The Gibbs change (in J) for the given reaction at
[Cu²⁺] = [Sn²⁺] = 1 M and 298K is :

Cu(s) + Sn²⁺(aq.) $$ \to $$ Cu²⁺(aq.) + Sn(s);

($$E_{S{n^{2 + }}|Sn}^0 = - 0.16\,V$$,
$$E_{C{u^{2 + }}|Cu}^0 = 0.34\,V$$)
Take F = 96500 C mol^–1)

The oxidation states of iron atoms in compounds (A), (B) and (C), respectively, are x, y and z. The sum of x, y and z is ________.

Na₄[Fe(CN)₅(NOS)]
       (A)

Na₄[FeO₄]
       (B)

[Fe₂(CO)₉]
       (C)

The internal energy change (in J) When 90 g of water undergoes complete evaporation at 100^oC is ____________.

(Given : $$\Delta $$H_vap for water at 373 K = 41 kJ/mol,
R = 8.314 JK^–1 mol^–1)

The number of chiral carbons present in the molecule given below is _____ .

The increasing order of the following compounds towards HCN addition is :

The major aromatic product C in the following reaction sequence will be :

In general the property (magnitudes only) that show an opposite trend in comparison to other properties across a period is

While titrating dilute HCl solution with aqueous NaOH, which of the following will not be required?

The IUPAC name for the following compound is

The major product in the following reaction is :

Which of the following compunds will show retention in configuration on nucleophilic substitution by OH^– ion?

Consider that a d⁶ metal ion (M²⁺) forms a complex with aqua ligands, and the spin only magnetic moment of the complex is 4.90 BM. The geometry and the crystal field stabilization energy of the complex is

For octahedral Mn(II) and tetrahedral Ni(II) complexes, consider the following statements:

(I) both the complexes can be high spin.
(II) Ni(II) complex can very rarely be low spin.
(III) with strong field ligands, Mn(II) complexes can be low spin.
(IV)aqueous solution of Mn(II) ions is yellow in colour.

The correct statements are :

Consider the following rections:

'x', 'y' and 'z' in these reactions are respectively.

An open beaker of water in equilibrium with water vapour is in a sealed container. When a few grams of glucose are added to the beaker of water, the rate at which water molecules :

For the following Assertion and Reason, the correct option is

Assertion (A): When Cu (II) and sulphide ions are mixed, they react together extremely quickly to give a solid.

Reason (R): The equilibrium constant of
Cu²⁺(aq) + S^2–(aq) ⇌ CuS(s) is high because the solubility product is low.

The figure that is not a direct manifestation of the quantum nature of atoms is :

If AB₄ molecule is a polar molecule, a possible geometry of AB₄ is

In Carius method of estimation of halogen, 0.172 g of an organic compound showed presence of 0.08 g of bromine. Which of these is the correct structure of the compound?

Let S be the set of all $$\lambda $$ $$ \in $$ R for which the system of linear equations

2x – y + 2z = 2
x – 2y + $$\lambda $$z = –4
x + $$\lambda $$y + z = 4

has no solution. Then the set S :

If a function f(x) defined by

$$f\left( x \right) = \left\{ {\matrix{ {a{e^x} + b{e^{ - x}},} & { - 1 \le x < 1} \cr {c{x^2},} & {1 \le x \le 3} \cr {a{x^2} + 2cx,} & {3 < x \le 4} \cr } } \right.$$

be continuous for some $$a$$, b, c $$ \in $$ R and f'(0) + f'(2) = e, then the value of of $$a$$ is :

Area (in sq. units) of the region outside

$${{\left| x \right|} \over 2} + {{\left| y \right|} \over 3} = 1$$ and inside the ellipse $${{{x^2}} \over 4} + {{{y^2}} \over 9} = 1$$ is :

Box I contains 30 cards numbered 1 to 30 and Box II contains 20 cards numbered 31 to 50. A box is selected at random and a card is drawn from it. The number on the card is found to be a non-prime number. The probability that the card was drawn from Box I is :

Let $$\alpha $$ > 0, $$\beta $$ > 0 be such that
$$\alpha $$³ + $$\beta $$² = 4. If the maximum value of the term independent of x in
the binomial expansion of $${\left( {\alpha {x^{{1 \over 9}}} + \beta {x^{ - {1 \over 6}}}} \right)^{10}}$$ is 10k,
then k is equal to :

Let A be a 2 $$ \times $$ 2 real matrix with entries from {0, 1} and |A| $$ \ne $$ 0. Consider the following two statements :

(P) If A $$ \ne $$ I₂ , then |A| = –1
(Q) If |A| = 1, then tr(A) = 2,

where I₂ denotes 2 $$ \times $$ 2 identity matrix and tr(A) denotes the sum of the diagonal entries of A. Then :

The sum of the first three terms of a G.P. is S and their product is 27. Then all such S lie in :

If the letters of the word 'MOTHER' be permuted and all the words so formed (with or without meaning) be listed as in a dictionary, then the position of the word 'MOTHER' is ______.

