The test to distinguish primary, secondary and tertiary amines is :

Consider the following sequence for aspartic acid :


The pI (isoelectric point) of aspartic acid is :

The plot shows the variation of −$$ln$$ K_p versus temperature for the two reactions.

M(s) + $${1 \over 2}$$ O₂(g) $$ \to $$ MO(s) and

C(s) + $${1 \over 2}$$ O₂(g) $$ \to $$ CO(s)


Identify the correct statement :

Bouveault-Blanc reduction reaction involves :

The gas evolved on heating CH₃MgBr in methanol is :

5 L of an alkane requires 25 L of oxygen for its complete combustion. If all volumes are measured at constant temperature and pressure, the alkane is :

The hydrocarbon with seven carbon atoms containing a neopentyl and a vinyl group is :

An organic compound contains C, H and S. The minimum molecular weight of the compound containing 8% sulphur is :

(atomic weight of S = 32 amu)

Which one of the following species is stable in aqueous solution?

Which one of the following complexes will consume more equivalents of aqueous solution of Ag(NO₃)?

Identify the correct trend given below : (Atomic No.=Ti : 22, Cr : 24 and Mo : 42)

A reaction at 1 bar is non-spontaneous at low temperature but becomes spontaneous at high temperature. Identify the correct statement about the reaction among the following :

The group of molecules having identical shape is :

The non-metal that does not exhibit positive oxidation state is :

The reaction of ozone with oxygen atoms in the presence of chlorine atoms can occur by a two step process shown below :

O₃(g) + Cl$${^ \bullet }$$ (g) $$ \to $$ O₂(g) + ClO$${^ \bullet }$$ (g) . . . . . .(i)

k_i = 5.2 × 10⁹ L mol⁻¹ s⁻¹

ClO$${^ \bullet }$$(g) + O$${^ \bullet }$$(g) $$ \to $$ O₂(g) + Cl$${^ \bullet }$$ (g) . . . . . . (ii)

k_ii = 2.6 × 10¹⁰ L mol⁻¹ s⁻¹

The closest rate constant for the overall reaction O₃(g) + O$${^ \bullet }$$ (g) $$ \to $$ 2 O₂(g) is :

The solubility of N₂ in water at 300 K and 500 torr partial pressure is 0.01 g L⁻¹. The solubility (in g L⁻¹) at 750 torr partial pressure is :

The total number of orbitals associated with the principal quantum number 5 is :

What will occur if a block of copper metal is dropped into a beaker containing a solution of 1M ZnSO₄?

For the reaction,
A(g) + B(g) $$ \to $$ C(g) + D(g), $$\Delta $$H^o and $$\Delta $$S^o are, respectively, − 29.8 kJ mol⁻¹ and −0.100 kJ K⁻¹ mol⁻¹ at 298 K. The equilibrium constant for the reaction at 298 K is :

Which intermolecular force is most responsible in allowing xenon gas to liquefy?

The amount of arsenic pentasulphide that can be obtained when 35.5 g arsenic acid istreated with excess H₂S in the presence of conc. HCl ( assuming 100% conversion) is :

For x $$ \in $$ R, x $$ \ne $$ -1,

if (1 + x)²⁰¹⁶ + x(1 + x)²⁰¹⁵ + x²(1 + x)²⁰¹⁴ + . . . . + x²⁰¹⁶ =

$$\sum\limits_{i = 0}^{2016} {{a_i}} \,{x^i},\,\,$$ then a₁₇ is equal to :

Let x, y, z be positive real numbers such that x + y + z = 12 and x³y⁴z⁵ = (0.1) (600)³. Then x³ + y³ + z³is equal to :

If the four letter words (need not be meaningful ) are to be formed using the letters from the word “MEDITERRANEAN” such that the first letter is R and the fourth letter is E, then the total number of all such words is :

The number of distinct real roots of the equation,

$$\left| {\matrix{ {\cos x} & {\sin x} & {\sin x} \cr {\sin x} & {\cos x} & {\sin x} \cr {\sin x} & {\sin x} & {\cos x} \cr } } \right| = 0$$ in the interval $$\left[ { - {\pi \over 4},{\pi \over 4}} \right]$$ is :

