Observation of “Rhumann’s purple” is a confirmatory test for the presence of :

The “N” which does not contribute to the basicity for the compound is :

Fluorination of an aromatic ring is easily accomplished by treating a diazonium salt with HBF₄. Which of the following conditions is correct about this reaction ?

The correct statement about the synthesis of erythritol (C(CH₂OH)4) used in the preparation of PETN is :

Which one of the following reagents is not suitable for the elimination reaction ?

Consider the reaction sequence below :


X is:

Bromination of cyclohexene under conditions given below yields :

Sodium extract is heated with concentrated HNO₃ before testing for halogens because :

The transition metal ions responsible for color in ruby and emerald are, respectively :

Which of the following is an example of homoleptic complex?

Identify the correct statement :

An aqueous solution of a salt MX₂ at certain temperature has a van’t Hoff factor of 2. The degree of dissociation for this solution of the salt is :

The following statements concern elements in the periodic table. Which of the following is true ?

The rate law for the reaction below is given by the expression k [A] [B]

A + B $$ \to $$ Product

If the concentration of B is increased from 0.1 to 0.3 mole, keeping the value of A at 0.1 mole, the rate constant will be :

A solid XY kept in an evacuated sealed container undergoes decomposition to form a mixture of gases X and Y at temperature T. The equilibrium pressure is 10 bar in this vessel. K_p for this reaction is :

Oxidation of succinate ion produces ethylene and carbon dioxide gases. On passing 0.2 Faraday electricity through an aqueous solution of potassium succinate, the total volume of gases (at both cathode and anode) at STP (1 atm and 273 K) is :

If 100 mole of H₂O₂ decompose at 1 bar and 300 K, the work done (kJ) by one mole of O₂(g) as it expands against 1 bar pressure is :

2H₂O₂(l)    $$\rightleftharpoons$$    2H₂O(l) + O₂(g)

(R = 8.3 J K ^$$-$$1 mol^$$-$$1)

The bond angle H - X - H is the greatest in the compound :

Aqueous solution of which salt will not contain ions with the electronic configuration 1s²2s²2p⁶3s²3p⁶ ?

The volume of 0.1N dibasic acid sufficient to neutralize 1 g of a base that furnishes 0.04 mole of OH⁻ in aqueous solution is :

Let a₁, a₂, a₃, . . . . . . . , a_n, . . . . . be in A.P.

If a₃ + a₇ + a₁₁ + a₁₅ = 72,

then the sum of its first 17 terms is equal to :

If    $${{{}^{n + 2}C{}_6} \over {{}^{n - 2}{P_2}}}$$ = 11, then n satisfies the equation :

If the coefficients of x⁻² and x⁻⁴ in the expansion of $${\left( {{x^{{1 \over 3}}} + {1 \over {2{x^{{1 \over 3}}}}}} \right)^{18}},\left( {x > 0} \right),$$ are m and n respectively, then $${m \over n}$$ is equal to :

If    A = $$\left[ {\matrix{ { - 4} & { - 1} \cr 3 & 1 \cr } } \right]$$,

then the determinant of the matrix (A²⁰¹⁶ − 2A²⁰¹⁵ − A²⁰¹⁴) is :

Let A be a 3 $$ \times $$ 3 matrix such that A² $$-$$ 5A + 7I = 0

Statement - I :  

A^$$-$$1 = $${1 \over 7}$$ (5I $$-$$ A).

Statement - II :

The polynomial A³ $$-$$ 2A² $$-$$ 3A + I can be reduced to 5(A $$-$$ 4I).

Then :

If x is a solution of the equation, $$\sqrt {2x + 1} $$ $$ - \sqrt {2x - 1} = 1,$$ $$\,\,\left( {x \ge {1 \over 2}} \right),$$ then $$\sqrt {4{x^2} - 1} $$ is equal to :

Let P = {$$\theta $$ : sin$$\theta $$ $$-$$ cos$$\theta $$ = $$\sqrt 2 \,\cos \theta $$}

and Q = {$$\theta $$ : sin$$\theta $$ + cos$$\theta $$ = $$\sqrt 2 \,\sin \theta $$} be two sets. Then

The sum $$\sum\limits_{r = 1}^{10} {\left( {{r^2} + 1} \right) \times \left( {r!} \right)} $$ is equal to :

For x $$ \in $$ R, x $$ \ne $$ 0, if y(x) is a differentiable function such that

x $$\int\limits_1^x y $$ (t) dt = (x + 1) $$\int\limits_1^x ty $$ (t) dt,  then y (x) equals :

(where C is a constant.)