If $$\mathop {\lim }\limits_{x \to 1} {{x + {x^2} + {x^3} + ... + {x^n} - n} \over {x - 1}}$$ = 820,
(n $$ \in $$ N) then the value of n is equal to _______.

Let $$\overrightarrow a $$, $$\overrightarrow b $$ and $$\overrightarrow c $$ be three unit vectors such that
$${\left| {\overrightarrow a - \overrightarrow b } \right|^2}$$ + $${\left| {\overrightarrow a - \overrightarrow c } \right|^2}$$ = 8.

Then $${\left| {\overrightarrow a + 2\overrightarrow b } \right|^2}$$ + $${\left| {\overrightarrow a + 2\overrightarrow c } \right|^2}$$ is equal to ______.

The integral $$\int\limits_0^2 {\left| {\left| {x - 1} \right| - x} \right|dx} $$
is equal to______.

If p(x) be a polynomial of degree three that has a local maximum value 8 at x = 1 and a local minimum value 4 at x = 2; then p(0) is equal to :

The value of

$${\left( {{{1 + \sin {{2\pi } \over 9} + i\cos {{2\pi } \over 9}} \over {1 + \sin {{2\pi } \over 9} - i\cos {{2\pi } \over 9}}}} \right)^3}$$ is :

The domain of the function
f(x) = $${\sin ^{ - 1}}\left( {{{\left| x \right| + 5} \over {{x^2} + 1}}} \right)$$ is (– $$\infty $$, -a]$$ \cup $$[a, $$\infty $$). Then a is equal to :

Let $$\alpha $$ and $$\beta $$ be the roots of the equation
5x² + 6x – 2 = 0. If S_n = $$\alpha $$ⁿ + $$\beta $$ⁿ, n = 1, 2, 3...., then :

If R = {(x, y) : x, y $$ \in $$ Z, x² + 3y² $$ \le $$ 8} is a relation on the set of integers Z, then the domain of R^–1 is :

Let X = {x $$ \in $$ N : 1 $$ \le $$ x $$ \le $$ 17} and
Y = {ax + b: x $$ \in $$ X and a, b $$ \in $$ R, a > 0}. If mean
and variance of elements of Y are 17 and 216
respectively then a + b is equal to :

Let y = y(x) be the solution of the differential equation,
$${{2 + \sin x} \over {y + 1}}.{{dy} \over {dx}} = - \cos x$$, y > 0,y(0) = 1.
If y($$\pi $$) = a and $${{dy} \over {dx}}$$ at x = $$\pi $$ is b, then the ordered pair (a, b) is equal to :

In a reactor, 2 kg of ₉₂U²³⁵ fuel is fully used up in 30 days. The energy released per fission is 200 MeV. Given that the Avogadro number, N = 6.023 $$ \times $$ 10²⁶ per kilo mole and 1 eV = 1.6 × 10^–19 J. The power output of the reactor is close to

A spherical mirror is obtained as shown in the figure from a hollow glass sphere. If an object is positioned in front of the mirror, what will be the nature and magnification of the image of the object?
(Figure drawn as schematic and not to scale)

Consider four conducting materials copper, tungsten, mercury and aluminium with resistivity $$\rho $$_C, $$\rho $$_T, $$\rho $$_M and $$\rho $$_A respectively. Then :

A particle of mass m with an initial velocity $$u\widehat i$$ collides perfectly elastically with a mass 3 m at rest. It moves with a velocity $$v\widehat j$$ after collision, then, v is given by :

A gas mixture consists of 3 moles of oxygen and 5 moles of argon at temperature T. Assuming the gases to be ideal and the oxygen bond to be rigid, the total internal energy (in units of RT) of the mixture is :

Train A and train B are running on parallel tracks in the opposite directions with speeds of 36 km/hour and 72 km/hour, respectively. A person is walking in train A in the direction opposite to its motion with a speed of 1.8 km/ hour. Speed (in ms^–1) of this person as observed from train B will be close to :
(take the distance between the tracks as negligible)

The least count of the main scale of a vernier callipers is 1 mm. Its vernier scale is divided into 10 divisions and coincide with 9 divisions of the main scale. When jaws are touching each other, the 7^th division of vernier scale coincides with a division of main scale and the zero of vernier scale is lying right side of the zero of main scale. When this vernier is used to measure length of a cylinder the zero of the vernier scale between 3.1 cm and 3.2 cm and 4^th VSD coincides with a main scale division. The length of the cylinder is : (VSD is vernier scale division)