If the equations x² + bx−1 = 0 and x² + x + b = 0 have a common root different from −1, then $$\left| b \right|$$ is equal to :

If P = $$\left[ {\matrix{ {{{\sqrt 3 } \over 2}} & {{1 \over 2}} \cr { - {1 \over 2}} & {{{\sqrt 3 } \over 2}} \cr } } \right],A = \left[ {\matrix{ 1 & 1 \cr 0 & 1 \cr } } \right]\,\,\,$$

Q = PAP^T, then P^T Q²⁰¹⁵ P is :

The point represented by 2 + i in the Argand plane moves 1 unit eastwards, then 2 units northwards and finally from there $$2\sqrt 2 $$ units in the south-westwardsdirection. Then its new position in the Argand plane is at the point represented by :

For x $$ \in $$ R, x $$ \ne $$ 0, Let f₀(x) = $${1 \over {1 - x}}$$ and
f_n+1 (x) = f₀(f_n(x)), n = 0, 1, 2, . . . .

Then the value of f₁₀₀(3) + f₁$$\left( {{2 \over 3}} \right)$$ + f₂$$\left( {{3 \over 2}} \right)$$ is equal to :

The value of $$\sum\limits_{r = 1}^{15} {{r^2}} \left( {{{{}^{15}{C_r}} \over {{}^{15}{C_{r - 1}}}}} \right)$$ is equal to :

A circle passes through (−2, 4) and touches the y-axis at (0, 2). Which one of the following equations can represent a diameter of this circle?

If  m and M are the minimum and the maximum values of

4 + $${1 \over 2}$$ sin² 2x $$-$$ 2cos⁴ x, x $$ \in $$ R, then M $$-$$ m is equal to :

Let a and b respectively be the semitransverse and semi-conjugate axes of a hyperbola whose eccentricity satisfies the equation 9e² − 18e + 5 = 0. If S(5, 0) is a focus and 5x = 9 is the corresponding directrix of this hyperbola, then a² − b² is equal to :

In a triangle ABC, right angled at the vertex A, if the position vectors of A, B and C are respectively 3$$\widehat i$$ + $$\widehat j$$ $$-$$ $$\widehat k$$,   $$-$$$$\widehat i$$ + 3$$\widehat j$$ + p$$\widehat k$$ and 5$$\widehat i$$ + q$$\widehat j$$ $$-$$ 4$$\widehat k$$, then the point (p, q) lies on a line :

If A and B are any two events such that P(A) = $${2 \over 5}$$ and P (A $$ \cap $$ B) = $${3 \over {20}}$$, hen the conditional probability, P(A $$\left| {} \right.$$(A' $$ \cup $$ B')), where A' denotes the complement of A, is equal to :

If the mean deviation of the numbers 1, 1 + d, ..., 1 +100d from their mean is 255, then a value of d is :

The shortest distance between the lines $${x \over 2} = {y \over 2} = {z \over 1}$$ and
$${{x + 2} \over { - 1}} = {{y - 4} \over 8} = {{z - 5} \over 4}$$ lies in the interval :

The point (2, 1) is translated parallel to the line L : x− y = 4 by $$2\sqrt 3 $$ units. If the newpoint Q lies in the third quadrant, then the equation of the line passing through Q and perpendicular to L is :

The area (in sq. units) of the region described by

A= {(x, y) $$\left| {} \right.$$y$$ \ge $$ x² $$-$$ 5x + 4, x + y $$ \ge $$ 1, y $$ \le $$ 0} is :

If a variable line drawn through the intersection of the lines $${x \over 3} + {y \over 4} = 1$$ and $${x \over 4} + {y \over 3} = 1,$$ meets the coordinate axes at A and B, (A $$ \ne $$ B), then the locus of the midpoint of AB is :