If   A > 0, B > 0   and    A + B = $${\pi \over 6}$$,

then the minimum value of tanA + tanB is :

The mean of 5 observations is 5 and their variance is 124. If three of the observations are 1, 2 and 6 ; then the mean deviation from the mean of the data is :

Let ABC be a triangle whose circumcentre is at P. If the position vectors of A, B, C and P are $$\overrightarrow a ,\overrightarrow b ,\overrightarrow c $$ and $${{\overrightarrow a + \overrightarrow b + \overrightarrow c } \over 4}$$ respectively, then the position vector of the orthocentre of this triangle, is :

ABC is a triangle in a plane with vertices

A(2, 3, 5), B(−1, 3, 2) and C($$\lambda $$, 5, $$\mu $$).

If the median through A is equally inclined to the coordinate axes, then the value of ($$\lambda $$³ + $$\mu $$³ + 5) is :

A hyperbola whose transverse axis is along the major axis of the conic, $${{{x^2}} \over 3} + {{{y^2}} \over 4} = 4$$ and has vertices at the foci of this conic. If the eccentricity of the hyperbola is $${3 \over 2},$$ then which of the following points does NOT lie on it?

The solution of the differential equation

$${{dy} \over {dx}}\, + \,{y \over 2}\,\sec x = {{\tan x} \over {2y}},\,\,$$

where 0 $$ \le $$ x < $${\pi \over 2}$$, and y (0) = 1, is given by :

A straight line through origin O meets the lines 3y = 10 − 4x and 8x + 6y + 5 = 0 at points A and B respectively. Then O divides the segment AB in the ratio :

A ray of light is incident along a line which meets another line, 7x − y + 1 = 0, at the point (0, 1). The ray is then reflected from this point along the line, y + 2x = 1. Then the equation of the line of incidence of the ray of light is :

The value of the integral

$$\int\limits_4^{10} {{{\left[ {{x^2}} \right]dx} \over {\left[ {{x^2} - 28x + 196} \right] + \left[ {{x^2}} \right]}}} ,$$

where [x] denotes the greatest integer less than or equal to x, is :

The integral $$\int {{{dx} \over {\left( {1 + \sqrt x } \right)\sqrt {x - {x^2}} }}} $$ is equal to :

(where C is a constant of integration.)

Let f(x) = sin⁴x + cos⁴ x. Then f is an increasing function in the interval :

Let a, b $$ \in $$ R, (a $$ \ne $$ 0). If the function f defined as

$$f\left( x \right) = \left\{ {\matrix{ {{{2{x^2}} \over a}\,\,,} & {0 \le x < 1} \cr {a\,\,\,,} & {1 \le x < \sqrt 2 } \cr {{{2{b^2} - 4b} \over {{x^3}}},} & {\sqrt 2 \le x < \infty } \cr } } \right.$$

is continuous in the interval [0, $$\infty $$), then an ordered pair ( a, b) is :

$$\mathop {\lim }\limits_{x \to 0} \,{{{{\left( {1 - \cos 2x} \right)}^2}} \over {2x\,\tan x\, - x\tan 2x}}$$ is :

Consider an electromagnetic wave propagating in vacuum. Choose the correct statement :

Which of the following shows the correct relationship between the pressure ‘P’ and density $$\rho $$ of an ideal gas at constant temperature ?

In the figure shown ABC is a uniform wire. If centre of mass of wire lies vertically below point A, then $${{BC} \over {AB}}$$ is close to :

Velocity-time graph for a body of mass 10 kg is shown in figure. Work-done on the body in first two seconds of the motion is :

A thin 1 m long rod has a radius of 5 mm. A force of 50 $$\pi $$kN is applied at one end to determine its Young’s modulus. Assume that the force is exactly known. If the least count in the measurement of all lengths is 0.01 mm, which of the following statements is false ?