If speed V, area A and force F are chosen as fundamental units, then the dimension of Young’s modulus will be

The mass density of a spherical galaxy varies as $${K \over r}$$ over a large distance ‘r’ from its centre. In that region, a small star is in a circular orbit of radius R. Then the period of revolution, T depends on R as :

When radiation of wavelength $$\lambda $$ is used to illuminate a metallic surface, the stopping potential is V. When the same surface is illuminated with radiation of wavelength 3$$\lambda $$, the stopping potential is $${V \over 4}$$. If the threshold wavelength for the metallic surface is n$$\lambda $$ then value of n will be __________.

A bead of mass m stays at point P(a, b) on a wire bent in the shape of a parabola y = 4Cx² and rotating with angular speed $$\omega $$ (see figure). The value of $$\omega $$ is (neglect friction) :

Shown in the figure is rigid and uniform one meter long rod AB held in horizontal position by two strings tied to its ends and attached to the ceiling. The rod is of mass ‘m’ and has another weight of mass 2 m hung at a distance of 75 cm from A. The tension in the string at A is :

Two identical strings X and Z made of same material have tension T_X and T_Z in them. If their fundamental frequencies are 450 Hz and 300 Hz, respectively, then the ratio T_X/T_Z is

A uniform cylinder of mass M and radius R is to be pulled over a step of height a (a < R) by applying a force F at its centre ‘O’ perpendicular to the plane through the axes of the cylinder on the edge of the step (see figure). The minimum value of F required is :

A plane electromagnetic wave, has
frequency of 2.0 $$ \times $$ 10¹⁰ Hz and its energy density is 1.02 $$ \times $$ 10^–8 J/m³ in vacuum. The amplitude of the magnetic field of the wave is close to
( $${1 \over {4\pi {\varepsilon _0}}} = 9 \times {10^9}{{N{m^2}} \over {{C^2}}}$$ and speed of light
= 3 $$ \times $$ 10⁸ ms^–1)

A charged particle (mass m and charge q)
moves along X-axis with velocity V₀. When it
passes through the origin it enters a region having uniform electric field
$$\overrightarrow E = - E\widehat j$$ which extends upto x = d.
Equation of path of electron in the region x > d is

A cylindrical vessel containing a liquid is rotated about its axis so that the liquid rises at its sides as shown in the figure. The radius of vessel is 5 cm and the angular speed of rotation is $$\omega $$ rad s^–1. The difference in the height, h (in cm) of liquid at the centre of vessel and at the side will be :

Interference fringes are observed on a screen by illuminating two thin slits 1 mm apart with a light source ($$\lambda $$ = 632.8 nm). The distance between the screen and the slits is 100 cm. If a bright fringe is observed on a screen at a distance of 1.27 mm from the central bright fringe, then the path difference between the waves, which are reaching this point from the slits is close is

A 5 $$\mu $$F capacitor is charged fully by a 220 V supply. It is then disconnected from the supply and is connected in series to another uncharged 2.5 $$\mu $$F capacitor. If the energy change during the charge redistribution is $${X \over {100}}J$$ then value of X to the nearest integer is _____.

A circular coil of radius 10 cm is placed in a uniform magnetic field of 3.0 $$ \times $$ 10^–5 T with its plane perpendicular to the field initially. It is rotated at constant angular speed about an axis along the diameter of coil and perpendicular to magnetic field so that it undergoes half of rotation in 0.2 s. The maximum value of EMF induced (in $$\mu $$V) in the coil will be close to the integer _______.

An engine takes in 5 moles of air at 20^oC and 1 atm, and compresses it adiabatically to 1/10^th of the original volume. Assuming air to be a diatomic ideal gas made up of rigid molecules, the change in its internal energy during this process comes out to be X kJ. The value of X to the nearest integer is________.

A small block starts slipping down from a point B on an inclined plane AB, which is making an angle $$\theta $$ with the horizontal section BC is smooth and the remaining section CA is rough with a coefficient of friction $$\mu $$. It is found that the block comes to rest as it reaches the bottom (point A) of the inclined plane. If BC = 2AC, the coefficient of friction is given by $$\mu $$ = ktan $$\theta $$ . The value of k is _________.

A beam of protons with speed 4 × 10⁵ ms^–1 enters a uniform magnetic field of 0.3 T at an angle of 60° to the magnetic field. The pitch of the resulting helical path of protons is close to :
(Mass of the proton = 1.67 $$ \times $$ 10^–27 kg, charge
of the proton = 1.69 $$ \times $$ 10^–19 C)