1
JEE Main 2024 (Online) 8th April Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

An octahedral complex with the formula $$\mathrm{CoCl}_3 \cdot \mathrm{nNH}_3$$ upon reaction with excess of $$\mathrm{AgNO}_3$$ solution gives 2 moles of $$\mathrm{AgCl}$$. Consider the oxidation state of $$\mathrm{Co}$$ in the complex is '$$x$$'. The value of "$$x+n$$" is __________.

A
6
B
5
C
3
D
8
2
JEE Main 2024 (Online) 8th April Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Given below are two statements:

Statement I: $$\mathrm{N}\left(\mathrm{CH}_3\right)_3$$ and $$\mathrm{P}\left(\mathrm{CH}_3\right)_3$$ can act as ligands to form transition metal complexes.

Statement II: As N and P are from same group, the nature of bonding of $$\mathrm{N}\left(\mathrm{CH}_3\right)_3$$ and $$\mathrm{P}\left(\mathrm{CH}_3\right)_3$$ is always same with transition metals.

In the light of the above statements, choose the most appropriate answer from the options given below:

A
Both Statement I and Statement II are incorrect.
B
Both Statement I and Statement II are correct.
C
Statement I is incorrect but Statement II is correct.
D
Statement I is correct but Statement II is incorrect.
3
JEE Main 2024 (Online) 8th April Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Match List I with List II

LIST I
(Compound)
LIST II
(Colour]
A. $$\mathrm{Fe}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]_3 \cdot \mathrm{xH_2O}$$ I. Violet
B. $$\left[\mathrm{Fe}(\mathrm{CN})_5 \mathrm{NOS}\right]^{4-}$$ II. Blood Red
C. $$[\mathrm{Fe}(\mathrm{SCN})]^{2+}$$ III. Prussian Blue
D. $$\left(\mathrm{NH}_4\right)_3 \mathrm{PO}_4\cdot12 \mathrm{MoO}_3$$ IV. Yellow

Choose the correct answer from the options given below:

A
A-IV, B-I, C-II, D-III
B
A-I, B-II, C-III, D-IV
C
A-II, B-III, C-IV, D-I
D
A-III, B-I, C-II, D-IV
4
JEE Main 2024 (Online) 6th April Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Given below are two statements :

Statement I: $$\mathrm{PF}_5$$ and $$\mathrm{BrF}_5$$ both exhibit $$\mathrm{sp}^3 \mathrm{~d}$$ hybridisation.

Statement II: Both $$\mathrm{SF}_6$$ and $$[\mathrm{Co}(\mathrm{NH}_3)_6]^{3+}$$ exhibit $$\mathrm{sp}^3 \mathrm{~d}^2$$ hybridisation.

In the light of the above statements, choose the correct answer from the options given below :

A
Both Statement I and Statement II are false
B
Statement I is true but Statement II is false
C
Statement I is false but Statement II is true
D
Both Statement I and Statement II are true
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