To determine refractive index of glass slab using a travelling microscope, minimum number of readings required are :

A particle of mass m is acted upon by a force F given by the empirical law F =$${R \over {{t^2}}}\,v\left( t \right).$$ If this law is to be tested experimentally by observing the motion starting from rest, the best way is to plot :

A neutron moving with a speed ‘v’ makes a head on collision with a stationary hydrogen atom in ground state. The minimum kinetic energy of the neutron for which inelastic collision will take place is :

Two stars are 10 light years away from the earth. They are seen through a telescope of objective diameter 30 cm. The wavelength of light is 600 nm. To see the stars just resolved by the telescope, the minimum distance between them should be (1 light year = 9.46 $$ \times $$ 10¹⁵ m) of the order of :

A photoelectric surface is illuminated successively by monochromatic light of wavelengths $$\lambda $$ and $${\lambda \over 2}.$$ If the maximum kinetic energy of the emitted photoelectrons in the second case is 3 times that in the first case, the work function of the surface is :

A bottle has an opening of radius a and length b. A cork of length b and radius (a + $$\Delta $$a) where ($$\Delta $$a < < a) is compressed to fit into the opening completely (See figure). If the bulk modulus of cork is B and frictional coefficient between the bottle and cork is $$\mu $$ then the force needed to push the cork into the bottle is :

A conducting metal circular-wire-loop of radius r is placed perpendicular to a magnetic field which varies with time as
B = B₀e$${^{{{ - t} \over r}}}$$ , where B₀ and $$\tau $$ are constants, at time t = 0. If the resistance of the loop is R then the heat generated in the loop after a long time (t $$ \to $$ $$\infty $$) is :

Within a spherical charge distribution of charge density $$\rho $$(r), N equipotential surfaces of potential V₀, V₀ + $$\Delta $$V, V₀ + 2$$\Delta $$V, .......... V₀ + N$$\Delta $$V ($$\Delta $$ V > 0), are drawn and have increasing radii r₀, r₁, r₂,..........r_N, respectively. If the difference in the radii of the surfaces is constant for all values of V₀ and $$\Delta $$V then :

In an engine the piston undergoes vertical simple harmonic motion with amplitude 7 cm. A washer rests on top of the piston and moves with it. The motor speed is slowly increased. The frequency of the piston at which the washer no longer stays in contact with the piston, is close to :

The resistance of an electrical toaster has a temperature dependence given by R(T) = R₀ [1 + $$\alpha $$(T − T₀)] in its range of operation. At T₀ = 300 K, R = 100 $$\Omega $$ and at T = 500 K, R = 120 $$\Omega $$. The toaster is connected to a voltage source at 200 V and its temperature is raised at a constant rate from 300 to 500 K in 30 s. The total work done in raising the temperature is :

An astronaut of mass m is working on a satellite orbiting the earth at a distance h from the earth’s surface. The radius of the earth is R, while its mass is M. The gravitational pull F_G on the astronaut is :

Concrete mixture is made by mixing cement, stone and sand in a rotating cylindrical drum. If the drum rotates too fast, the ingredients remain stuck to the wall of the drum and proper mixing of ingredients does not take place. The maximum rotational speed of the drum in revolutions per minute(rpm) to ensure proper mixing is close to :

(Take the radius of the drum to be 1.25 m and its axle to be horizontal) :

A, B, C and D are four different physical quantities having different dimensions. None of them is dimensionless. But we know that the equation AD = C ln (BD) holds true. Then which of the combination is not a meaningful quantity ?

A particle of mass M is moving in a circle of fixed radius R in such a way that its centripetal acceleration at time t is given by n² R t² where n is a constant. The power delivered to the particle by the force acting on it, is :

A galvanometer has a 50 division scale. Battery has no internal resistance. It is found that there is deflection of 40 divisions when R = 2400 $$\Omega $$. Deflection becomes 20 divisions when resistance taken from resistance box is 4900 $$\Omega $$. Then we can conclude :

To get an output of 1 from the circuit shown in figure the input must be :

Figure shows a network of capacitors where the numbers indicates capacitances in micro Farad. The value of capacitance C if the equivalent capacitance between point A and B is to be 1 $$\mu $$F is :

Consider a thin metallic sheet perpendicular to the plane of the paper moving with speed ‘v’ in a uniform magnetic field B going into the plane of the paper (See figure). If charge densities $$\sigma $$₁ and $$\sigma $$₂ are induced on the left and right surfaces, respectively, of the sheet then (ignore fringe effects) :

A hemispherical glass body of radius 10 cm and refractive index 1.5 is silvered on its curved surface. A small air bubble is 6 cm below the flat surface inside it along the axis. The position of the image of the air bubble made by the mirror is seen :