If   f(x) is a differentiable function in the interval (0, $$\infty $$) such that f (1) = 1 and

$$\mathop {\lim }\limits_{t \to x} $$   $${{{t^2}f\left( x \right) - {x^2}f\left( t \right)} \over {t - x}} = 1,$$ for each x > 0, then $$f\left( {{\raise0.5ex\hbox{$\scriptstyle 3$} \kern-0.1em/\kern-0.15em \lower0.25ex\hbox{$\scriptstyle 2$}}} \right)$$ equal to :

If   $$2\int\limits_0^1 {{{\tan }^{ - 1}}xdx = \int\limits_0^1 {{{\cot }^{ - 1}}} } \left( {1 - x + {x^2}} \right)dx,$$

then $$\int\limits_0^1 {{{\tan }^{ - 1}}} \left( {1 - x + {x^2}} \right)dx$$ is equalto :

The minimum distance of a point on the curve y = x²−4 from the origin is :

If   $$\int {{{dx} \over {{{\cos }^3}x\sqrt {2\sin 2x} }}} = {\left( {\tan x} \right)^A} + C{\left( {\tan x} \right)^B} + k,$$

where k is a constant of integration, then A + B +C equals :

If the function

f(x) = $$\left\{ {\matrix{ { - x} & {x < 1} \cr {a + {{\cos }^{ - 1}}\left( {x + b} \right),} & {1 \le x \le 2} \cr } } \right.$$

is differentiable at x = 1, then $${a \over b}$$ is equal to :

If    $$\mathop {\lim }\limits_{x \to \infty } {\left( {1 + {a \over x} - {4 \over {{x^2}}}} \right)^{2x}} = {e^3},$$ then 'a' is equal to :

A 50 $$\Omega $$ resistance is connected to a battery of 5 V. A galvanometer of resistance 100 $$\Omega $$ is to be used as an ammeter to measure current through the resistance, for this a resistance r_s is connected to the galvanometer. Which of the following connections should be employed if the measured current is within 1% of thecurrent without the ammeter in the circuit ?

Which of the following option correctly describes the variation of the speed v and acceleration ‘a’ of a point mass falling vertically in a viscous medium that applies a force F = − kv, where ‘k’ is a constant, on the body ? (Graphs are schematic and not drawn to scale)

Figure shows elliptical path abcd of a planet around the sun S such that the area of triangle csa is $${1 \over 4}$$ the area of the ellipse. (See figure) With db as the semimajor axis, and ca as the semiminor axis. If t₁ is the time taken for planet to go over path abc and t₂ for path taken over cda then :

To find the focal length of a convex mirror, a student records the following data :

Object Pin	Convex Lens	Convex Mirror	Image Pin
22.2 cm	32.2 cm	45.8 cm	71.2 cm

The focal length of the convex lens is f₁ and that of mirror is f₂. Then taking index correction to be negligibly small, f₁ and f₂ are close to :

A simple pendulum made of a bob of mass m and a metallic wire of negligible mass has time period 2 s at T=0^oC. If the temperature of the wire is increased and the corresponding change in its time period is plotted against its temperature, the resulting graph is a line of slope S. If the coefficient of linear expansion of metal is $$\alpha $$ then the value of S is :

A uniformly tapering conical wire is made from a material of Young’s modulus Y and has a normal, unextended length L. The radii, at the upper and lower ends of this conical wire, have values R and 3 R, respectively. The upper end of the wire is fixed to a rigid support and a mass M is suspended from its lower end. The equilibrium extended length, of this wire, would equal :

The truth table given in fig. represents :

A	B	Y
0	0	0
0	1	1
1	0	1
1	1	1

In Young’s double slit experiment, the distance between slits and the screen is 1.0 m and monochromatic light of 600 nm is being used. A person standing near the slits is looking at the fringe pattern. When the separation between the slits is varied, the interference pattern disappears for a particular distance d₀ between the slits. If the angular resolution of the eye is $$({{{1}} \over {60}})^o$$, the value of d₀ is close to :

Microwave oven acts on the principle of :

When photons of wavelength $${\lambda _1}$$ are incident on an isolated sphere, the corresponding stopping potential is found to be V. When photons of wavelength $${\lambda _2}$$ are used, the corresponding stopping potential was thrice that of the above value. If light of wavelength $${\lambda _3}$$ is used then find the stopping potential for this case :

A hydrogen atom makes a transition from n = 2 to n = 1 and emits a photon. This photon strikes a doubly ionized lithium atom (z = 3) in excited state and completely removes the orbiting electron. The least quantum number for the excited state of the ion for the process is :

The potential (in volts) of a charge distribution is given by.

