In respect of the equation k = Ae^-E_a/RT in chemical kinetics, which one of the following statements is correct?

The rate law for a reaction between the substances A and B is given by Rate = k[A]ⁿ [B]^m On doubling the concentration of A and halving the concentration of B, the ratio of the new rate to the earlier rate of the reaction will be as

For the reaction system:

2NO(g) + O₂(g) $$\to$$ 2NO₂(g) volume is suddenly reduce to half its value by increasing the pressure on it. If the reaction is of first order with respect to O₂ and second order with respect to NO, the rate of reaction will

Which one of the following substances has the highest proton affinity?