$ times the speed of sound, then the value of n will be :

An object is taken to a height above the surface of earth at a distance $${5 \over 4}$$ R from the centre of the earth. Where radius of earth, R = 6400 km. The percentage decrease in the weight of the object will be :

A bag of sand of mass 9.8 kg is suspended by a rope. A bullet of 200 g travelling with speed 10 ms^$$-$$1 gets embedded in it, then loss of kinetic energy will be :

A ball is projected from the ground with a speed 15 ms^$$-$$1 at an angle $$\theta$$ with horizontal so that its range and maximum height are equal,
then 'tan $$\theta$$' will be equal to :

The maximum error in the measurement of resistance, current and time for which current flows in an electrical circuit are $$1 \%, 2 \%$$ and $$3 \%$$ respectively. The maximum percentage error in the detection of the dissipated heat will be :

Hydrogen atom from excited state comes to the ground state by emitting a photon of wavelength $$\lambda$$. The value of principal quantum number '$$n$$' of the excited state will be : ($$\mathrm{R}:$$ Rydberg constant)

A particle is moving in a straight line such that its velocity is increasing at 5 ms^$$-$$1 per meter. The acceleration of the particle is _____________ ms^$$-$$2 at a point where its velocity is 20 ms^$$-$$1.

Three identical spheres each of mass M are placed at the corners of a right angled triangle with mutually perpendicular sides equal to 3 m each. Taking point of intersection of mutually perpendicular sides as origin, the magnitude of position vector of centre of mass of the system will be $$\sqrt x$$ m. The value of x is ____________.

A block of ice of mass 120 g at temperature 0$$^\circ$$C is put in 300 g of water at 25$$^\circ$$C. The x g of ice melts as the temperature of the water reaches 0$$^\circ$$C. The value of x is _____________.

[Use specific heat capacity of water = 4200 Jkg^$$-$$1K^$$-$$1, Latent heat of ice = 3.5 $$\times$$ 10⁵ Jkg^$$-$$1]

$${x \over {x + 4}}$$ is the ratio of energies of photons produced due to transition of an electron of hydrogen atom from its

(i) third permitted energy level to the second level and

(ii) the highest permitted energy level to the second permitted level.

The value of x will be ____________.

Two ideal diodes are connected in the network as shown in figure. The equivalent resistance between A and B is __________ $$\Omega$$.

Two parallel plate capacitors of capacity C and 3C are connected in parallel combination and charged to a potential difference 18 V. The battery is then disconnected and the space between the plates of the capacitor of capacity C is completely filled with a material of dielectric constant 9. The final potential difference across the combination of capacitors will be ___________ V.

A convex lens of focal length 20 cm is placed in front of a convex mirror with principal axis coinciding each other. The distance between the lens and mirror is 10 cm. A point object is placed on principal axis at a distance of 60 cm from the convex lens. The image formed by combination coincides the object itself. The focal length of the convex mirror is ____________ cm.

Magnetic flux (in weber) in a closed circuit of resistance 20 $$\Omega$$ varies with time t(s) at $$\phi$$ = 8t² $$-$$ 9t + 5. The magnitude of the induced current at t = 0.25 s will be ____________ mA.