V(z) = 30 $$-$$ 5x² for $$\left| z \right|$$ $$ \le $$ 1 m.
V(z) = 35 $$-$$ 10 $$\left| z \right|$$ for $$\left| z \right|$$ $$ \ge $$1 m.

V(z) does not depend on x and y. If this potential is generated by a constant charge per unit volume $${\rho _0}$$ (in units of $${\varepsilon _0}$$) which is spread over a certain region, then choose the correct statement.

A magnetic dipole is acted upon by two magnetic fields which are inclined to each other at an angle of 75^o. One of the fields has a magnitude of 15 mT. The dipole attains stable equilibrium at an angle of 30^o with this field. The magnitude of the other field (in mT ) is close to

Three capacitors each of 4 $$\mu $$F are to be connected in such a way that the effective capacitance is 6 $$\mu $$F. This can be done by connecting them :

Two particles are performing simple harmonic motion in a straight line about the same equilibrium point. The amplitude and time period for both particles are same and equal to A and I, respectively. At time t = 0 one particle has displacement A while the other one has displacement $${{ - A} \over 2}$$ and they are moving towards each other. If they cross each other at time t, then t is :

200 g water is heated from 40^oC to 60^oC. Ignoring the slight expansion of water, the change in its internal energy is close to (Given specific heat of water = 4184 J/kg/K) :

The ratio of work done by an ideal monoatomic gas to the heat supplied to it in an isobaric process is :

A cubical block of side 30 cm is moving with velocity 2 ms⁻¹ on a smooth horizontal surface. The surface has a bump at a point O as shown in figure. The angular velocity (in rad/s) of the block immediately after it hits the bump, is :

A car of weight W is on an inclined road that rises by 100 m over a distance of 1 km and applies a constant frictional force $${W \over 20}$$ on the car. While moving uphill on the road at a speed of 10 ms⁻¹, the car needs power P. If it needs power $${p \over 2}$$ while moving downhill at speed v then value of $$\upsilon $$ is :

In the following ‘I’ refers to current and other symbols have their usual meaning. Choose the option that corresponds to the dimensions of electrical conductivity :

A rocket is fired vertically from the earth with an acceleration of 2g, where g is the gravitational acceleration. On an inclined plane inside the rocket, making an angle $$\theta $$ with the horizontal, a point object of mass m is kept. The minimum coefficient of friction $$\mu $$_min between the mass and the inclined surface such that the mass does not move is :

A convex lens, of focal length 30 cm, a concave lens of focal length 120 cm, and aplane mirror are arranged as shown. For an object kept at a distance of 60 cm from the convex lens, the final image, formed by the combination, is a real image, at a distance of :

A series LR circuit is connected to a voltage source with
V(t) = V₀ sin$$\Omega $$t. After very large time, current I(t) behaves as
(t₀ >> $${L \over R}$$) :

An experiment is performed to determine the I - V characteristics of a Zener diode, which has a protective resistance of R = 100 $$\Omega $$, and a maximum power of dissipation rating of 1 W. The minimum voltage range of the DC source in the circuit is :

Consider a water jar of radius R that has water filled up to height H and is kept on astand of height h (see figure). Through a hole of radius r (r << R) at its bottom, the water leaks out and the stream of water coming down towards the ground has a shape like a funnel as shown in the figure. If the radius of the cross-section of water stream when it hits the ground is x. Then :

In the circuit shown, the resistance r is a variable resistance. If for r = fR, the heat generation in r is maximum then the value of f is :

To know the resistance G of a galvanometer by half deflection method, a battery of emf V_E and resistance R is used to deflect the galvanometer by angle $$\theta $$. If a shunt of resistance S is needed to get half deflection then G, R and S are related by the equation :