1
AIEEE 2003
MCQ (Single Correct Answer)
+4
-1
For the reaction equilibrium
N2O4 (g) $$\leftrightharpoons$$ 2NO2 (g)
the concentrations of N2O4 and NO2 at equilibrium are 4.8 $$\times$$ 10-2 and 1.2 $$\times$$ 10-2 mol L-1 respectively. The value of Kc for the reaction is
A
3 $$\times$$ 10-1 mol L-1
B
3 $$\times$$ 10-3 mol L-1
C
3 $$\times$$ 103 mol L-1
D
3.3 $$\times$$ 102 mol L-1
2
AIEEE 2003
MCQ (Single Correct Answer)
+4
-1
The internal energy change when a system goes from state A to B is 40 kJ/mole. If the system goes from A to B by a reversible path and returns to state A by an irreversible path what would be the net change in internal energy?
A
> 40 kJ
B
< 40 kJ
C
Zero
D
40 kJ
3
AIEEE 2003
MCQ (Single Correct Answer)
+4
-1
The enthalpy change for a reaction does not depend upon :
A
use of different reactants for the same product
B
the nature of intermediate reaction steps
C
the differences in initial or final temperature of involved substances
D
the physical states of reactants and products
4
AIEEE 2003
MCQ (Single Correct Answer)
+4
-1
In an irreversible process taking place at constant T and P and in which only pressure-volume work is being done, the change in Gibbs free energy (dG) and change in entropy (dS), satisfy the criteria :
A
(dS)V, E > 0, (dG)T, P < 0
B
(dS)V, E = 0, (dG)T, P = 0
C
(dS)V, E = 0, (dG)T, P > 0
D
(dS)V, E < 0, (dG)T, P < 0

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