The number of unpaired electrons responsible for the paramagnetic nature of the following complex species are respectively :

[Fe(CN)₆]³⁻, [FeF₆]³⁻, [CoF₆]³⁻, [Mn(CN)₆]³⁻

A(g) → B(g) + C(g) is a first order reaction.

The reaction was started with reactant A only. Which of the following expressions is correct for rate constant k?

Given below are two statements :

1 M aqueous solutions of each of Cu(NO₃)₂, AgNO₃, Hg₂(NO₃)₂, Mg(NO₃)₂ are electrolysed using inert electrodes. Given: E⁰_Ag⁺/Ag = 0.80 V, E⁰_Hg2²⁺/Hg = 0.79 V, E⁰_Cu²⁺/Cu = 0.24 V and E⁰_Mg²⁺/Mg = -2.37 V.

Statement (I) : With increasing voltage, the sequence of deposition of metals on the cathode will be Ag, Hg and Cu.

Statement (II) : Magnesium will not be deposited at the cathode instead oxygen gas will be evolved at the cathode.

In the light of the above statements, choose the most appropriate answer from the options given below :

The extra stability of half-filled subshell is due to :

(A) Symmetrical distribution of electrons

(B) Smaller coulombic repulsion energy

(C) The presence of electrons with the same spin in non-degenerate orbitals

(D) Larger exchange energy

(E) Relatively smaller shielding of electrons by one another

Indentify the correct statements :