In an irreversible process taking place at constant T and P and in which only pressure-volume work is being done, the change in Gibbs free energy (dG) and change in entropy (dS), satisfy the criteria :

The enthalpy change for a reaction does not depend upon :

The correct relationship between free energy change in a reaction and the corresponding equilibrium constant K_c is :

If at 298 K the bond energies of C - H, C - C, C = C and H - H bonds are respectively 414, 347, 615 and 435 kJ/mol, the value of enthalpy change for the reaction
H₂C = CH₂(g) + H₂(g) $$\to$$ H₃C - CH₃(g) at 298 K will be :