1
AIEEE 2003
MCQ (Single Correct Answer)
+4
-1
One mole of the complex compound Co(NH3)5Cl3, gives 3 moles of ions on dissolution in water. One mole of the same complex reacts with two moles of AgNO3 solution to yield two moles of AgCl (s). The structure of the complex is :
A
[Co(NH3)3Cl3]. 2NH3
B
[Co(NH3)4Cl2] Cl. NH3
C
[Co(NH3)4Cl] Cl2. NH3
D
[Co(NH3)5Cl] Cl2
2
AIEEE 2003
MCQ (Single Correct Answer)
+4
-1
In the coordination compound, K4[Ni(CN)4], the oxidation state of nickel is :
A
0
B
+1
C
+2
D
-1
3
AIEEE 2003
MCQ (Single Correct Answer)
+4
-1
Bottles containing C6H5l and C6H5CH2I lost their original labels. They were labelled A and B for testing A and B were separately taken in test tubes and boiled with NaOH solution. The end solution in each tube was made acidic with dilute HNO3 and then some AgNO3 solution was added. Substance B gave a yellow precipitate. Which one of the following statements is true for this experiment?
A
A and C6H5CH2I
B
B and C6H5I
C
Addition of HNO3 was unnecessary
D
A was C6H5I
4
AIEEE 2003
MCQ (Single Correct Answer)
+4
-1
During dehydration of alcohols to alkenes by heating with conc. H2SO4 the initiation step is
A
formation of carbocation
B
elimination of water
C
formation of an ester
D
protonation of alcohol molecule
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