1
JEE Main 2024 (Online) 4th April Evening Shift
MCQ (Single Correct Answer)
+4
-1

The number of unpaired d-electrons in $$\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}$$ is ________.

A
0
B
2
C
1
D
4
2
JEE Main 2024 (Online) 4th April Evening Shift
MCQ (Single Correct Answer)
+4
-1

A first row transition metal in its +2 oxidation state has a spin-only magnetic moment value of $$3.86 \mathrm{~BM}$$. The atomic number of the metal is

A
22
B
23
C
26
D
25
3
JEE Main 2024 (Online) 4th April Morning Shift
MCQ (Single Correct Answer)
+4
-1

Number of complexes from the following with even number of unpaired "$$\mathrm{d}$$" electrons is ________ $$[\mathrm{V}(\mathrm{H}_2 \mathrm{O})_6]^{3+},[\mathrm{Cr}(\mathrm{H}_2 \mathrm{O})_6]^{2+},[\mathrm{Fe}(\mathrm{H}_2 \mathrm{O})_6]^{3+},[\mathrm{Ni}(\mathrm{H}_2 \mathrm{O})_6]^{3+},[\mathrm{Cu}(\mathrm{H}_2 \mathrm{O})_6]^{2+}$$ [Given atomic numbers: $$\mathrm{V}=23, \mathrm{Cr}=24, \mathrm{Fe}=26, \mathrm{Ni}=28 \mathrm{Cu}=29$$]

A
1
B
5
C
2
D
4
4
JEE Main 2024 (Online) 4th April Morning Shift
MCQ (Single Correct Answer)
+4
-1

The correct sequence of ligands in the order of decreasing field strength is :

A
$$\mathrm{NCS}^{-}>\mathrm{EDTA}^{4-}>\mathrm{CN}^{-}>\mathrm{CO}$$
B
$$\mathrm{CO}>\mathrm{H}_2 \mathrm{O}>\mathrm{F}^{-}>\mathrm{S}^{2-}$$
C
$$\mathrm{S}^{2-}>{ }^{-} \mathrm{OH}>\mathrm{EDTA}^{4-}>\mathrm{CO}$$
D
$${ }^{-} \mathrm{OH}>\mathrm{F}^{-}>\mathrm{NH}_3>\mathrm{CN}^{-}$$
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