1
AIEEE 2003
MCQ (Single Correct Answer)
+4
-1
Which one of the following statements is not true?
A
pH + pOH = 14 for all aqueous solutions
B
The pH of 1 $$\times$$ 10-8 M HCl is 8
C
96,500 coulombs of electricity when passed through a CuSO4 solution deposits 1 gram equivalent of copper at the cathode
D
The conjugate base of $$H_2PO_4^-$$ is $$HPO_4^{2-}$$
2
AIEEE 2003
MCQ (Single Correct Answer)
+4
-1
The internal energy change when a system goes from state A to B is 40 kJ/mole. If the system goes from A to B by a reversible path and returns to state A by an irreversible path what would be the net change in internal energy?
A
> 40 kJ
B
< 40 kJ
C
Zero
D
40 kJ
3
AIEEE 2003
MCQ (Single Correct Answer)
+4
-1
If at 298 K the bond energies of C - H, C - C, C = C and H - H bonds are respectively 414, 347, 615 and 435 kJ/mol, the value of enthalpy change for the reaction
H2C = CH2(g) + H2(g) $$\to$$ H3C - CH3(g) at 298 K will be :
A
- 250 kJ
B
+ 125 kJ
C
- 125 kJ
D
+ 250 kJ
4
AIEEE 2003
MCQ (Single Correct Answer)
+4
-1
In an irreversible process taking place at constant T and P and in which only pressure-volume work is being done, the change in Gibbs free energy (dG) and change in entropy (dS), satisfy the criteria :
A
(dS)V, E > 0, (dG)T, P < 0
B
(dS)V, E = 0, (dG)T, P = 0
C
(dS)V, E = 0, (dG)T, P > 0
D
(dS)V, E < 0, (dG)T, P < 0
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